• Title/Summary/Keyword: Porous particle

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Magnetic Properties of Electrodeposited Iron and Cobalt on Porous Aluminum Oxide Layer (다공성 알루미늄 양극산화 피막에 도금된 철 및 코박트의 자기적 성질)

  • Kim, K. H.;Kang, T.;Sohn, H. J.
    • Journal of the Korean institute of surface engineering
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    • v.23 no.3
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    • pp.150-159
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    • 1990
  • The magnetic properties of electrodeposited iron and cobalt films on porous aluminum oxide film were examined. There exists perpendicular magnetic anisotropy due to the shape anisotropy. The coercivity and squareness ratio of films were strongly dependent on deposited particle diameter. The effect of packing fraction on squareness ratio was also apprecible. Unlike the iron-deposited films, the magnetic properties of cobalt films were changed by preferred orientation because of it's large crystal ansotropy constant.(about 10 times of Fe) The Fe deposited films were found to be more suitable for perpendicular magenetic recording media bacause perpendicular coercivity, squareness ratio and the ratio of perpendicular coercivity to horizontal ones of iron films are greater than those of cobalt films.

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A Numerical Study on Solute Transport in Heterogeneous Porous Media

  • Jeong, Woo-Chang;Song, Jai-Woo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2002.05b
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    • pp.1027-1033
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    • 2002
  • The solute transport in a two-dimensional heterogeneous porous medium is numerically studied by using a random walk particle tracking (RWPT) method. Lognormally isotropic hydraulic conductivity fields are generated by using the turning band methods with mean zero and four different values of standard deviation. The numerical transport experiments are carried out to investigate the large time and spatial effects of the variable pore velocity field on solute plumes. The behavior of the solute plume through numerical simulations is presented in terms of longitudinal and transverse spatial moments: displacement of center-of-mass, plume spread variance and skewness coefficient. It was observed that the dispersive behavior of the solute plume is strongly affected by the degree of heterogeneity in the flow domain.

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Sintering of porous ceramic of diatomite according to molding pressure and PEG content

  • Lee, Ye-Na;Ahn, Seok-Hwan;Nam, Hoseok;Nam, Ki-Woo
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.467-471
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    • 2018
  • Diatomite powder, a naturally occurring porous raw material, was used to make ceramic materials with porosity and high strength. The sintering behavior of the diatomite powder at various sintering temperatures suggests that diatomite monoliths with a high porosity and strength can be prepared at $1100^{\circ}C$. The compressive strength of the sintered diatomite monoliths increased as the sintering temperature increased, and the molding pressure of 2 MPa and the binder of 18.6 wt.% were excellent. When the sintering temperature rises, the diatomite powder is melted, and its pores gradually disappear. SEM images show that strengthening begins with the formation of inter-particle bonds at a low sintering temperature.

Study on dryout heat flux of axial stratified debris bed under top-flooding

  • Wenbin Zou;Lili Tong;Xuewu Cao
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.636-643
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    • 2024
  • The coolability of the debris bed with a simulant of solidified corium is experimentally studied, focusing on the effects of the structure of the axial stratified debris bed on the dryout heat flux (DHF). DHF was obtained for the four structures with different particle sizes for the axial stratified debris bed under top flooding. The experimental results show that the dryout position of the axial stratified debris bed is formed at the stratified interface indicated by the temperature rise, and the DHF of the axial stratified bed is much lower than that of the homogeneous bed packed with the upper small particles. To predict the dryout heat flux of the stratified debris beds, by considering the properties of the mixed area, a one-dimensional dryout heat flux model of the porous medium is derived from a water and vapor momentum equation for porous medium, two-phase permeability modifications, interfacial drag, and the correlation between capillary pressure and liquid saturation and verified with the experimental data. The modified model can give reasonable results under different structures.

Estimation of Settling Efficiency in Sedimentation Basin Using Particle Tracking Method (입자추적기법을 이용한 침전지의 효율 평가)

  • Lee, Kil-Seong;Kim, Sang-Hoon
    • Journal of Korea Water Resources Association
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    • v.37 no.4
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    • pp.293-304
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    • 2004
  • Sedimentation basin plays an important role in urban water treatment, and there are many complicated phenomena which need to be understood for efficient design and control of it. Especially, the study on the improvement of settling efficiency is required. In this study, commercial CFD (Computational Fluid Dynamics) program, FLUENT, and particle tracking method were used to simulate the flow in sedimentation basin, and to predict the settling efficiency. Computational domain of real scale was made, and detail factors such as porous wall, and outlet trough were considered instead of being simplified. The simulation results were compared with the experimental data to calibrate the parameters of particle tracking method. Sensitivity analysis showed that the particle diameter had more significant effects on settling efficiency than the particle density. The computation results gave the best agreements with the experimental data, when the value of particle diameter was 26.5 ${\mu}{\textrm}{m}$.

