• 제목/요약/키워드: Pore density

검색결과 602건 처리시간 0.03초

Structural and Optical Properties of Porous Silicon Prepared by Electrochemical Etching

  • Lee, Jeong-Seok;Cho, Nam-Hee
    • 한국세라믹학회지
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    • 제39권2호
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    • pp.109-112
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    • 2002
  • The structural and optical features of Porous Silicon(PS) were investigated; the porous silicon was prepared by electrochemical etching of silicon wafers in HF solution. The morphologies and Photoluminescece(PL) features of the PS were investigated in terms of etching time, current density and aging conditions. The average pore diameter and pore depth were determined by current density and etching time, respectively. As-prepared PS exhibited the maximum PL peak at the wavelength of ∼ 450 nm. The degree of deviation from as-prepared PS during aging treatment seemed to depend on the microstructure as well as morphology of the PS. It is found that etching current density played an important role on the microstructural features of the PS.

새로운 Black Color의 합성;화장품에서 블랙 색소로서 Meso-pore Silca에 캡슐레이션된 Carbon-black Silica (Synthesis of New Black Pigment; Carbon Black Pigment Capsulated into the Meso-pore of Silica as Black Pigment in Cosmetic)

  • Hye-in, Jang;Kyung-chul, Lee;Hee-chang , Ryoo
    • 대한화장품학회지
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    • 제30권2호
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    • pp.189-195
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    • 2004
  • 카본 블랙은 매우 낮은 밀도로 화장품에는 사용되지 않고 있지만 독성이 없고 안정한 물리적 특성과 검은색의 특성으로 이용 가치가 있다고 사료되는 바이다. 본 연구에서는 TEOS, a) PEO/ lecithin, b) PEO/polyethylene glycol, c) lecithin/polyethylene을 ethanol/water 수용액상에서 계면활성제를 탄화시켜 sol-gei반응에 의해 meso-porous silica샘플을 얻었고 N2 조건하 50$0^{\circ}C$에서 열처리된 organic-inorganic hybrid silica를 합성하였다. Pore안에 카본 블랙을 함유하는 meso-porous silica는 친수성, 소수성 용매에서 모두 좋은 분산성을 보여준다. 이 샘플은 BET에 의해 specific surface area (750$m^2$/g)과 pore size (4-6 nm)이고, XRD측정으로 pore structure (cylindrical type)를, 샘플의 SEM촬영으로 morphology(0.1-0.5$\mu\textrm{m}$ 입자 크기를 갖는 spherical powder)를 갖는다는 것을 알아냈다. 이렇게 합성한 카본-실리카 블랙 컬러를 마스카라에 적용하면 일반적으로 마스카라에 사용되던 블랙 컬러 사용시 보다 좀더 검은색을 보여주는 것은 물론이고 우수한 분산성도 갖는다. 무엇보다 이 파우더의 밀도 조절이 가능하여 마스카라 뿐 만 아니라 모든 화장품에의 사용이 가능하다.

Active Exchange of Water and Nutrients between Seawater and Shallow Pore Water in Intertidal Sandflats

  • Hwang, Dong-Woon;Kim, Gue-Buem;Yang, Han-Soeb
    • Ocean Science Journal
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    • 제43권4호
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    • pp.223-232
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    • 2008
  • In order to determine the temporal and spatial variations of nutrient profiles in the shallow pore water columns (upper 30 cm depth) of intertidal sandflats, we measured the salinity and nutrient concentrations in pore water and seawater at various coastal environments along the southern coast of Korea. In the intertidal zone, salinity and nutrient concentrations in pore water showed marked vertical changes with depth, owing to the active exchange between the pore water and overlying seawater, while they are temporally more stable and vertically constant in the sublittoral zone. In some cases, the advective flow of fresh groundwater caused strong vertical gradients of salinity and nutrients in the upper 10 cm depth of surface sediments, indicating the active mixing of the fresher groundwater with overlying seawater. Such upper pore water column profiles clearly signified the temporal fluctuation of lower-salinity and higher-Si seawater intrusion into pore water in an intertidal sandflat near the mouth of an estuary. We also observed a semimonthly fluctuation of pore water nutrients due to spring-neap tide associated recirculation of seawater through the upper sediments. Our study shows that the exchange of water and nutrients between shallow pore water and overlying seawater is most active in the upper 20 cm layer of intertidal sandflats, due to physical forces such as tides, wave set-up, and density-thermal gradient.

