• Analytical Science and Technology
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• v.36 no.5
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• pp.236-249
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• 2023

Carbon dioxide (CO₂) capture and storage is a critical issue for mitigating climate change. Porous aromatic Schiff base complexes have emerged as a promising class of materials for CO₂ capture due to their high surface area, porosity, and stability. In this study, we investigate the potential of Schiff base complexes as an effective media for CO₂ storage. We review the synthesis and characterization of porous aromatic Schiff bases materials complexes and examine their CO₂ sorption properties. We find that Schiff base complexes exhibit high CO₂ adsorption capacity and selectivity, making them a promising candidate for use in carbon capture applications. Moreover, we investigate the effect of various parameters such as temperature, and pressure on the CO₂ adsorption properties of Schiff base complexes. The Schiff bases possessed tiny Brunauer-Emmett-Teller surface areas (4.7-19.4 m²/g), typical pore diameters of 12.8-29.43 nm, and pore volumes ranging from 0.02-0.073 cm³/g. Overall, our results suggest that synthesized complexes have great potential as an effective media for CO₂ storage, which could significantly reduce greenhouse gas emissions and contribute to mitigating climate change. The study provides valuable insights into the design of novel materials for CO₂ capture and storage, which is a critical area of research for achieving a sustainable future.

• Journal of Hydrogen and New Energy
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• v.22 no.3
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• pp.386-401
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• 2011

Mathematical models for various steps in coal gasification reactions were developed and applied to investigate the effects of operation parameters on dynamic behavior of gasification process. Chemical reactions considered in these models were pyrolysis, volatile combustion, water shift reaction, steam-methane reformation, and char gasification. Kinetics of heterogeneous reactions between char and gaseous agents was based on Random pore model. Momentum balance and Stokes' law were used to estimate the residence time of solid particles (char) in an up-flow reactor. The effects of operation parameters on syngas composition, reaction temperature, carbon conversion were verified. Parameters considered here for this purpose were $O_2$-to-coal mass ratio, pressure of reactor, composition of coal, diameter of char particle. On the basis of these parametric studies some quantitative parameter-response relationships were established from both dynamic and steady-state point of view. Without depending on steady state approximation, the present model can describe both transient and long-time limit behavior of the gasification system and accordingly serve as a proto-type dynamic simulator of coal gasification process. Incorporation of heat transfer through heterogenous boundaries, slag formation and steam generation is under progress and additional refinement of mathematical models to reflect the actual design of commercial gasifiers will be made in the near futureK.

• Geotechnical Engineering
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• v.14 no.1
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• pp.81-92
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• 1998

Coal ash from thermal power plants has been produced in large quantity and discarded uselessly, However, it is possible to supply construction material properly by utilizing the coal ash as construction material. In this study, the applicable model and its applicability for deformation analysis of coal ash fill and reclamation ground are studied. Camflay model gives complete constitutive law which illustrates deformation and pore water pressure while soil is loaded under the various stresses at drained and undrained conditions. The merit of proposed model which is acquired from laboratory tests is that only a few soil parameters are available. The whole parameters of Camflay model are obtained by typical mechanical test and CV triaxial test on the sample with optimum mixing ratio( i.e. fly ash : bottom ash=5:5) Then the results from proposed numerical analysis are compared with laboratory results. The differences between laboratory test and numerical analysis are negligible. Parameters deter mined from laboratory tests are useful as a basic data for deformation analysis of coal ash reclamation ground using Camflay model.

• Proceedings of the Korean Geotechical Society Conference
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• 1991.10a
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• pp.87-102
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• 1991

It has been reported that the failure of Carsington Dam in Eng1and occured due to the existence of a thin yellow clay layer which was not identified during the design work, and due to pre-existing shears of the clay layer. The slope stability analyses during the design work, which utilized traditional circular arc type failure method and neglected the existence of the clay layer, showed a safety factor of 1.4. However, the post-failure analyses which utilized translational failure mode considering the clay layer and the pre-existing shear deformation revealed the reduction of safety factor to unity. The post-failure analysis assumed 10。 inclination of the horizontal forces onto each slice based on the results of finite element analyses. In this paper, Bishop's simplified method, Janbu method, and Morgenstern-Price method were used for the comparison of both circular and translational failure analysis methods. The effects of the pre-existing shears and subsquent movement were also considered by varying the soil strength parameters and the pore pressure ratio according to the given soi1 parameters. The results showed factor of safefy 1.387 by Bishop's simplified method(STABL) which assumed circular arc failure surface and disregarding yellow clay layer and pre-failure material properties. Also the results showed factor of safety 1.093 by Janbu method(STABL) and 0.969 by Morgenstern-Price method(MALE) which assumed wedge failure surface and considerd yellow clay layer using post failure material properties. In addition, dam behavior was simulated by Cam-Clay model FEM program. The effects of pore pressure changes with loading and consolidation, and strength reduction near or at failure were also considered based on properly assumed stress-strain relationship and pore pressure characteristics. The results showed that the failure was initiated at the yellow clay layer and propagated through other zones by showing that stress and displacement were concentrated at the yel1ow clay layer.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.7 no.6
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• pp.39-48
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• 2004

The purpose of this paper was to confirm the application of the equation of the soil-water characteristic curve on an unsaturated soil. To this ends, a series of suction test was conducted on the selected 4 kinds of soil which is located in Korea, using the modified pressure extractor apparatus. And it was carried out to analyze the experimental parameters which can describe the soil-water characteristics, were determined by using the data obtained from the experiment. From the results, it was found that the matric suction was varied according to the grain size distribution, amount of fine grain particle and void ratio. Also it was found that the residual volumetric water content was decreased with the void ratio, but the index related air entry value, the soil parameter related water content and the parameter with residual water content were increased with the void ratio. And the application of equation of the soil-water characteristic curve was confirmed for the various conditions and the various state by the comparison between the volumetric water content measured by the experiment and the predicted values.

