• Title/Summary/Keyword: Porous Layer

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Printability of coating layer with nano silica sol for inkjet printing high-end photo paper (나노 실리카 졸을 이용한 잉크젯 프린팅용 고품질 인쇄용지 도공층의 인쇄적성)

  • Kim, Hye-Jin;Nahm, Sahn;Han, Kyu-Sung;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.352-358
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    • 2019
  • In recent years, printing paper with a function of information delivery and aesthetic value has attracted a great attention with increasing market demand for coated paper that is capable of high quality printing. The coated paper for inkjet printing with high-quality of photorealistic grades requires the coating layer with a good wettability and porous surface structure in order to improve the printability of ink. In this study, the coated paper was prepared using polyvinyl alcohol (PVA) and surface treated nano silica sol with silane coupling agent. It was confirmed that the coating layer with surface treated nano silica sol showed a uniform pore distribution and flat surface roughness. Glossiness of the prepared printing paper was similar to that of commercial high quality photo paper. Especially, the coated paper with surface treated nano silica sol showed improved printability with excellent roundness of the printed dot of ink. These results indicates that the coating layer with excellent wettability and uniform pore distribution can be formed by using the nano-silica particles with improved dispersibility through the surface treatment of the silane coupling agent.

Characteristics and Stability of Compositional Convection in Binary Solidification with a Constant Solidification Velocity (일정한 응고속도를 갖는 2성분 응고에서 조성 대류의 특성 및 안정성)

  • Hwang, In Gook
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.199-204
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    • 2014
  • In binary solidification compositional convection in a porous mushy layer influences the quality of the final products. We consider the mushy layer solidifying from below with a constant solidification velocity. The disturbance equations for the mushy layer are derived using linear stability theory. The basic-state temperature fields and the distribution of the porosity in the mushy layer are investigated numerically. When the superheat is large, the thickness of the mushy layer is relatively small compared to the thickness of the thermal boundary layer. With decreasing the superheat the critical Rayleigh number based on the thickness of the mushy layer increases and the mushy layer becomes stable to the compositional convection. The critical Rayleigh number obtained from the continuity conditions of temperature and heat flux at the mush-liquid interface is smaller than that from the isothermal condition at the upper boundary of the mushy layer.

Characteristics on ceramic membrane of alumina synthesized by precipitation method(I) (침전법으로 합성된 알루미나 분말을 이용한 세라믹 분리막 제조에 관한 연구(I))

  • 박신서;서규식;김철홍;신민철;이희수;엄우식;이재훈
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.113-118
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    • 1999
  • Aluminum hydrates were synthesized using $AlCl_3$.$6H_2O$as starting material by precipitation method. The phases of obtained powder were amorphous, boehmite, bayerite, nordstrandite depending on the pH of solutions. Aluminum hydrates transformed to $\alpha-Al_2O_3$via $\gamma$- $Al_2O_3$,$\delta$- $Al_2O_3$,and $\theta$-$Al_2O_3$,and particle sizes were grown by increment of heating temperature. The TEX>$\gamma$- $Al_2O_3$ powder was coated on intermediate layer of ceramic membrane by the dip-coating method, and unsupported membrane was also prepared for comparison. The supported layer showed porous structure with small grains, but the unsupported layer revealed interconnected larger grains. Grain growth is dominant in the unsupported layer than in the supported one.

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Effect of TaB2 Addition on the Oxidation Behaviors of ZrB2-SiC Based Ultra-High Temperature Ceramics

  • Lee, Seung-Jun;Kim, Do-Kyung
    • Korean Journal of Materials Research
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    • v.20 no.4
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    • pp.217-222
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    • 2010
  • Zirconium diboride (ZrB2) and mixed diboride of (Zr0.7Ta0.3)B2 containing 30 vol.% silicon carbide (SiC) composites were prepared by hot-pressing at $1800^{\circ}C$. XRD analysis identified the high crystalline metal diboride-SiC composites at $1800^{\circ}C$. The TaB2 addition to ZrB2-SiC showed a slight peak shift to a higher angle of 2-theta of ZrB2, which confirmed the presence of a homogeneous solid solution. Elastic modulus, hardness and fracture toughness were slightly increased by addition of TaB2. A volatility diagram was calculated to understand the oxidation behavior. Oxidation behavior was investigated at $1500^{\circ}C$ under ambient and low oxygen partial pressure (pO2~10-8 Pa). In an ambient environment, the TaB2 addition to the ZrB2-SiC improved the oxidation resistance over entire range of evaluated temperatures by formation of a less porous oxide layer beneath the surface SiO2. Exposure of metal boride-SiC at low pO2 resulted in active oxidation of SiC due to the high vapor pressure of SiO (g), and, as a result, it produced a porous surface layer. The depth variations of the oxidized layer were measured by SEM. In the ZrB2-SiC composite, the thickness of the reaction layer linearly increased as a function of time and showed active oxidation kinetics. The TaB2 addition to the ZrB2-SiC composite showed improved oxidation resistance with slight deviation from the linearity in depth variation.

Preparation of Asymmetric Ceramic Membrane by Coating-Pyrolysis Process (도포-열분해법을 이용한 비대칭 세라믹 분리막 제조)

  • Ryu, Hyun-Wook;Kim, Byung-Hoon
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1153-1157
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    • 2002
  • The fabrication of a three-layered asymmetric ceramic membrane was performed by slip casting of the porous alumina support and dip coating of the alumina intermediate layer using high purity ${\alpha}-Al_2O_3$ powders that have different particle size, followed by screen printing-pyrolysis of the $Tio_2$ layer as an ultrafilteration membrane using Ti-naphthenate solution. The bending strength, porosity and mean pore size of the alumina support were 231 kg/$cm^2$s, 30.26% and 0.19 ${mu}m$, respectively. The thickness of the intermediate layer was 30 ${mu}m$ and the mean pore size of that was 0.063 ${mu}m$. Also, the top layer was 0.5 ${mu}m$ thick and micropores with about 20 nm size were formed uniformly.