Increased Osteoblast Adhesion Densities on High Surface Roughness and on High Density of Pores in NiTi Surfaces

  • 임연민;강동우;김연욱;남태현
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.39.1-39.1
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    • 2009
  • NiTi alloy is widely used innumerous biomedical applications (orthodontics, cardiovascular, orthopaedics, etc.) for its distinctive thermomechanical and mechanical properties such as shape memory effect, super elasticity, low elastic modulus and high damping capacity. However, NiTi alloy is still a controversial biomaterial because of its high Ni content which can trigger the risk of allergy and adverse reactions when Ni ion releases into the human body. In order to improve the corrosion resistance of the TiNi alloy and suppress the release of Ni ions, many surface modification techniques have been employed in previous literature such as thermal oxidation, laser surface treatment, sol-gel method, anodic oxidation and electrochemical methods. In this paper, the NiTi was electrochemically etched in various electrolytes to modify surface. The microstructure, element distribution, phase composition and roughness of the surface were investigatedby scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry(EDS), X-ray diffractometry (XRD) and atomic force microscopy (AFM). Systematic controlling of nano and submicron surface features was achieved by altered density of hydro fluidic acid in etchant solution. Nanoscale surface topography, such as, pore density, pore width, pore height, surface roughness and surface tension were extensively analyzed as systematical variables.Importantly, bone forming cell, osteoblast adhesion was increased in high density of hydro fluidic treated surface structures, i.e., in greater nanoscale surface roughness and in high surface areas through increasing pore densities.All results delineate the importance of surface topography parameter (pores) inNiTi to increase the biocompatibility of NiTi in identical chemistry which is crucial factor for determining biomaterials.

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Pore Distribution of Porous Silicon layer by Anodization Process

  • Lee, Ki-Yong;Chung, Won-Yong;Kim, Do-Hyun
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1996년도 The 9th KACG Technical Annual Meeting and the 3rd Korea-Japan EMGS (Electronic Materials Growth Symposium)
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    • pp.494-496
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    • 1996
  • The purpose of this study is to investigate the effect of process conditions on pore distribution in porous silicon layer prepared by electrochemical reaction. Porous silicon layers formed on p-type silicon wafer show the network structure of fine porse whose diameters are less than 100${\AA}$. In n-type porous silicon, selective growth was found on the pore surface by wet etching process after PR patterning. And numerical method showed high current density on the pore tip. With this result we confirmed that pore formation has two steps. First step is the initial attack on the surface and second step is the directional growth on the pore tip.

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주요제지원료의 특성 및 고해가 종이의 pore structure 및 물성에 미치는 영향 (Effect of raw materials of the papermaking and physical treatment on the pore structure and properties of the paper)

  • 남기영;정순기;원종명
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2007년도 추계학술발표논문집
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    • pp.127-134
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    • 2007
  • Paper is composed network of fibers. Since paper is plain, most cases paper is considered two-dimensional. But network of fibers creates a network of pores, and pores between fibers are most important part of the paper structure. So we have to make an approach to the paper by three-dimensionally. Pore structure in the Z-direction of the paper can affect directly not only basic properties od the paper such as density, porosity, opacity and strength but also coverage of the coating colors during coatong and printing properties. We studied effect of raw materials of the papermaking and physical treatment on the pore structure and properties of the paper.

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양극산화를 이용한 나노템플레이트 기공 크기 제어에 관한 연구 (A study on the pore size control of nano template by anodic aluminum oxidation)

  • 이수호;서문수;유현민;이재형;정연호;임동건;황현석
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1495-1496
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    • 2011
  • Anodic aluminum oxide (AAO) nanotemplates for nano electronic device applications have been attracting increasing interest because of ease of fabrication, low cost process, and possible fabrication in large area. The size and density of the nanostructured materials can be controlled by changing the pore diameter and the pole density of AAO nanotemplate. In this paper, AAO nanotemplate was fabricated by second anodization method. In addition, effects of electrolyte and anodization voltate on the microstructure of porous alumina films were investigated. Vertically well aligned pores had the average pore sizes of 15-70 nm and the length of approximately 40 ${\mu}m$.

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충돌공기제트에서의 다공성 방열기의 열전달 특성 (Heat Transfer from a Porous Heat Sink by Air Jet Impingement)

  • 백진욱;김서영;강병하
    • 설비공학논문집
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    • 제13권2호
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    • pp.73-79
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    • 2001
  • Experiment were carried out to investigate the heat transfer characteristics of an aluminum foam block as a porous heat sink on a heat source by a vertical air jet impingement that can be applied for electronics cooling. The performance of the aluminum foam heat sink was evaluated by the convective heat transfer coefficient on the heat source. At a fixed porosity, pore density ($\beta$) of the foam and Reynolds number Re were varied in the range of $\beta$a=10, 20, 40 PPI(Pore Per Inch) and $850\leqRe\leq25000$. A nozzle diameter and the nozzle-to-plate spacing were also varied. It was found that the convective heat transfer was enhanced by the aluminum foam heat sink with lower pore density due to relatively intensified flow through the foam block. The aluminum foam block with much reduced weight shows slightly better performance with larger Nusselt number, compared with the convectional heat sink.

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Binder가 PZT계 세라믹스의 소결특성에 미치는 영향 (Effect of Binder on the Sintering Characteristics of PZT Ceramics)

  • 정우환;김정주;조상희
    • 한국세라믹학회지
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    • 제25권4호
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    • pp.385-389
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    • 1988
  • Effects of binder addition on the porosity, pore size and grain size of PZT ceramics were investigated. The binders were used PVA, PEG and MC, they were added separately and simultaneously. After sintering for 90 min 125$0^{\circ}C$, the porosity and the pore size were determined by using an image processing method. Simultaneous addition of two different binders resulted in the highest sintered density and the large pore size.

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