• 제목/요약/키워드: Porous microstructure

검색결과 311건 처리시간 0.027초

Ultrahigh Birefringence and Extremely Low Loss Slotted-core Microstructure Fiber in Terahertz Regime

  • Habib, Md. Ahasan;Anower, Md. Shamim;Hasan, Md. Rabiul
    • Current Optics and Photonics
    • /
    • 제1권6호
    • /
    • pp.567-572
    • /
    • 2017
  • A novel slotted-core hexagonal photonic crystal fiber (PCF) for terahertz (THz) wave guiding is proposed in this paper. A trade-off managed between effective material loss (EML) and birefringence for efficient guidance of THz waves is illustrated in this article. The rectangular slot shaped air-holes break the symmetry of the porous-core which offers ultra-high birefringence of $8.8{\times}10^{-2}$. The proposed structure offers low bending loss of $1.07{\times}10^{-34}cm^{-1}$ and extremely low effective material loss (EML) of $0.035cm^{-1}$ at an operating frequency of 1.0 THz. In addition other guiding properties such as power fraction, dispersion and confinement loss are also discussed. The proposed THz waveguide can be effectively used for convenient transmission of THz waves.

Nanocomposite Ni-CGO Synthesized by the Citric Method as a Substrate for Thin-film IT-SOFC

  • Wang, Zhenwei;Liu, Yu;Hashimoto, Shin-ichi;Mori, Masashi
    • 한국세라믹학회지
    • /
    • 제45권12호
    • /
    • pp.782-787
    • /
    • 2008
  • Ni-ceria cermets have been extensively investigated as candidates for the anode in intermediate-temperature solid oxide fuel cells. We have used the citric method to synthesize nanocomposite powders consisting of NiO (Ni metal content: $40{\sim}60%$ by volume) highly dispersed in $Ce_{0.9}Gd_{0.1}O_{1.95}$ (CGO). The microstructure characteristics and sintering behaviors of the nanocomposites were investigated. No impurity phases were observed and the shrinkage of these substrates matched well with that of a CGO electrolyte with a specific surface area of $11\;m^2/g$. Densification of the CGO electrolyte layer to $<5\;{\mu}m$ thickness was achieved by co-firing the laminated electrolyte with the porous NiO-CGO substrate at $1400^{\circ}C$ for 6 h.

$LaNiO_3$전도성 세라믹의 합성과 도전특성 (Synthesis and Conductivity Properties of $LaNiO_3$ Ceramic Conductors)

  • 조정호;조주현;김강언;정수태
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
    • /
    • pp.406-409
    • /
    • 2001
  • The conductivity properties and synthesis of $LaNiO_{3}$ ceramics from $La_{1+\delta}NiO_{3}(\delta=-0.06,0,0.06)$ were investigated. A single perovskite phase was realized at $800^{\circ}C$. $La_{2}NiO_{4}$ and other unexpected oxide were observed at $1000^{\circ}C$. The Microstructure was showed clearly that it is a low density porous material. $LaNiO_3$ ceramic showed a metallic conductivity. The conductivity of La rich samples had a higher value than the La poor samples.

  • PDF

Representative Volume Element Analysis of Fluid-Structure Interaction Effect on Graphite Powder Based Active Material for Lithium-Ion Batteries

  • Yun, Jin Chul;Park, Seong Jin
    • 한국분말재료학회지
    • /
    • 제24권1호
    • /
    • pp.17-23
    • /
    • 2017
  • In this study, a finite element analysis approach is proposed to predict the fluid-structure interaction behavior of active materials for lithium-ion batteries (LIBs), which are mainly composed of graphite powder. The porous matrix of graphite powder saturated with fluid electrolyte is considered a representative volume element (RVE) model. Three different RVE models are proposed to consider the uncertainty of the powder shape and the porosity. P-wave modulus from RVE solutions are analyzed based on the microstructure and the interaction between the fluid and the graphite powder matrix. From the results, it is found that the large surface area of the active material results in low mechanical properties of LIB, which leads to poor structural durability when subjected to dynamic loads. The results obtained in this study provide useful information for predicting the mechanical safety of a battery pack.

졸겔법에 의한 박막형 습도센서 소제개발에 관한 연구(II) (A Study on the Development of Thin Film Type Humidity Sensor Materials by Sol-Gel Method(II))

  • 유도현;강대하;나동근;황명환;육재호;이덕출
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1994년도 하계학술대회 논문집 C
    • /
    • pp.1472-1474
    • /
    • 1994
  • In this paper, $TiO_2-V_2O_5$ thin films are fabricated by Sol-Gel method and their humidity-sensing characteristics have been investigated. The microstructure of specimen is porous. The humidity-sensing characteristics of thin films are good according to increasing heat treatment temperature and decreasing measurement frequency.