Particle Behavior and Deformation During Compaction of Al Powder Using MPFEM (다입자유한요소법을 이용한 Al분말 압축공정에서 입자의 거동과 변형에 관한 연구)

  • Lee, Kyung-Hun;Lee, Jung-Min;Kim, Byung-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.4
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    • pp.383-390
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    • 2010
  • This paper describes multiparticle finite element model (MPFEM)-based powder compaction simulations performed to demonstrate the densification of compacted aluminum powders. A 2D MPFEM was used to explore the densification of a collection of aluminum particles with different average particle sizes under various ram speeds. Individual particles are discretized using a finite element mesh for a detailed description of contact mechanics. Porous aluminum powders with average particle sizes of $20\;{\mu}m$ and $3\;{\mu}m$ were compressed uniaxially at ram speeds of 5, 15, 30, and 60 mm/min by using an MTS servo-hydraulic tester. The slow ram speed was of great advantage to powder densification in low compaction force due to sufficient particle rearrangement. Owing to a decrease in the average particle size of aluminum, the compaction force increased.

Recent Research Trends of Mixed Matrix Membranes for CO2 Separation (이산화탄소 분리용 혼합 매질 분리막 최신 연구 동향)

  • Chi, Won Seok;Lee, Jae Hun;Park, Min Su;Kim, Jong Hak
    • Membrane Journal
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    • v.25 no.5
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    • pp.373-384
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    • 2015
  • In the past few decades, polymeric membrane has played an important role in gas separation applications. For the separation of $CO_2$, one of greenhouse gases, high permselectivity, long-term stability and scale-up are needed. However, conventional polymeric membranes have shown a trade-off relation between permeability and selectivity while inorganic materials are highly permeable but expensive. Mixed matrix membranes (MMMs) combining the advantages of both polymeric and inorganic materials have become a possible breakthrough for the next-generation gas separation membranes. The MMMs could be either symmetric or asymmetric but the latter is more preferred to improve the permeance. Important factors influencing the MMM fabrication include homogeneous distribution of inorganic particles and good interfacial contact between inorganic filler and organic matrix. Recently, metal organic frameworks (MOFs) have received much attention as a new class of porous crystalline materials and a potential candidate for $CO_2$ separation. Zeolitic imidazolate frameworks (ZIFs), a sub-branch of MOFs, are the most widely used in MMMs due to small particle size and appropriate pore size for $CO_2$ separation. One of the major issues associated with the incorporation of porous particles in a polymeric membrane is to control the microstructure of the porous particle materials such as particle size, orientation, and boundary conditions etc. In this review, major challenges surrounding MMMs and the strategies to tackle these challenges are given in detail.

Synthesis of Ceria Nanosphere by Ultrasonic Spray Pyrolysis

  • Kim, Jong-Young;Kim, Ung-Soo;Cho, Woo-Seok
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.249-252
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    • 2009
  • Nanocrystalline ceria particles were prepared by using the ultrasonic spray pyrolysis method. The prepared ceria particles were found to be spherical and non-agglomerated by the SEM and TEM analyses. It was found that carrier gas influences the size and morphology. It was found that the air stream of carrier gas results in porous agglomerated structure of ceria abrasives, whereas solid nano-sphere can be obtained in a more oxidizing atmosphere.

Adsorption of Colloidal Silica Particles on a Glass Substrate

  • Sim, Soo-Man
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1011-1016
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    • 2002
  • Colloidal particles of silica (100 nm in size) were electrostatically dispersed and adsorbed on a glass substrate coated with silica sol or alumina sol. Stability of the suspensions and microstructure of the adsorbed particle layers were discussed in terms of total potential energies between the particles and the substrate. Well-dispersed suspension resulted in a layer with densely packed and regularly arranged particles, whereas less stable suspension resulted in a porous layer with loosely packed and irregularly arranged particles. Despite repulsive interactions between the particles and the substrate coated with silica sol, the observed adsorption can be attributed to chemical bonds formed at the interface between the particle and silica sol. In contrast, the adsorption of the particles on the substrate coated with alumina sol formed a layer with strongly adhered and densely packed particles, due to large attractive interactions between the particles and alumina sol.

Modeling the alkali aggregate reaction expansion in concrete

  • Zahira, Sekrane Nawal;Aissa, Asroun
    • Computers and Concrete
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    • v.16 no.1
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    • pp.37-48
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    • 2015
  • Alkali aggregate reaction affects numerous civil engineering structures and causes irreversible expansion and cracking. This work aims at developing model to predict the potential expansion of concrete containing alkali-reactive aggregates. First, the paper presents the experimental results concerning the influence of particle size of an alkali-reactive aggregate on mortar expansion studied at 0.15-0.80 mm, 1.25-2.50 mm and 2.5-5.0 mm size fractions and gives data necessary for model development. Results show that no expansion was measured on the mortars using small particles (0.15-0.80 mm) while the particles (1.25-2.50 mm) gave the largest expansions. Finally, model is proposed to simulate the experimental results by studying correlations between the measured expansions and the size of aggregates and to calculate the thickness of the porous zone necessary to take again all the volume of the gel created by this chemical reaction.