• Membrane and Water Treatment
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• v.10 no.3
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• pp.245-250
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• 2019

Prussian blue (PB) is well known for its excellent $Cs^+$ ions adsorption capacity. Due to the high dispersibility of PB in aqueous phase, composite materials imbedding PB in supporting materials have been introduced as a solution. However, building PB particles inside porous supporting materials is still difficult, as PB particles are not fully formed and elute out to water. In this study, we suggest layer-by-layer (LBL) assembly to provide better immobilization of PB on supporting materials of poly vinyl alcohol sponge (PVA) and cellulose filter (CF). Three different PB attachment methods, ex-situ/in-situ/LBL assembly, were evaluated using PB leaching test as well as $Cs^+$ adsorption test. Changes of surface functionality and morphology during PB composite preparation protocols were monitored through Fourier transform infrared spectroscopy and scanning electron microscopy. The results indicate that LBL assembly led to better PB attachment on supporting materials, bringing less eluting PB particles in aqueous phase compared to other synthesis methodologies, such as ex-situ and in-situ synthesis. By enhancing the stability of the adsorbent, adsorption capacity of PVA-PB with LBL improved nine times and that of CF-PB improved over 20 times. Therefore, the results suggest that LBL assembly offers a better orientation for growing PB particles on porous supporting materials.

• Journal of the Korean Ceramic Society
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• v.39 no.10
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• pp.919-927
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• 2002

In order to fabricate double-layered porous materials powders of different particle sizes were pressed stepwise. Ford＇s equation which predicts the fired density with the change in pressed density was employed in order to adjust the difference in sintering shrinkage of the green body with double-layered porous structure. Double-layered porous materials were characterized by investigating microstructures and permeability. SEM micrographs showed the distinct difference in pore sizes of double-layered porous material. Permeability of single-layered porous material increased by increasing the starting particle sizes and porosity as well. Permeability of the double-layered porous material depends largely on the layer of small pore diameter.

• Corrosion Science and Technology
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• v.5 no.4
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• pp.137-140
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• 2006

The effect of pre-existing barrier-type film on porous aluminum oxide film formation during anodization was investigated to control the uniform film growth rate. Initial potential fluctuations during anodization indicated that the breakdown of barrier-film is preceded before the porous formation and the induction time for the porous film growth increases with the increases of pre-existing film thickness. The porous film growth mechanism is lot affected by the presence of barrier film on aluminum surface. In parallel, uniform growth of barrier film underneath the porous structure was attained by two-step anodization processes.

• Journal of the Korean Ceramic Society
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• v.29 no.1
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• pp.35-40
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• 1992

Porous glass in the ZrO2-SiO2 system containing up to 30 mol% zirconia were prepared from the mixed solutions of Zr(O.nC3H7)4 and partially prehydrolyzed TEOS by the sol-gel method. Pore characteristics, physical properties and alkali resistance were investigated. The gels converted into the porous glass by heating at $700^{\circ}C$, it was found that the glass like skeleton was already made up in lower temperature regions. The specific surface area of the porous glass was 227 $m^2$/g, average mean pore size was about 19$\AA$ and porosity was 19.2%, pore characteristics and physical properties depended on heating temperature. Alkali resistance of the porous glass increased as the zirconia content increased, because of the appearance of Zr-enriched layer at glass surface.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.04a
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• pp.613-619
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• 1997

The present study has an objetive to define the characteristic of the Porous Concrete to be used in the resistant layers of the pavement. Up to the moment there is no material which is capable which is capable of satisfying the mechanical resistances and drainability, two characterstics which interves, and a detailled study has been carried out on the same order to obtain the porous concrete of this study. such as: Mode and time of compaction. type of cement, water/cement ratio, maxium size of aggregates, sieve test. incorporation of some additives and additions etc., among them emphasizing the use of a method of compaction vibro-compression in the laboratory with which an optimum compacting was reached, and can be obtanied on the site with a spreader rated with double tamper. With this porous concrete for this study whose dominating characteristics is the drainability jointly with a high mechanical resistance. a safe and silence firm is obtained, with can be a great diffusion in the near future, for its application on the pavements. Based on these works carried out, there was the first experience in the world of field application with 25cm of resistance layer of Porous Concrete Pavement in Salamanca, Spain.