  • PDF

The Sintering Behaviour of Fe-Mn-C Powder System, Correlation between Thermodynamics and Sintering Process, Mn Distribution, Microstructure

  • Hryha, Eduard;Dudrova, Eva
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
    • /
    • pp.839-840
    • /
    • 2006
  • Sintering behavior of the Fe-0.8Mn-0.5C powder system was studied on the specimens with a density of ${\sim}7.0g/cc$ sintered at $1120^{\circ}C$ for 30 min in a gas mixture of $7%H_2/93%N_2$ with the inlet dew point of $-60^{\circ}C$. During the atmosphere monitoring ($CO/CO_2$-content and dew point) was showed, that carbothermical reduction occurs in two different temperature ranges; three peaks of dew point profile also can be distinguished during sintering cycle as well. Following sintering the Mn-content distribution and microstructures around the Mn-source were micro-analytical evaluated; the results showed that manganese travels through porous iron matrix up to ${\sim}60{\mu}m$.

  • PDF

Fabrication of $TiO_2-CeO_2$ Composite Membranes with Thermal Stability

  • Bae, Dong-Sik;Han, Kyong-Sop;Park, Sang-Hael
    • The Korean Journal of Ceramics
    • /
    • 제1권4호
    • /
    • pp.219-223
    • /
    • 1995
  • Ceramic membranes of the supported $TiO_2-CeO_2$ were prepared by dip-coating method on an $\alpha-Al_2O_3$ porous substrate. The mean pore diameter of an alumina support was 0.125 um. The mean particle diameter of $TiO_2-CeO_2$ top layer varied with firing temperature and ranged from 20 to 85 nm. The thermal stability of the composite membranes was studied from their surface microstructure after calcination at $600-900^{\circ}C$. The supported $TiO_2-CeO_2$ composite membranes exhibited much higher heat resistance than the $TiO_2$ membrane.

  • PDF

$\alpha$-Fe$_2$O$_3$ 박막 센서의 환원성 가스감지특성 (Sensing Properties of $\alpha$-Fe$_2$O$_3$ Thin Film Gas Sensor to Reducing Gases)

  • 이은태;장건익;이덕동
    • 한국세라믹학회지
    • /
    • 제36권5호
    • /
    • pp.465-470
    • /
    • 1999
  • Sensing properties of $\alpha$-Fe2O3 thin film to reducing gases such as CHx and CO were systematically examined after deposition on Al2O3 substrate by PECVD(Plasma Enhanced Chemical Vapor Deposition)technique. Microstructure of deposited $\alpha$-Fe2O3 thin film showed the porous island structure. This specimen was annealed at 450, 550, $650^{\circ}C$ to enhance the gas sensing properties and investigated in terms of CO and C4H10 concentration from 500ppm to 3,000 ppm at operating temperature of 35$0^{\circ}C$ The gas sensitivity(%) to C4H10 measured at the operating temperature of 35$0^{\circ}C$ was 98.24 (highest sensitivity) 69.51 to CO and 2% to CH4 respectviely.

  • PDF

졸-겔법에 의한 지르코니아 섬유 제조 및 그 특성 (Preparation of $ZrO_2$ Fibers by the Sol-Gel Process and its Properties)

  • 김환;김영정;황규홍
    • 한국세라믹학회지
    • /
    • 제23권4호
    • /
    • pp.78-84
    • /
    • 1986
  • Zirconium acetate solution which was obtained from $ZrOCl_2$.$8H_2O$ was condensed polymerized and drawn to fibers by pulling method. Drawn gel fibers fired at 130$0^{\circ}C$ were short porous and mechanically weak. But addition of CaO about 13m/o caused the fibers to have the cubic structure and relatively dense microstructure. In order to clarify the condition for the synthesis of zirconia fibers viscosity measurement DTA-TG analysis X-ray diffraction infrared spectroscopy, SEM and specific surface area were studied.

  • PDF

Thermal Shock Resistance of Bilayered YSZ Thermal Barrier Coating

  • Lee, Dong Heon;Kim, Tae Woo;Lee, Kee Sung;Kim, Chul
    • 한국세라믹학회지
    • /
    • 제55권5호
    • /
    • pp.452-460
    • /
    • 2018
  • This study investigate changes in mechanical behaviors such as indentation load-displacement and hardness of thermal barrier coatings (TBCs) using cycling of thermal shock test. Relatively dense and porous TBCs on nickel-based bondcoat/super alloy are prepared using different starting granules, 204C-NS and 204NS commercial powers, and the effect of double layers of 204C-NS on 204NS and 204NS on 204C-NS are investigated. The highest temperature applied during thermal shock test is $1100^{\circ}C$ and the maximum number of cycles is 1,200. The results indicate that bilayered TBC showed a relatively mechanically resistant property during thermal shock cycles and that the mechanical behavior is influenced by the microstructure of TBCs by exposure to high temperature during tests or different starting granules.