• Title/Summary/Keyword: Porosity change

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Mechanistic Model of Dryout in a Heat-Generating Porous Medium

  • Kim, Seong-Ho;Chang, Soon-Heung
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.537-542
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    • 1996
  • In the present work the influence of various physical parameters on the two-phase flow behavior in a self-heated porous medium has been studied using a numerical model, that is, the effects of heat generation rate, of porosity, of particle size, and of system pressure on the dryout process. To analyze the effect of these parameters, the variation of both liquid volumetric fraction and liquid axial velocity is evaluated at the steady state or at the onset of a first boiled-out region. The analysis of computational results indicate that a qualitative tendency exists between the parameters such as heat generation rate, porosity, effective particle diameter and the temporal development of the liquid volumetric fraction field up to dryout. In addition to these parameters, a variation of fluid properties such as phase density, phase viscosity due to a change of system pressure can be used for gaining insight into the nature of two-phase flow behavior up to dryout.

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The Preparation of Porous Silica Glass by the Sol-Gel Method -Change of Properties of Gel by Addition of Fromamide- (졸-겔법에 의한 다공질 실리카 유리의 제조에 관한 연구 -Formamide 첨가에 의한 겔의 성질 변화-)

  • 서정민;신대용;최성일;한상목
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.169-174
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    • 1993
  • The porous silica glass prepared by the sol-gel method from the mixed solution of Si(OCH3)4, H2O, HCl and CH3OH with HCONH2 as a DCCA (Drying Control Chemical Additives). For investigation the characteristics of gels and glasses, we examined gels and glasses using TG-DTA, XRD, IR, SEM and porosimeter. The more content of formamide in the mixed solution increased, the more pore size and porosity of gel increased. In the excess formamide added gel, the properties of pore of gel were not so changed. The porous silica glass was prepared from the dry gel after heat treatment at 75$0^{\circ}C$. Porosity and mean pore size of the porous silica glass was 17~25% and 40~60$\AA$ relatively.

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Fixed-Grid Simulation of Convection-Dominated Melting in a Rectangular Cavity

  • Wongee Chun;Kim, Sin;Kim, Min-Chan
    • Journal of Mechanical Science and Technology
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    • v.15 no.6
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    • pp.796-803
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    • 2001
  • Numerical solutions for the convection-dominated melting in a rectangular cavity are presented. The enthalpy-porosity model is employed as the mathematical model. This model is applied in conjunction with the EIT method to detect boundary movement in a phase changing environment. The absorption and evolution of latent heat during the phase change is dealt with by the enthalpy-based energy equation. This seems to be more efficient than resolving the temperature-based energy equation. The velocity switch-off, which is required when solid changes into liquid, is modeled by the porous medium assumption. For efficiency and simplicity of the solutions procedure, this paper proposes a simple algorithm, which iterates the temperature and the liquid fraction of the cells comprising the front layer. The numerical results agree reasonably well with the experimental data and other previous works using the transformed-grid system.

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Phase Transition and Thermal Expansion Behavior of Zirconia Setter Fabricated from Fused CaO Stabilized Zirconia

  • Park, Ji-Hoon;Bang, Il-Hwan;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.56 no.2
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    • pp.184-190
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    • 2019
  • To improve resistance in thermal shock of zirconia setter which is frequently and repeatedly exposed to high temperature, high degree of porosity and control of thermal expansion are needed for which the fused CSZ (CaO stabilized zirconia) is used to produce the zirconia setter. In the present study, the effects of sintering temperature, cool down condition, addition of CaO stabilizer, and addition of other additives on phase transition and thermal expansion behavior of the fabrication process of zirconia setter, were examined. The zirconia setter, fabricated with fused CSZ at 1550℃, exhibited 20.4 MPa of flexural strength, 6.8% of absorbance, and 27.9% of apparent porosity. The rapid change in thermal expansion of zirconia setter is observed at temperature around 800℃, and it was reduced by low firing temperature, slowed cooled down, and addition of CaO.

Size Effects of the Catalyst on Characteristics of Zn/Air Batteries (MnO2입자 크기에 따른 아연공기전지의 특성연구)

  • 김지훈;엄승욱;문성인;윤문수;김주용;박정식;박정후
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12
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    • pp.1150-1154
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    • 2003
  • The voltage profile during discharge of the zinc air battery has very flat pattern until reach to end of discharge voltage. But, when zinc air battery is discharged by high current, the discharge voltage and energy becomes low. Therefore, we focused on effects of catalyst size to solve this problems by increasing active sites of oxygen reduction reaction. The size of catalyst was reduced from 27 to l${\mu}{\textrm}{m}$ and we examined average discharge voltage, capacity, energy, resistance and characteristics during GSM pulse discharge of zinc air battery with change of current density. And we also measured porosity of the cathode according to the ASTM. So we have got improvement of average discharge voltage and energy when catalyst was minimized and we have got optimum size of catalyst at 5${\mu}{\textrm}{m}$.

