• Journal of the Korean Electrochemical Society
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• v.19 no.1
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• pp.21-27
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• 2016

Vanadium redox flow batteries (VRFBs) using the electrolytes containing various vanadium ions in sulfuric acid as supporting solution are one of the energy storage devices in alternatively charging and discharging operation modes. The positive electrolyte contains $V^{5+}/V^{4+}$ and the negative electrolyte $V^{2+}/V^{3+}$ depending on the operation mode. To prevent the mixing of two solutions, proton exchange membranes are mainly used in VRFBs. Nafion 117 could be the most promising candidate due to the strong oxidative property of $V^{5+}$ ion, but causes high crossover of electroactive species to result in a decrease in coulombic efficiency. In this study, the composite membranes using Nafion ionomer and porous polyethylene substrate were prepared to keep good chemical stability and to decrease the cost of membranes, and were compared to the properties and performance of the commercially available electrolyte membrane, Nafion 117. As a result, the water uptake and ionic conductivity of the composite membranes increased as the thickness of the composite membranes increased, but those of Nafion 117 slightly decreased. The permeability of vanadium ions for the composite membranes significantly decreased compared to that for Nafion 117. In a single cell test for the composite membranes, the voltage efficiency decreased and the coulombic efficiency increased, finally resulting in the similar energy efficiency. In conclusion, the less cost of the composite membranes by decreasing 6.4 wt.% of the amount of perfluorinated sulfonic acid polymer due to the introduction of porous substrate and lower vanadium ion permeability to decrease self-discharge were achieved than Nafion 117.

• Steel and Composite Structures
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• v.21 no.5
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• pp.999-1016
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• 2016

This study presents free vibration of beam made of porous material. The mechanical properties of the beam is variable in the thickness direction and the beam is investigated in three situations: poro/nonlinear nonsymmetric distribution, poro/nonlinear symmetric distribution, and poro/monotonous distribution. First, the governing equations of porous beam are derived using principle of virtual work based on Euler-Bernoulli theory. Then, the effect of pores compressibility on natural frequencies of the beam is studied by considering clamped-clamped, clamped-free and hinged-hinged boundary conditions. Moreover, the results are compared with homogeneous beam with the same boundary conditions. Finally, the effects of poroelastic parameters such as pores compressibility, coefficients of porosity and mass on natural frequencies has been considered separately and simultaneously.

• Steel and Composite Structures
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• v.36 no.2
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• pp.179-186
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• 2020

In this paper, the forced resonance vibration of porous functionally graded (FG) curved nanobeam is examined. In order to capture the hardening and softening mechanisms of nanostructure, the nonlocal strain gradient theory is employed to build the size-dependent model. Using the Timoshenko beam theory together with the Hamilton principle, the equations of motion for the curved nanobeam are derived. Then, Navier series are used in order to obtain the dynamical deflections of the porous FG curved nanobeam with simply-supported ends. It is found that the resonance position of the nanobeam is very sensitive to the nonlocal and strain gradient parameters, material variation, porosity coefficient, as well as geometrical conditions. The results indicate that the resonance position is postponed by increasing the strain gradient parameter, while the nonlocal parameter has the opposite effect on the results. Furthermore, increasing the opening angle or length-to-thickness ratio will result in resonance position moves to lower-load frequency.

• Journal of Power System Engineering
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• v.15 no.6
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• pp.81-85
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• 2011

Because of excellent mechanical properties, such as good friction coefficient and heat resistance characteristics, PTFE parts have been widely used in the industries. However, the poor wear resistance of PTFE has been a main problem limiting wider applications. In this study, to improve the poor wear resistance of PTFE, porous PTFE composites were prepared by mixing additives(sodium bicarbonate and graphite) with PTFE powder. The friction coefficient, wear resistance and lubricating property of porous PTFE composites were measured and the results were compared with those of untreated PTFE.

• Steel and Composite Structures
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• v.35 no.4
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• pp.567-578
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• 2020

Based on third-order shear deformation shell theory, the present paper investigates post-buckling properties of eccentrically stiffened metal foam curved shells/panels having initial geometric imperfectness. Metal foam is considered as porous material with uniform and non-uniform models. The single-curve porous shell is subjected to in-plane compressive loads leading to post-critical stability in nonlinear regime. Via an analytical trend and employing Airy stress function, the nonlinear governing equations have been solved for calculating the post-buckling loads of stiffened geometrically imperfect metal foam curved shell. New findings display the emphasis of porosity distributions, geometrical imperfectness, foundation factors, stiffeners and geometrical parameters on post-buckling properties of porous curved shells/panels.

