• Bulletin of the Korean Chemical Society
• /
• 제34권2호
• /
• pp.519-523
• /
• 2013

When atomic layer deposition (ALD) is performed on a porous material by using an organometallic precursor, minimum exposure time of the precursor for complete coverage becomes much longer since the ALD is limited by Knudsen diffusion in the pores. In the previous report by Min et al. (Ref. 23), shrinking core model (SCM) was proposed to predict the minimum exposure time of diethylzinc for ZnO ALD on a porous cylindrical alumina monolith. According to the SCM, the minimum exposure time of the precursor is influenced by volumetric density of adsorption sites, effective diffusion coefficient, precursor concentration in gas phase and size of the porous monolith. Here we modify the SCM in order to consider undesirable adsorption of byproduct molecules. $TiO_2$ ALD was performed on the cylindrical alumina monolith by using titanium tetrachloride ($TiCl_4$) and water. We observed that the byproduct (i.e., HCl) of $TiO_2$ ALD can chemically adsorb on adsorption sites, unlike the behavior of the byproduct (i.e., ethane) of ZnO ALD. Consequently, the minimum exposure time of $TiCl_4$ (~16 min) was significantly much shorter than that (~71 min) of DEZ. The predicted minimum exposure time by the modified SCM well agrees with the observed time. In addition, the modified SCM gives an effective diffusion coefficient of $TiCl_4$ of ${\sim}1.78{\times}10^{-2}\;cm^2/s$ in the porous alumina monolith.

• Advances in nano research
• /
• 제7권2호
• /
• pp.109-123
• /
• 2019

In this article, the free vibration analysis of annular sandwich plates with various functionally graded (FG) porous cores and carbon nanotubes reinforced composite (CNTRC) facesheets is investigated based on modified couple stress theory (MCST) and first order shear deformation theories (FSDT). The annular sandwich plate is composed of two face layers and a functionally graded porous core layer which contains different porosity distributions. Various approaches such as extended mixture rule (EMR), Eshelby-Mori-Tanaka (E-M-T), and Halpin-Tsai (H-T) are used to determine the effective material properties of microcomposite circular sandwich plate. The governing equations of motion are extracted by using Hamilton's principle and FSDT. A Ritz method has been utilized to calculate the natural frequency of an annular sandwich plate. The effects of material length scale parameters, boundary conditions, aspect and inner-outer radius ratios, FG porous distributions, pore compressibility and volume fractions of CNTs are considered. The results are obtained by Ritz solutions that can be served as benchmark data to validate their numerical and analytical methods in the future work and also in solid-state physics, materials science, and micro-electro-mechanical devices.

• 한국토양비료학회지
• /
• 제40권3호
• /
• pp.189-195
• /
• 2007

Riew와 Sposito의 차원 분열 모델을 적용하여 토양과 상토를 대상으로 다공성 매체의 공극 분포와 보수력 비교를 시도하였다. 토양 시료는 라이시메터에서 2" 코아로 채취하였다. 상토 시료는 코코피트, 제올라이트 및 펄라이트를 혼합하여 아크릴 코아(100 mL)에 충진하여 조제하였다. 식 D=log(N)/log(1/r)를 포함한 차원 분열 모델에 의한 계산 Excell 프로그램을 작성하고, 이에 의해 분획된 다공성 매질을 이루는 보다 작은 크기(부피)의 매질 분획 상수인 N 값과 자기유사 비율 r 값을 얻었다. 이에 의해 대상 토양과 상토의 공극 분포와 빈도에 대한 자료를 얻을 수 있었다. 그 결과 라이시메타 토양은 상토 보다 더 넓은 공극 분포를 갖으며, 이에 비해 평균 공극크기는 상토 보다 라이시메타 토양에서 적은 것으로 해석되었다. 또한 공극크기(${\gamma}$) 분포에 따른 토양, 상토의 보수력은 토양은 상당한 단계의 토양수분이 빠져 나갔을 때 포장용수량(FC, 30kPa) 상태에 이르고, 상토는 비교적 적은 단계에서 포장용수량에 이르는 것으로 나타났다.