The Effect of Some Physical Parameters on Saturation and Velocity Profiles in a Porous Medium

  • Ghyym S. H.
    • 한국전산유체공학회:학술대회논문집
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    • 1997.10a
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    • pp.120-125
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    • 1997
  • In the present work the influence of various physical parameters on the two-phase flow behavior in a self-heated porous medium has been studied using a numerical model, that is, the effects of heat generation rate, of porosity, of particle size, and of system pressure on the dryout process. To analyze the effect of these parameters, the variation of both liquid volumetric fraction (i.e., liquid saturation) and liquid axial velocity is evaluated at the steady state or at the onset of a first boiled-out region. The analysis of computational results indicate that a qualitative tendency exists between the parameters such as heat generation rate, porosity, effective particle diameter and the temporal development of the liquid volumetric fraction field up to dryout. In addition to these parameters, a variation of fluid properties such as phase density, phase viscosity due to a change of system pressure can be used for gaining insight into the nature of two-phase flow behavior up to dryout.

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Formation of Microporosities in Sputter-Deposited AgInSbTe Thin Films and Their Behavior (스퍼터 증착시킨 AgInSbTe 박막에서 미세기공의 형성과 그 거동)

  • Kim, Myong-R.;Seo, H.;Park, J. W.;Choi, W. S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.84-89
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    • 1996
  • The nucleation and growth of microporosities was observed during the course of annealing treatment of sputter-deposited AgInSbTe thin films. There was a close correlation between the density of microporosity and the sputtering gas pressure in annealed thin films. The void density for a given composition decreased with sputtering gas pressure. It was shown from the present study that the number of porosities decreased while the average porosity size increased as the annealing temperature and holding time increased. The mechanism of porosity formation in the sputter-deposited AgInSbTe thin flus containing Ar-impurity trapped from the Ar-plasma is discussed in the present article.

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The Effect of Pressure on Liquid Segregation in Direct Rheo-Forging Process of Aluminum Alloys (알루미늄 소재의 레오로지 직접단조공정에서 가압력이 액상 편석에 미치는 영향)

  • Oh, S.W.;Bae, J.W.;Kang, C.G.
    • Transactions of Materials Processing
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    • v.16 no.3 s.93
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    • pp.178-186
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    • 2007
  • Rheo-forging process of aluminum alloy is suitable for large parts of net shape without defects and excellent mechanical properties in comparison with conventional die casting and forging process. To control the microstructure of the product with high mechanical properties in rheo-forming, solid fraction is required to prevent porosity and liquid segregation. Therefore, in rheo-forging process, die shape, pressure type and solid fraction are very important parameters. The defects such as porosity, liquid segregation and unfitting phenomena occur during rheo-forging process. To prevent these defects, mechanical properties and microstructure analysis of samples versus the change of pressure are carried out and the problem and its solutions are proposed. Also, the mechanical properties versus various pressures were compared with and without heat treatment. The alloys used for rheo-forming are A356 and 2024 aluminum alloy. The rheology material is fabricated by electromagnetic process with controlling current and stirring time.

Application of hyperbolic shear deformation theory to free vibration analysis of functionally graded porous plate with piezoelectric face-sheets

  • Arefi, M.;Meskini, M.
    • Structural Engineering and Mechanics
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    • v.71 no.5
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    • pp.459-467
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    • 2019
  • In this paper, hyperbolic shear deformation theory is used for free vibration analysis of piezoelectric rectangular plate made of porous core. Various types of porosity distributions for the porous material is used. To obtain governing equations of motion, Hamilton's principle is used. The Navier's method is used to obtain numerical results of the problem in terms of significant parameters. One can conclude that free vibration responses are changed significantly with change of important parameters such as various porosities and dimensionless geometric parameters such as thickness to side length ratio and ratio of side lengths.

Changes in Cement Hydrate Characteristics and Chloride Diffusivity in High Performance Concrete with Ages (재령에 따른 고성능 콘크리트의 수화 특성치와 염화물 확산성 변화)

  • Koh, Tae-Ho;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.6
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    • pp.9-17
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    • 2019
  • Cement hydrates and the related characteristics change with ages, and the behaviors are much related with chloride diffusion. In this work, 30% replacement ratio with FA(Fly Ash) and GGBFS(Ground Granulated Blast Furnace Slag) are considered for concrete with three levels of W/B (Water to Binder ratio) and 2 years of curing period. Chloride diffusion coefficients from accelerated condition are obtained at 5 measurement period (28days, 56days, 180days, 365days, and 730days), and the results are compared with porosity, binding capacity, and permeability from program-DUCOM. The similar changing pattern between chloride diffusion and permeability is observed since permeability is proportional to the square of porosity. Curing period is grouped into 4 periods and the changing ratios are investigated. Cement hydrate characteristics such as porosity, permeability, and diffusion coefficient are dominantly changed at the early ages (28~56 days), and diffusion coefficient in OPC concrete with low W/B continuously changes to 180days.