• International Journal of Air-Conditioning and Refrigeration
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• v.13 no.2
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• pp.99-106
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• 2005

Falling film heat transfer has been widely used in many applications in which heat and mass transfer occur simultaneously, such as evaporative coolers, cooling towers, absorption chillers, etc. In such cases, it is desirable that the falling film spreads widely on the surface to form a thin liquid film to enlarge contact surface and to reduce the thermal resistance across the film and/or the flow resistance to the vapor stream over the film. In this respect, hydrophilic treatment of the surface has been tried to improve the surface wettability by decreasing the contact angle between the liquid and the surface. However, the hydrophilic treatment was found not very effective to increase the surface wettedness of inclined surfaces, since the liquid flow forms rivulet patterns instead of a thin film as it flows down the inclined surface and accelerates gradually by the gravity. In this work, a novel method is suggested to improve the surface wettedness enormously. In this work, the surface is treated to have a thin hydrophilic porous layer on the surface. With this treatment, the liquid can spread widely on the surface by the capillary force resulting from the porous structure. In addition to this, the liquid can be held within the porous structure to improve surface wettedness regardless of the surface inclination. The experiment on the evaporative cooling of inclined surfaces has been conducted to verify the effectiveness of the surface treatment. It is measured that the latent heat transfer increases almost by $80\%$ at the hydrophilic porous layer coated surface as compared with the untreated surface.

• Proceedings of the Membrane Society of Korea Conference
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• 2002.05a
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• pp.35-41
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• 2002

Dense oxygen ionic conducting materials can be used for oxygen separation membranes at high temperatures. However, they show relatively low permeation flux because of their large resistances. To reduce resistances and improve the oxygen permeation flux, thin dense yttria-stabilized-zirconia (YSZ)/Pd composite dual-phase membranes were fabricated by a new approach that combines the reservoir method and chemical vapor deposition (CVD). A thin porous YSZ layer was coated on a porous alumina support by dip-coating the YSZ suspension. A continuous Pd phase was formed inside pores of the YSZ layer by the reservoir method. The residual pores of the YSZ/Pd layer were plugged with yttria/zirconia by CVD to ensure the gas tightness of the membranes. The oxygen permeation fluxes through these composite membrane were 2.0$\times$10$^{-8}$ mol/cm$^2$.s and 4.8$\times$10$^{-8}$ mol/cm$^2$.s at 105$0^{\circ}C$ when air and oxygen were used as the permeate gases, respectively. These oxygen permeation values are about 1 order of magnitude higher than those of pure YSZ membranes prepared under similar conditions.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1730-1735
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• 2003

The plume-induced shock wave is a complex phenomenon, consisting of plume-induced boundary layer separation, separated shear layer, multiple shock waves, and their interactions. The knowledge base of plume interference effect on powered missiles and flight vehicles is not yet adequate to get an overall insight of the flow physics. Computational studies are performed to better understand the flow physics of the plume-induced shock and separation particularly at high plume to exit pressure ratio. Test model configurations are a simplified missile model and two rounded and porous afterbodies to simulate moderately and highly underexpanded exhaust plumes at the transonic/supersonic speeds. The result shows that the rounded afterbody and porous wall attached at the missile base can alleviate the plume-induced shock wave phenomenon, and improve the control of the missile body.

• Journal of the Korean Institute of Telematics and Electronics
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• v.24 no.4
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• pp.646-651
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• 1987

The photoconductive multilayer composed of glassy, porous, and fine-grained layers was fabdricated with Se and Sb2S3 by vacuum evaporation in order to be used as vidicon target. And its electrical, optical properties were investigatee. The fabrication conditions were as follow: the glassy layer was first deposited to have the thickness of 6500 \ulcornerat the deposition rate of 250\ulcornersec. High photosensitivity(\ulcorner=1) was obtained but its shortcoming was high dielectric constant. Therefore, the porous layer was added to lower dielectric constant and had 7500\ulcornerthick in the argon gas ambikent of 7x10-\ulcorner And the fine-grained layer was formed to prevent secondary electron emission and obtain good resolution. Its thickness was about 1700\ulcorner For the given vidicon target, the light transfer characteristic, that is, photosensitivity (\ulcorner) was measured to be 0.8 at the applied voltage of 25V. The spectral sensitivity was quite similar to that of the human eyes.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.3
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• pp.294-301
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• 2003

We examine a problem in which porous/viscoelastic compliant thin plates are subject to pressure fluctuations under transitional or turbulent boundary layer. Measurements are presented of the frequency spectra of the near-field pressure and radiated sound by compliant surface. A porous plate consisting of 5mm thick. open-cell foam with fabric covering and a viscoelastic-painted plate of 1mm thick over an acoustic board of 4mm thick were placed over a rigid surface in an anechoic wind tunnel. Streamwise velocity and wall pressure measurements were shown to highly attenuate the convective wall pressure energy when the convective wavenumber (k$_{c}$h) was 3.0 or more. The sound source localization on the compliant walls is applied to the measurement of radiated sound by using an acoustic mirror system.