• Title/Summary/Keyword: Pore density

Search Result 601, Processing Time 0.041 seconds

Structural and Optical Properties of Porous Silicon Prepared by Electrochemical Etching

  • Lee, Jeong-Seok;Cho, Nam-Hee
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.2
    • /
    • pp.109-112
    • /
    • 2002
  • The structural and optical features of Porous Silicon(PS) were investigated; the porous silicon was prepared by electrochemical etching of silicon wafers in HF solution. The morphologies and Photoluminescece(PL) features of the PS were investigated in terms of etching time, current density and aging conditions. The average pore diameter and pore depth were determined by current density and etching time, respectively. As-prepared PS exhibited the maximum PL peak at the wavelength of ∼ 450 nm. The degree of deviation from as-prepared PS during aging treatment seemed to depend on the microstructure as well as morphology of the PS. It is found that etching current density played an important role on the microstructural features of the PS.

Synthesis of New Black Pigment; Carbon Black Pigment Capsulated into the Meso-pore of Silica as Black Pigment in Cosmetic (새로운 Black Color의 합성;화장품에서 블랙 색소로서 Meso-pore Silca에 캡슐레이션된 Carbon-black Silica)

  • Hye-in, Jang;Kyung-chul, Lee;Hee-chang , Ryoo
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.30 no.2
    • /
    • pp.189-195
    • /
    • 2004
  • Carbon black have not been used as pigment material in cosmetic because of very low density and dispersity, but carbon black have applicable character as black pigment because of non-toxic, stable physico-chemical property, and black colority. In this study, mesoporous silica samples were synthesized by sol-gel reaction using surfactants-template method; TEOS (tetraethoxysilane) - a) PEO/lecithin, b) PEO/polyethylene glycol, c) lecithin/polyethylene glycol in ethanol/water solution. Synthesized organic-inorganic hybrid - silica were heat-treated in N2 condition at 500$^{\circ}C$. Mesoporous silica with black carbon in pore have the effective density and show the good dispersity in both hydrophilic and hydrophobic solvent. Properties of the samples were measured; specific surface area (750㎡/g) and pore size (4-6nm) using BET, pore structure (cylindrical type) using XRD, morphology (spherical powder with 0.1-0.5$\mu\textrm{m}$ partical size) of the samples using SEM. Carbon-silica black color applied to mascara, it shows a dark black colority and good dispersity as compared with the general black color titania pigment. Moreover, it is possible to control the density of black color pigment because it is possible to control pore volume and particle size of mesoporous silica properly. It show the good volume effects in mascara. That is why possible to apply all kinds of cosmetic products.

Active Exchange of Water and Nutrients between Seawater and Shallow Pore Water in Intertidal Sandflats

  • Hwang, Dong-Woon;Kim, Gue-Buem;Yang, Han-Soeb
    • Ocean Science Journal
    • /
    • v.43 no.4
    • /
    • pp.223-232
    • /
    • 2008
  • In order to determine the temporal and spatial variations of nutrient profiles in the shallow pore water columns (upper 30 cm depth) of intertidal sandflats, we measured the salinity and nutrient concentrations in pore water and seawater at various coastal environments along the southern coast of Korea. In the intertidal zone, salinity and nutrient concentrations in pore water showed marked vertical changes with depth, owing to the active exchange between the pore water and overlying seawater, while they are temporally more stable and vertically constant in the sublittoral zone. In some cases, the advective flow of fresh groundwater caused strong vertical gradients of salinity and nutrients in the upper 10 cm depth of surface sediments, indicating the active mixing of the fresher groundwater with overlying seawater. Such upper pore water column profiles clearly signified the temporal fluctuation of lower-salinity and higher-Si seawater intrusion into pore water in an intertidal sandflat near the mouth of an estuary. We also observed a semimonthly fluctuation of pore water nutrients due to spring-neap tide associated recirculation of seawater through the upper sediments. Our study shows that the exchange of water and nutrients between shallow pore water and overlying seawater is most active in the upper 20 cm layer of intertidal sandflats, due to physical forces such as tides, wave set-up, and density-thermal gradient.

Increased Osteoblast Adhesion Densities on High Surface Roughness and on High Density of Pores in NiTi Surfaces

  • Im, Yeon-Min;Gang, Dong-U;Kim, Yeon-Uk;Nam, Tae-Hyeon
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2009.11a
    • /
    • pp.39.1-39.1
    • /
    • 2009
  • NiTi alloy is widely used innumerous biomedical applications (orthodontics, cardiovascular, orthopaedics, etc.) for its distinctive thermomechanical and mechanical properties such as shape memory effect, super elasticity, low elastic modulus and high damping capacity. However, NiTi alloy is still a controversial biomaterial because of its high Ni content which can trigger the risk of allergy and adverse reactions when Ni ion releases into the human body. In order to improve the corrosion resistance of the TiNi alloy and suppress the release of Ni ions, many surface modification techniques have been employed in previous literature such as thermal oxidation, laser surface treatment, sol-gel method, anodic oxidation and electrochemical methods. In this paper, the NiTi was electrochemically etched in various electrolytes to modify surface. The microstructure, element distribution, phase composition and roughness of the surface were investigatedby scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry(EDS), X-ray diffractometry (XRD) and atomic force microscopy (AFM). Systematic controlling of nano and submicron surface features was achieved by altered density of hydro fluidic acid in etchant solution. Nanoscale surface topography, such as, pore density, pore width, pore height, surface roughness and surface tension were extensively analyzed as systematical variables.Importantly, bone forming cell, osteoblast adhesion was increased in high density of hydro fluidic treated surface structures, i.e., in greater nanoscale surface roughness and in high surface areas through increasing pore densities.All results delineate the importance of surface topography parameter (pores) inNiTi to increase the biocompatibility of NiTi in identical chemistry which is crucial factor for determining biomaterials.