• Steel and Composite Structures
• /
• 제43권1호
• /
• pp.79-90
• /
• 2022

In this study, the dynamic behavior of functionally graded layered deep beams with viscoelastic core is investigated including the porosity effect. The material properties of functionally graded layers are assumed to vary continuously through thickness direction according to the power-law function. To investigate porosity effect in functionally graded layers, three different distribution models are considered. The viscoelastically cored deep beam is exposed to harmonic sinusoidal load. The composite beam is modeled based on plane stress assumption. The dynamic equations of motion of the composite beam are derived based on the Hamilton principle. Within the framework of the finite element method (FEM), 2D twelve -node plane element is exploited to discretize the space domain. The discretized finite element model is solved using the Newmark average acceleration technique. The validity of the developed procedure is demonstrated by comparing the obtained results and good agreement is detected. Parametric studies are conducted to demonstrate the applicability of the developed methodology to study and analyze the dynamic response of viscoelastically cored porous functionally graded deep beams. Effects of viscoelastic parameter, porosity parameter, graduation index on the dynamic behavior of porous functionally graded deep beams with viscoelastic core are investigated and discussed. Material damping and porosity have a significant effect on the forced vibration response under harmonic excitation force. Increasing the material viscosity parameters results in decreasing the vibrational amplitudes and increasing the vibration time period due to increasing damping effect. Obtained results are supportive for the design and manufacturing of such type of composite beam structures.

• Structural Engineering and Mechanics
• /
• 제88권1호
• /
• pp.1-12
• /
• 2023

In this study, forced vibration behavior of a piezo magneto electric sandwich Timoshenko beam is investigated. It is assumed a sandwich beam with porous core and graphene platelet reinforced composite (GPLRC) in facesheets subjected to magneto-electro-elastic and temperature-dependent material properties. The magneto electro platelets are under linear function along with the thickness that includes a cosine function and magnetic and electric constant potentials. The governing equations of motion are derived using modified strain gradient theory for microstructures. The effects of material length scale parameters, temperature change, different distributions of porous, various patterns of graphene platelets, and the core to face sheets thickness ratio on the natural frequency and excited frequency of a sandwich Timoshenko beam are scrutinized. Various size-dependent methods effects such as MSGT, MCST, and CT on the natural frequency is considered. Moreover, the final results affirm that the increase in porosity coefficient and volume fractions lead to an increase in the amount of natural frequency; while vice versa for the increment in the aspect ratio. From forced vibration analysis, it is understood that by increasing the values of volume fraction and the length thickness of GPL, the maximum deflection of a sandwich beam decreases. Also, it is concluded that increasing the temperature, the thickness of GPL, and the initial force leads to a decrease in the maximum deflection of GPL. It is also shown that resonance phenomenon occurs when the natural and excitation frequencies become equal to each other. Outcomes also reveal that the third natural frequency owns the minimum value of both deflection and frequency ratio and the first natural frequency has the maximum.

• FOCUS: LIFE SCIENCE
• /
• 제1호
• /
• pp.3.1-3.7
• /
• 2024

The article discusses the critical role of chromatography in the analysis and purification of proteins in biopharmaceuticals, emphasizing the importance of comprehensive characterization for ensuring their safety and efficacy. It highlights the use of Avantor® ACE® HPLC columns for the separation and purification of proteins, focusing on the analysis of intact proteins using reversed-phase liquid chromatography (RPLC) with fully porous particles. This article also details the application of different mobile phase additives, such as TFA and formic acid, and emphasizes the advantages of using type B ultra-pure silica-based columns for efficiency and peak shape in biomolecule analysis. Additionally, it addresses the challenges of analyzing intact proteins due to slow molecular diffusion and introduces the concept of solid-core (or superficially porous) particles, emphasizing their benefits over traditional porous particles for the analysis of therapeutic proteins. Furthermore, it discusses the development of Avantor® ACE® UltraCore BIO columns, specifically designed for the high-efficiency separation of large biomolecules, such as proteins, and demonstrates their effectiveness in achieving high-resolution separations, even for higher molecular weight proteins like monoclonal antibodies (mAbs). In addition, it underscores the complexity of analyzing and characterizing intact protein biopharmaceuticals, requiring a range of analytical techniques and the use of wide-pore stationary phases, operated at elevated temperatures and with relatively shallow gradients. It highlights the comprehensive range of options offered by Avantor® ACE® wide pore columns, including both fully porous and solid-core particles, bonded with a variety of complementary stationary phase chemistries to optimize selectivity during method development. The use of ultrapure and highly inert base silica is emphasized for enabling the use of lower concentrations of mobile phase modifiers without compromising analyte peak shape, particularly beneficial for LC-MS applications. Then the article concludes by emphasizing the significance of reversed-phase liquid chromatography and its compatibility with mass spectrometry as a valuable tool for the separation and analysis of intact proteins and their closely related variants in biopharmaceuticals.