• Tunnel and Underground Space
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• v.7 no.1
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• pp.39-50
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• 1997

Reference concepts for the disposal of spent nuclear fuel and the current status of underground rock laboratory were studied. An analysis to simulate the deep disposal of spent nuclear fuel in saturated rock mass was conducted. Main input parameters for numerical study were determined based on the KBS-3 concept. A series of results showed that the temperature distribution around a cavern reached the maximum value at about 10 years after the emplacement of spent fuel. The maximum temperature at the surface of canister was more than about 12$0^{\circ}C$ at about 4 years. This temperature was not much higher than the temperature criteria to meet the performance criteria of an artificial barrier in the KBS-3 concept. The maximum upward displacement due to the heat generation of spent fuel was about 0.9cm at about 10 years after the emplacement of spent fuel. It turned out that the vertical displacement became smaller with the decrease in heat generation of a canister. The quantity of groundwater inflow into a disposal tunnel increased by about 1.6 times at 20 years after the emplacement of spent fuel with the increase of pore pressure around a cavern.

• Geotechnical Engineering
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• v.12 no.4
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• pp.101-114
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• 1996

In this study, the characteristics of bearing capacity and deformation of intermediate soils are investigated through centrifuge tests. The experimental parameters are footing width, initial stress condition of soils and relative loading rate defined relationship of loading rate and permeability of soils. It is examined that loading rate influences on the bearing capacities and deformations. Based on the test results, some problem of existing specification are introduced in the view of related loading rates and load intensities. Especially it is showed that load intensities magnitude rlre reversed in the same settlement ratio(s/B(%)), due to partial drained effect as well as loading rates in undrained con dition based on the excess pore pressure and deformations measured under loading.

• Journal of the Korean Geotechnical Society
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• v.20 no.8
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• pp.123-133
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• 2004

The magnitudes of wall thrust acting on quay walls can easily vary due to the development of excess pore pressure in backfill. In this research, a new displacement model was proposed to predict the displacement of the wall considering such magnitude variations of the wall thrust. This model is based on Newmark sliding block concept. The magnitude variation of the wall thrust is modelled by varying the magnitude of yield acceleration. The parametric study was performed to analyze the effects of input parameters on the seismic displacement of the wall, and the validity of this model was verified by comparing its predicted displacements with those of Is shaking table tests.

• Geomechanics and Engineering
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• v.34 no.6
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• pp.665-681
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• 2023

Liquefaction is one of the most devastating geotechnical phenomena that severely damage vital structures and lifelines. Before constructing structures on problematic ground, it is necessary to improve the site and solve the geotechnical problem. Among ground improvement methods dealing with liquefaction, gravel drain (GD) columns and deep soil mixing (DSM) columns are popular. In this study, the results of a series of seismic experiments in a 1g environment on a structure located over liquefiable ground with different thicknesses reinforced with GD and DSM techniques were presented. The dynamic response of the reinforced ground system was investigated based on the parameters of subsidence rate, excess pore water pressure ratio, and maximum acceleration. The time history of the input acceleration was applied harmonically with an acceleration range of 0.2g and at frequencies of 1, 2, and 3 Hz. The results show that the thickness of the liquefiable layer and the frequency of the input motion have a significant impact on the effectiveness of the improvement method and all responses. Among the two techniques used, DSM in thick liquefied layers was much more efficient than GD in controlling the subsidence and rupture of the soil under the foundation. Maximum settlement values, settlement rate, and foundation rotation in the thicker liquefied layer at the 1-Hz input frequency were higher than at other frequencies. At low thicknesses, the dynamic behavior of the GD was closer to that of the DSM.

• Journal of the Korean Geotechnical Society
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• v.15 no.2
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• pp.129-138
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• 1999

This study is performed for the development of a field monitoring and test technique both of self-weight and hydraulic consolidation by which the soil parameters of dredge-reclaimed clay can be obtained effectively. The field monitoring development and tests mentioned above make it possible to reproduce the process of the self-weight consolidation from settling to reclaimed soft ground. The experimental research is mainly focussed on the characteristics of self-weight consolidation of dredged clayey soil. And theoretical study has pointed out the limits in the application of Terzaghi's one dimensional consolidation theory in interpreting reclaimed clayey ground. Furthermore, a finite difference analysis has been made on the basis of Mikasa s self-weight consolidation theory which takes the problems of Terzaghi's theory into consideration. The relationships between specific volume, effective stress, and the coefficient of permeability of Kunsan reclaimed clayey soil have been obtained by laboratory tests. On the other hand, through the field monitoring, pore pressure, total pressure, and water levels have been measured after pouring. The results of these experiments have been analyzed, and compared with those from Terzaghi's method and the finite difference analysis of Mikasa's self-weight consolidation theory. In conclusion, the measured settlements is comparatively consistent with Mikasa's self-weight consolidation theory rather than Terzaghi's consolidation theory.