  • PDF

Pore Distribution of Porous Silicon layer by Anodization Process

  • Lee, Ki-Yong;Chung, Won-Yong;Kim, Do-Hyun
    • Proceedings of the Korea Association of Crystal Growth Conference
    • /
    • 1996.06a
    • /
    • pp.494-496
    • /
    • 1996
  • The purpose of this study is to investigate the effect of process conditions on pore distribution in porous silicon layer prepared by electrochemical reaction. Porous silicon layers formed on p-type silicon wafer show the network structure of fine porse whose diameters are less than 100${\AA}$. In n-type porous silicon, selective growth was found on the pore surface by wet etching process after PR patterning. And numerical method showed high current density on the pore tip. With this result we confirmed that pore formation has two steps. First step is the initial attack on the surface and second step is the directional growth on the pore tip.

  • PDF

Effect of raw materials of the papermaking and physical treatment on the pore structure and properties of the paper (주요제지원료의 특성 및 고해가 종이의 pore structure 및 물성에 미치는 영향)

  • Nam, Ki-Young;Chung, Soon-Ki;Won, Jong-Myoung
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2007.11a
    • /
    • pp.127-134
    • /
    • 2007
  • Paper is composed network of fibers. Since paper is plain, most cases paper is considered two-dimensional. But network of fibers creates a network of pores, and pores between fibers are most important part of the paper structure. So we have to make an approach to the paper by three-dimensionally. Pore structure in the Z-direction of the paper can affect directly not only basic properties od the paper such as density, porosity, opacity and strength but also coverage of the coating colors during coatong and printing properties. We studied effect of raw materials of the papermaking and physical treatment on the pore structure and properties of the paper.

  • PDF

A study on the pore size control of nano template by anodic aluminum oxidation (양극산화를 이용한 나노템플레이트 기공 크기 제어에 관한 연구)

  • Lee, Su-Ho;Seo, Mun-Su;Yoo, Hyun-Min;Lee, Jae-Hyeong;Joung, Yeun-Ho;Lim, Dong-Gun;Hwang, Hyeon-Seok
    • Proceedings of the KIEE Conference
    • /
    • 2011.07a
    • /
    • pp.1495-1496
    • /
    • 2011
  • Anodic aluminum oxide (AAO) nanotemplates for nano electronic device applications have been attracting increasing interest because of ease of fabrication, low cost process, and possible fabrication in large area. The size and density of the nanostructured materials can be controlled by changing the pore diameter and the pole density of AAO nanotemplate. In this paper, AAO nanotemplate was fabricated by second anodization method. In addition, effects of electrolyte and anodization voltate on the microstructure of porous alumina films were investigated. Vertically well aligned pores had the average pore sizes of 15-70 nm and the length of approximately 40 ${\mu}m$.

  • PDF

Heat Transfer from a Porous Heat Sink by Air Jet Impingement (충돌공기제트에서의 다공성 방열기의 열전달 특성)

  • 백진욱;김서영;강병하
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.13 no.2
    • /
    • pp.73-79
    • /
    • 2001
  • Experiment were carried out to investigate the heat transfer characteristics of an aluminum foam block as a porous heat sink on a heat source by a vertical air jet impingement that can be applied for electronics cooling. The performance of the aluminum foam heat sink was evaluated by the convective heat transfer coefficient on the heat source. At a fixed porosity, pore density ($\beta$) of the foam and Reynolds number Re were varied in the range of $\beta$a=10, 20, 40 PPI(Pore Per Inch) and $850\leqRe\leq25000$. A nozzle diameter and the nozzle-to-plate spacing were also varied. It was found that the convective heat transfer was enhanced by the aluminum foam heat sink with lower pore density due to relatively intensified flow through the foam block. The aluminum foam block with much reduced weight shows slightly better performance with larger Nusselt number, compared with the convectional heat sink.

  • PDF

Effect of Binder on the Sintering Characteristics of PZT Ceramics (Binder가 PZT계 세라믹스의 소결특성에 미치는 영향)

  • 정우환;김정주;조상희
    • Journal of the Korean Ceramic Society
    • /
    • v.25 no.4
    • /
    • pp.385-389
    • /
    • 1988
  • Effects of binder addition on the porosity, pore size and grain size of PZT ceramics were investigated. The binders were used PVA, PEG and MC, they were added separately and simultaneously. After sintering for 90 min 125$0^{\circ}C$, the porosity and the pore size were determined by using an image processing method. Simultaneous addition of two different binders resulted in the highest sintered density and the large pore size.

  • PDF