• Steel and Composite Structures
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• v.46 no.2
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• pp.263-277
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• 2023

Free vibration analysis of multi-directional porous functionally graded (FG) sandwich plate has been performed for two cases namely: FG skin with homogeneous core and FG core with homogeneous skin. Hamilton's principle was employed and the solution was obtained using Navier's technique. This theory imposes traction-free boundary conditions on the surfaces and does not require shear correction factors. The results obtained are validated with those available in the literature. The composition of metal-ceramic-based functionally graded material (FGM) changes in longitudinal and transverse directions according to the power law. Imperfections in the functionally graded material introduced during the fabrication process were modeled with different porosity laws such as evenly, unevenly distributed, and logarithmic uneven distributions. The effect of porosity laws and geometry parameters on the natural frequency was investigated. On comparing the natural frequency of two cases for perfect and imperfect sandwich plates a reverse trend in natural frequency result was seen. The finding shows a multidirectional functionally graded structures perform better compared to uni-directional gradation. Hence, critical grading parameters and imperfection types have been identified which will guide experimentalists and researchers in selecting fabrication routes for improving the performance of such structures.

• Computers and Concrete
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• v.32 no.5
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• pp.439-454
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• 2023

In this article, the surface stress effects on the buckling analysis of the annular sandwich plate is developed. The proposed plate is composed of two face layers made of carbon nanotubes (CNT) reinforced composite with assuming of fully bonded to functionally graded porous core. The generalized rule of the mixture is employed to predict the mechanical properties of the microcomposite sandwich plate. The derived potentials energy based on higher order shear deformation theory (HSDT) and modified couple stress theory (MCST) is solved by employing the Ritz method. An exact analytical solution is presented to calculate the critical buckling loads of the annular sandwich plate. The predicted results are validated by carrying out the comparison studies for the buckling analysis of annular plates with those obtained by other analytical and finite element methods. The effects of various parameters such as material length scale parameter, core thickness to total thickness ratio (hc/h), surface elastic constants based on surface stress effect, various boundary condition and porosity distributions, size of the internal pores (e0), Skempton coefficient and elastic foundation on the critical buckling load have been studied. The results can be served as benchmark data for future works and also in the design of materials science, injunction high-pressure micropipe connections, nanotechnology, and smart systems.

• The Journal of Engineering Geology
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• v.9 no.3
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• pp.253-265
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• 1999

Physical properties of Paleozoic sedimentary rocks in Gabsan formation in Jechon area were obtained by both geophysical well log methods and core property measurements, and the similarity and difference shown between the well log and core log responses were analyzed. The physical properties obtained are natural gamma, resistivity and density. From the difference in density response between the well log and core measurement, the need of correction for natural gamma effect on density log was strongly suggested. And fairly good correlation was obtained between well log and core properties, and among natural gamma, resistivity and density by applying natural gamma correction on density log. It is noted that shale in Gabsan formation reveals very high density, even higher than the density of adjacent non-porous limestone.

• Journal of Sensor Science and Technology
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• v.27 no.5
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• pp.345-351
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• 2018

We employed an unprecedented technique to synthesize porous $WO_3@SnO_2$ nanofibers exhibiting core-shell and fiber-in-tube configurations. Firstly, 2-methylimidazole was uniformly incorporated in as-spun nanofibers containing ammonium metatungstate hydrate and the sacrificial polymer (polyacrylonitrile). Secondly, the 2-methylimidazole on the surfaces of nanofibers was complexed with tin(II) chloride ($SnCl_2$) via simple impregnation of the as-spun nanofibers in ethanol containing tin(II) chloride dihydrate ($SnCl_2{\cdot}2H_2O$). The presence of vacant p-orbitals in tin (Sn) and the nucleophilic nitrogen on the imidazole ring allowed for the reaction between $SnCl_2$ and 2-methylimidazole, forming adducts on the surfaces of the as-spun nanofibers. The calcination of these nanofibers resulted in porous $WO_3@SnO_2$ nanofibers with a higher surface area ($55.3m^2{\cdot}g^{-1}$) and a better response to 1-5 ppm of acetone than pristine $SnO_2$ NFs synthesized using a similar method. An improved response to acetone was achieved upon functionalization of the $WO_3@SnO_2$ nanofibers with catalytic palladium nanoparticles. This work demonstrates the potential application of $WO_3@SnO_2$ nanofibers as sensing layers for chemiresistive sensory devices for the detection of acetone in exhaled breath.

• Nuclear Engineering and Technology
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• v.52 no.4
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• pp.708-720
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• 2020

Core-wide temperature distribution in sodium-cooled fast reactor plays a key role in its decay heat removal process, however the prediction for temperature distribution is quite complex due to the conjugate heat transfer between the assembly flow and the inter-wrapper flow. Hybrid medium model has been proposed for conjugate heat transfer modeling in the core. The core is modeled with a Realistic modeled inter-wrapper flow and hybrid medium modeled assembly flow. To validate present model, simulations for a three-assembly model were performed with Realistic modeling, traditional porous medium model and hybrid medium model, respectively. The influences of Uniform/Non-Uniform power distribution among assemblies and the Peclet number within the assembly flow have been considered. Compared to traditional porous medium model, present model shows a better agreement with in Realistic modeling prediction of the temperature distribution and the radial heat transfer between the inter-wrapper flow and the assembly flow.

