• Title/Summary/Keyword: Pore density

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Pore Characteristics of Porous Alumina Ceramics Fabricated from Boehmite Hydrosol and Alumina Particles (Boehmite 수화졸의 알루미나로 제조한 다공성 알루미나 세라믹스의 기공특성)

  • 오경영
    • Journal of the Korean Ceramic Society
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    • v.33 no.5
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    • pp.547-555
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    • 1996
  • Porous alumina ceramics were fabricated by pseudo-boehmite phydosol-gel process within/without commercial $\alpha$-alumina particles average 1 and 40 micron respectively. The pore characteristics of fired specimens were studied by the measurement of bulk density total porosity thyermal analysis pore volume pore distribution BET area XRD and SEM. with increasing of firing temperature pore volume and BET surface area were decreased and the average pore size was increased to approximately 146$\AA$ upto 80$0^{\circ}C$ by de-watering of [OH] and formation of $\alpha$-alumina. The fired relative density of the alumina-dispersed specimen with average 1 micron particle was increased with the amounts of dispersed particle by bimodal packing theory which is compared to the ones of specimen including of average 40 micron particle. It was confirmed that the percola-tion threshold in porous ceramics with coarser particle (40 micron) has formed between the transformed-alumina from hydrogel and dispersed-alumina of above 50 vol% particle and the total porosity was increased at the threshold point above.

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Prediction of terminal density through a two-surface plasticity model

  • Won, Jongmuk;Kim, Jongchan;Park, Junghee
    • Geomechanics and Engineering
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    • v.23 no.5
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    • pp.493-502
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    • 2020
  • The prediction of soil response under repetitive mechanical loadings remains challenging in geotechnical engineering applications. Modeling the cyclic soil response requires a robust model validation with an experimental dataset. This study proposes a unique method adopting linearity of model constant with the number of cycles. The model allows the prediction of the terminal density of sediments when subjected to repetitive changes in pore-fluid pressure based on the two-surface plasticity. Model simulations are analyzed in combination with an experimental dataset of sandy sediments when subjected to repetitive changes in pore fluid pressure under constant deviatoric stress conditions. The results show that the modified plastic moduli in the two-surface plasticity model appear to be critical for determining the terminal density. The methodology introduced in this study is expected to contribute to the prediction of the terminal density and the evolution of shear strain at given repetitive loading conditions.

Gas Permeation Characteristics of Porous Alumina Membrane Prepared by Anodic Oxidation (양극산화에 의한 다공성 알루미나 막의 기체투과 특성)

  • 함영민
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.72-78
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    • 1998
  • For investigation into gas permeation characteristics, the porous alumina membrane with asymmetrical structure, having upper layer with 10 nanometer under of pore diameter and lower layer with 36 nanometer of pore diameter, was prepared by anodic oxidation using DC power supply of constant current mode in an aqueous solution of sulfuric acid. The aluminium plate was pre-treated with thermal oxidation, chemical polishing and electrochemical polishing before anodic oxidation. Because the pore size depended upon the electrolyte, electrolyte concentration, temperature, current density, and so on, the the membranes were prepared by controling the current density, as a very low current density for upper layer of membrane and a high current density for lower layer of membrane. By control of current quantity, the thicknesses of upper layer of membranes were about $6{\;}{\mu}m$ and the total thicknesses of membranes were about $80-90{\;}{\mu}m$. We found that the mechanism of gas permeation depended on model of the Knudsen flow for the membrane prepared at each condition.

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Pore Filling Theory of Liquid Phase Sintering and Microstrcture Evolution (액상소결의 기공채움 이론과 미세구조 발달)

  • 이성민
    • Journal of Powder Materials
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    • v.6 no.1
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    • pp.81-87
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    • 1999
  • Based on the pore filling theory, the microstructure evolution during liquid-phase sintering has been analyzed in terms of interrelationship between average grain size and relative density. For constant liquid volume fraction, the microsturucture trajectories reduced to a single curve in a grain size(x)-density(y) map, regardless of grain growth constant. The slope of curves in the map was inversely proportional to average pore size, while it increased fapidly with liquid volume fraction. Increase in pore volume fraction retarded the densification considerably, but showed marginal effect on the slope. The activation energy of densification was predicted to be the same as that of grain growth as long as the liquid volume fraction is constant for any temperature range studied. The present analyses on microstricture evolution may demonstrate the usefulness of pore filling theory and provide a guideline for process optimization of liquid-phase sintering.

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The Effect of MgO Content on the Preparation of Porous Hydroxyapaite Scaffolds by Polymer Sponge Method (폴리머 스펀지법을 이용한 다공성 수산화아파타이트 지지체 제조 시 MgO 첨가량에 따른 영향)

  • Jin, Hyeong-Ho;Min, Sang-Ho;Lee, Won-Ki;Park, Hong-Chae;Yoon, Seog-Young
    • Korean Journal of Materials Research
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    • v.16 no.11
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    • pp.715-718
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    • 2006
  • Porous hydroxyapatite (HAp) scaffolds have been prepared by using the slurry including HAp and magnesia based on the replication of polymer sponge substrate. The influence of MgO content in slurry on the pore morphology and size, density, porosity, and mechanical strength of porous HAp scaffolds was investigated. The obtained scaffolds with average pore sizes ranging 150 to 300 mm had open, relatively uniform, and interconnected porous structure regardless of MgO content. As the MgO content increased, the pore network frame of scaffolds became to be relatively stronger, even though the pore size was not much changed. The compressive strength of the scaffolds increased rapidly with the increase of MgO content because of increasing the pore wall thickness and density of the scaffolds. As a result, the porosity, density, and compressive strength of the porous HAp scaffolds prepared by the sponge method were significantly affected by the addition of MgO.