• Structural Engineering and Mechanics
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• v.71 no.1
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• pp.99-107
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• 2019

Wave propagation analysis of a porous graphene platelet reinforced (GPLR) nanocomposite shell is investigated for the first time. The homogenization of the utilized material is procured by extending the Halpin-Tsai relations for the porous nanocomposite. Both symmetric and asymmetric porosity distributions are regarded in this analysis. The equations of the shell's motion are derived according to Hamilton's principle coupled with the kinematic relations of the first-order shear deformation theory of the shells. The obtained governing equations are considered to be solved via an analytical solution which includes two longitudinal and circumferential wave numbers. The accuracy of the presented formulations is examined by comparing the results of this method with those reported by former authors. The simulations reveal a stiffness decrease in the cases which porosity influences are regarded. Also, one must pay attention to the effects of longitudinal wave number on the wave dispersion curves of the nanocomposite structure.

• Smart Structures and Systems
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• v.23 no.5
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• pp.429-447
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• 2019

The present study analyzed free vibration of the three-layered micro annular/circular plate which its core and face sheets are made of saturated porous materials and FG-CNTRCs, respectively. The structure is subjected to magneto-electric fields and magneto-electro-mechanical pre loads. Mechanical properties of the porous core and also FG-CNTRC face sheets are varied through the thickness direction. Using dynamic Hamilton's principle, the motion equations based on MCS and FSD theories are derived and solved via GDQ as an efficient numerical method. Effect of different parameters such as pores distributions, porosity coefficient, pores compressibility, CNTs distribution, elastic foundation, multi-physical pre loads, small scale parameter and aspect ratio of the plate are investigated. The findings of this study can be useful for designing smart structures such as sensor and actuator.

• Steel and Composite Structures
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• v.38 no.5
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• pp.523-531
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• 2021

The generalized thermoelastic analysis problem of a two-dimension porous medium with and without energy dissipation are obtained in the context of Green-Naghdi's (GNIII) model. The exact solutions are presented to obtain the studying fields due to the pulse heat flux that decay exponentially in the surface of porous media. By using Laplace and Fourier transform with the eigenvalues scheme, the physical quantities are analytically presented. The surface is shocked by thermal (pulse heat flux problems) and applying the traction free on its outer surfaces (mechanical boundary) through transport (diffusion) process of temperature to observe the analytical complete expression of the main physical fields. The change in volume fraction field, the variations of the displacement components, temperature and the components of stress are graphically presented. Suitable discussion and conclusions are presented.

• Steel and Composite Structures
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• v.36 no.6
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• pp.671-687
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• 2020

The aim of this research is to analyze buckling and bending behavior of a sandwich Reddy beam with porous core and composite face sheets reinforced by boron nitride nanotubes (BNNTs) and shape memory alloy (SMA) wires resting on Vlasov's foundation. To this end, first, displacement field's equations are written based on the higher-order shear deformation theory (HSDT). And also, to model the SMA wire properties, constitutive equation of Brinson is used. Then, by utilizing the principle of minimum potential energy, the governing equations are derived and also, Navier's analytical solution is applied to solve the governing equations of the sandwich beam. The effect of some important parameters such as SMA temperature, the volume fraction of SMA, the coefficient of porosity, different patterns of BNNTs and porous distributions on the behavior of buckling and bending of the sandwich beam are investigated. The obtained results show that when SMA wires are in martensite phase, the maximum deflection of the sandwich beam decreases and the critical buckling load increases significantly. Furthermore, the porosity coefficient plays an important role in the maximum deflection and the critical buckling load. It is concluded that increasing porosity coefficient, regardless of porous distribution, leads to an increase in the critical buckling load and a decrease in the maximum deflection of the sandwich beam.

• Journal of Welding and Joining
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• v.10 no.4
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• pp.213-221
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• 1992

Al$_{2}$O$_{3}$ ceramic coating layer by gas flame spraying was very porous, therefore it could not have wear and corrosion resistance at all. To get a dense and strong coating layer, a method to infiltrate an alloy into the pores of $Al_{2}$O$_{3}$ ceramic coating was investigated. Cu-Ti alloys, which had good wettability and reactivity with $Al_{2}$O$_{3}$ ceramic, were examined for infiltration. Infiltration of the alloys was performed in vacuum at 1100.deg.C. The melt of Cu-50 at % Ti alloy was well penetrated through the porous $Al_{2}$O$_{3}$ coating and tightly sealed the pores, unbounded area and microcracks in the coating. The alloy melt in the pores reacted with $Al_{2}$O$_{3}$ ceramic to produce a suboxide phase, Cu$_{2}$Ti$_{4}$O. This composite layer which was composed of $Al_{2}$O$_{3}$ and Cu$_{2}$Ti$_{4}$O phase had good microstructure and wear and corrosion resistance. Additionally, microstructures at interfaces between coating layers were greatly improved owing to the effect of vacuum heat treating.