• Advances in materials Research
• /
• 제11권4호
• /
• pp.279-298
• /
• 2022

In this paper, the important novelty and the defining a physical phenomenon of the resent research is the development of nonlocal stress and strain parameters on the porous sandwich beam with functionally graded materials in the top and bottom face sheets.Also, various beam models including Euler-Bernoulli, Reddy and the generalized formulation of two-variable beam theories are obtained in this research. According to a nonlocal strain elasticity theory, the strain at a reference point in the body is dependent not only on the stress state at that point, but also on the stress state at all of the points throughout the body. Thus, the nonlocal stress-strain elasticity theory is defined that can be actual at micro/nano scales. It can be seen that the critical buckling load and transverse deflection of sandwich beam by considering both nonlocal stress-strain parameters is higher than the nonlocal stress parameter. On the other hands, it is noted that by considering the nonlocal stress-strain parameters simultaneously becomes the actual case.

• Steel and Composite Structures
• /
• 제46권2호
• /
• pp.203-210
• /
• 2023

In the present research, dynamic deflections of a sandwich beam having functionally graded (FG) porous core have been investigated assuming that the sandwich beam is exposed to a pulse load of blast type. The two layers of sandwich beam have been made of a polymeric matrix reinforced by graphene oxide powder (GOP). The micromechanical formulation of the layers has been done via Halpin-Tsai model. The solution method is chosen to be Ritz method which is an efficient method to solve the system of equations of beams modeled based on a higher-order theory. To derive the time history of sandwich beam under pulse load, Laplace method has been used. The porosity content of the core, the GOP content of the layers, thickness of the layer and also duration of the applied load have great influences of the responses of sandwich beam.

• 한국세라믹학회지
• /
• 제41권2호
• /
• pp.176-181
• /
• 2004

지정폐기물인 전기로 제강 분진은 현재 대부분이 매립 등 부적절하게 처리되고 있어 지하수 오염 등의 환경파괴를 일으킬 위험이 있다. 전기로 제강 분진의 자원화를 위하여 전기로 제강 분진/점토의 조성으로 다공체를 제조하였으며, 다공체의 기공 특성 분석을 하였다. 다공체는 서로 다른 두 개의 미세구조로 형성되어있으며, 표면부위의 미세구조는 치밀하고 검은색이 아니고, 내부부위는 검은색이며 다공성의 미세구조(black coring)를 갖는다. 블랙코아 부위의 면적과 경량화정도를 정량화하기 위하여 Ic(core index)와 Is(shell index)를 정의하였으며, 인공경량골재로서의 최적 경량화 조건은 Ic가 0.5이상이고, Is는 0.4이상이다.

• Steel and Composite Structures
• /
• 제43권1호
• /
• pp.117-127
• /
• 2022

This study investigates the wave propagation in porous functionally graded (FG) sandwich plates subjected to hygrothermal environments. A new simple three-unknown first-ordershear deformation theory (FSDT) incorporating an integral term is utilized in this paper. Only three unknowns are used to formulate the governing differential equation by applying the Hamilton principle. The FG layer of the sandwich plate is modeled using the power-law function with evenly distributed porosities to represent the defects of the manufacturing process. The plate is subjected to nonlinear hygrothermal changes across the thickness. The effects of the power-law exponent, core to thickness ratios, porosity volume, and the relations between volume fraction and wave properties of porous FG plate under the hygrothermal environment are investigated. The results showed that the waves' phase velocities increase linearly with the waves number in the FGM plate. The porosity of the FG materials plate has a noticeable impact on the phase velocity when considering the high ratios of the core layer. It has a negligible effect on small core layers. Finally, it is observed that changing temperatures and moistures do not influence the relationship between the power law and the phase velocity.