Effect of Blowing Agents on Physical Properties of Polyurethane-polydimethylsiloxane Hybrid Foam

  • Asell Kim;Hyeonwoo Jeong;Sang Eun Shim
    • Elastomers and Composites
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    • v.58 no.4
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    • pp.208-215
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    • 2023
  • In this study, the properties of polyurethane-polydimethylsiloxane (PU-PDMS) hybrid foams containing different types and contents of physical blowing agents (PBAs) were investigated. Two types of blowing agents, namely physical blowing agents and thermally expandable microspheres (TEM), were applied. The apparent density was measured using precisely cut foam samples, and the pore size was measured using image software. In addition, the microstructure of the foam was confirmed via scanning electron microscopy and transmission electron microscopy. The thermal conductivities related to the microstructures of the different foams were compared. When 0.5 phr of the hydrocarbon-based PBA was added, the apparent density and pore size of the foam were minimal; however, the pore size was larger than that of neat foam. In contrast, the addition of 3 phr of TEM effectively reduced both the apparent density and pore size of the PBAs. The increase in resin viscosity owing to TEM could enhance bubble production stability, leading to the formation of more uniform and smaller pores. These results indicate that TEM is a highly efficient PBA that can be employed to decrease the weight and pore size of PU-PDMS hybrid foams.

Pore Characterization in Cross Section of Yellow Poplar (Liriodendron tulipifera) Wood

  • Jang, Eun-Suk;Kang, Chun-Won;Jang, Sang-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.1
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    • pp.8-20
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    • 2019
  • This study was conducted to analyze the pore structure of Yellow poplar. Cross-sectional surfaces of heartwood and sapwood of Yellow poplar (Liriodendron tulipifera) were observed by SEM, and the true density of the heartwood, intermediate wood and sapwood were measured by gas pycnometery, while gas permeability and pore size of heartwood, intermediate wood and sapwood were measured by capillary flow porometery. The pores were classified as through pore, blind pore and closed pore. It was determined that the permeability was increased due to the content and size of through pore being increased although the total porosity of specimen showed slight difference from pith to bark. The content of through pore porosity was 33.754 % of heartwood and 47.810 % of sapwood, showed an increasing trend from pith to bark, however, those for the blind pore porosity and closed pore porosity were 27.890 % and 19.492 % for heartwood and 19.447 % and 4.660 % for sapwood, showed a decreasing trend from pith to bark. The max pore size of specimens was increased by about 5 times from $5.927{\mu}m$ to $31.334{\mu}m$, and mean flow pore size was increased by about 315 times from $0.397{\mu}m$ to $12.437{\mu}m$ from pith to bark.

Modeling of Pore Coarsening in the Rim Region of High Burn-up UO2 Fuel

  • Xiao, Hongxing;Long, Chongsheng
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.1002-1008
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    • 2016
  • An understanding of the coarsening process of the large fission gas pores in the high burn-up structure (HBS) of irradiated $UO_2$ fuel is very necessary for analyzing the safety and reliability of fuel rods in a reactor. A numerical model for the description of pore coarsening in the HBS based on the Ostwald ripening mechanism, which has successfully explained the coarsening process of precipitates in solids is developed. In this model, the fission gas atoms are treated as the special precipitates in the irradiated $UO_2$ fuel matrix. The calculated results indicate that the significant pore coarsening and mean pore density decrease in the HBS occur upon surpassing a local burn-up of 100 GWd/tM. The capability of this model is successfully validated against irradiation experiments of $UO_2$ fuel, in which the average pore radius, pore density, and porosity are directly measured as functions of local burn-up. Comparisons with experimental data show that, when the local burn-up exceeds 100 GWd/tM, the calculated results agree well with the measured data.

Experiment and Analysis on the Heat Transfer Characteristics of a Channel Filled with Metal Form (발포 금속을 사용하는 채널의 열전달 특성 실험 및 해석)

  • Son, Young-Seok;Shin, Jee-Young;Cho, Young-Il
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.7
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    • pp.448-453
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    • 2010
  • Porous media containing complex fluid passage have especially large surface area per unit volume. This study is aimed to identify the heat transfer characteristics of high-porosity metal foams in a horizontal channel. Experiment is performed under various heat flux, velocity and pore density. Nusselt number decreases with higher pore density. Metal foams shows higher heat transfer coefficients than pin-fin structure with the same porosity. This is due to the more complex flow passage and larger heat transfer area based on the structure of the metal foams. The analysis on the pin-fin structure may not be suitable to the metal foam structure but should be identified extensively through further study.

The Fundamental Study on Thermal Conductivity with Variation Density of Light Weight Foam Concrete and Iron plate structure (경량기포콘크리트의 밀도변화에 따른 열전도 특성에 관한 기초적 연구)

  • Choi, Hun-Gug;Jung, Eun-Hye;Kang, Cheol;Lee, Eun-Young;Kim, Dae-Yeon;Kim, Jin-Man
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.849-852
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    • 2006
  • The lightweight foamed concrete is superior to properties of insulation and light-weight because it is included in many inner pore. So, lightweight foamed concrete used to construction field that need to property of insulation. The property of insulation of lightweight foamed concrete is varied with density. Also, Density is varied with hardening matrix and pore rate. The purpose of the experiment is to know thermal properties of specimen according to the change of density when heating the specimen. As a result of this experiment, the higher density, the lower temperature of mold. this tendency isn't same as ordinary lightweight foamed concrete, and then density 0.9 is expressed most low temperature result also the discontinuity of shape of mold was efficient for the prevention of the temperature rise.

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