• Current Optics and Photonics
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• v.1 no.6
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• pp.567-572
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• 2017

A novel slotted-core hexagonal photonic crystal fiber (PCF) for terahertz (THz) wave guiding is proposed in this paper. A trade-off managed between effective material loss (EML) and birefringence for efficient guidance of THz waves is illustrated in this article. The rectangular slot shaped air-holes break the symmetry of the porous-core which offers ultra-high birefringence of $8.8{\times}10^{-2}$. The proposed structure offers low bending loss of $1.07{\times}10^{-34}cm^{-1}$ and extremely low effective material loss (EML) of $0.035cm^{-1}$ at an operating frequency of 1.0 THz. In addition other guiding properties such as power fraction, dispersion and confinement loss are also discussed. The proposed THz waveguide can be effectively used for convenient transmission of THz waves.

• Macromolecular Research
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• v.17 no.12
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• pp.1010-1014
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• 2009

Monodispersed microparticles with a poly(D,L-lactide-co-glycolide) (PLGA) core and a poly(ethyl 2-cyanoacrylate) (PE2CA) shell were prepared by Shirasu porous glass (SPG) membrane emulsification to reduce the initial burst release of doxorubicin (DOX). Solution mixtures with different weight ratios of PLGA polymer and E2CA monomer were permeated under pressure through an SPG membrane with $1.9\;{\mu}m$ pore size into a continuous water phase with sodium lauryl sulfate as a surfactant. Core-shell structured microparticles were formed by the mechanism of anionic interfacial polymerization of E2CA and precipitation of both polymers. The average diameter of the resulting microparticles with various PLGA:E2CA ratios ranged from 1.42 to $2.73\;{\mu}m$. The morphology and core-shell structure of the microparticles were observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The DOX release profiles revealed that the microparticles with an equivalent PLGA:E2CA weight ratio of 1:1 exhibited the optimal condition to reduce the initial burst of DOX. The initial release rate of DOX was dependent on the PLGA:E2CA ratio, and was minimized at a 1:1 ratio.

• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.449-454
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• 2016

In this study, highly monodispersed porous carbon microcapsules with a hollow core were synthesized using polystyrene (PS) beads as a hard template. The surface of PS was first modified with polyvinylpyrollidone (PVP) for the easy attachment of inorganic silica sol. After coating the surface of PVP modified PS microspheres with SBA-16 sol, the carbon microcapsules with a hollow macroporous core were fabricated through reverse replication method by filling carbon sources in the mesopores of silica mold. The hollow carbons having a mesoporous shell structure and narrow particle size distribution could be obtained after the carbonization of carbon source and the dissolution of silica mold by HF solution. The mesoporous characteristics and electrochemical properties of hollow carbon microcapsules were characterized by XRD, SEM, TEM, $N_2$ adsorption/desorption analysis and cyclic voltammetry. They showed the high electric conductivity and capability for use as efficient electro-materials such as a supercapacitor.

• Steel and Composite Structures
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• v.37 no.6
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• pp.711-731
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• 2020

This paper deals with free vibration of FG sandwich annular sector plates on Pasternak elastic foundation with different boundary conditions, based on the three-dimensional theory of elasticity. The plates with simply supported radial edges and arbitrary boundary conditions on their circular edges are considered. The influence of carbon nanotubes (CNTs) waviness, aspect ratio, internal pores and graphene platelets (GPLs) on the vibrational behavior of functionally graded nanocomposite sandwich plates is investigated in this research work. The distributions of CNTs are considered functionally graded (FG) or uniform along the thickness of upper and bottom layers of the sandwich sectorial plates and their mechanical properties are estimated by an extended rule of mixture. In this study, the classical theory concerning the mechanical efficiency of a matrix embedding finite length fibers has been modified by introducing the tube-to-tube random contact, which explicitly accounts for the progressive reduction of the tubes' effective aspect ratio as the filler content increases. The core of structure is porous and the internal pores and graphene platelets (GPLs) are distributed in the matrix of core either uniformly or non-uniformly according to three different patterns. The elastic properties of the nanocomposite are obtained by employing Halpin-Tsai micromechanics model. A semi-analytic approach composed of 2D-Generalized Differential Quadrature Method (2D-GDQM) and series solution is adopted to solve the equations of motion. The fast rate of convergence and accuracy of the method are investigated through the different solved examples. Some new results for the natural frequencies of the plate are prepared, which include the effects of elastic coefficients of foundation, boundary conditions, material and geometrical parameters. The new results can be used as benchmark solutions for future researches.

• Journal of Electrochemical Science and Technology
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• v.12 no.3
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• pp.346-357
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• 2021

In recent years, supercapacitors have been developed rapidly as a rechargeable energy storage device. And the performance of supercapacitors is depending on electrode materials, the preparation method and performance of electrode materials have become the primary goal of scientific development. This study synthesizes Co₃O₄@MnO₂@PPy cathode material with porous pattern core-shell structure by hydrothermal method and electrodeposition. The result samples are characterized by X-ray diffraction transmission/scanning electron microscope, and X-ray photoelectron spectroscopy. Electrochemical evaluation reveals that electrochemical performance is significantly enhanced by PPy depositing. The specific capacitance of Co₃O₄@MnO₂@PPy is 977 F g^-1 at 1 A g^-1, the capacitance retention rate of 105%. Furthermore, the electrochemical performance of Co₃O₄@MnO₂@PPy//AC asymmetric supercapacitor assembles with AC as the negative electrode material is significantly better than that of MnO₂//AC and Co₃O₄@MnO₂//AC. The capacity of Co₃O₄@MnO₂@PPy//AC is 102.78 F g^-1. The capacity retention rate is still 120% for 5000 charge-discharge cycles.