• Title/Summary/Keyword: Pore characteristics

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Evaluation of Pore Size Distribution of Berea Sandstone using X-ray Computed Tomography (X-ray CT를 이용한 베레아 사암의 공극크기분포 산정)

  • Kim, Kwang Yeom;Kim, Kyeongmin
    • The Journal of Engineering Geology
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    • v.24 no.3
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    • pp.353-362
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    • 2014
  • Pore structures in porous rock play an important role in hydraulic & mechanical behaviour of rock. Porosity, size distribution and orientation of pores represent the characteristics of pore structures of porous rock. While effective porosity can be measured easily by conventional experiment, pore size distribution is hard to be quantified due to the lack of corresponding experiment. We assessed pore size distribution of Berea sandstone using X-ray CT image based analysis combined with associated images processing, i.e., image filtering, binarization and skeletonization subsequently followed by the assessment of local thickness and star chord length. The aim of this study is to propose a new and effective way to evaluate pore structures of porous rock using X-ray CT based analysis for pore size distribution.

Adsorption and Desorption Characteristics of Toluene in Modified Activated Carbon Using Microwave Irradiation (마이크로파를 이용한 탈착시스템에서 개질화 된 활성탄의 흡.탈착 특성)

  • Kim, Beom-Jun;Choi, Sung-Woo
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.493-500
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    • 2008
  • This paper describes the adsorption/desorpton efficiency of a modified activated carbon by irradiated microwave to treat toluene. By employing microwave energy, the regeneration time was considerably shortened compared with conventional thermal heating regeneration. New adsorbent called ACB (Activated Carbon-Bentonite) was prepared from powder activated carbon with mixing bentonite as a binder. Specific surface area, average pore size and total pore volume of ACB were calculated from the nitrogen adsorption/desorption isotherm. The surface of ACB was characterized with scanning electron microscope(SEM). The results showed that the specific surface area, total pore volume, average pore size of ABC was not influenced by regenerating cycle with microwave irradiation. Toluene was adsorbed onto ACB which desorbed by MW irradiation. Absorption capacity of ACB was 0.117 $g_{toluene}/g_{ACB}$. Desorption efficiency of toluene increased as higher microwave output was applied.

Micromechanics based Models for Pore-Sructure Formation and Hydration Heat in Early-Age Concrete (초기재령 콘크리트의 세공구조 형성 및 발영특성에 관한 미시역학적 모델)

  • 조호진;박상순;송하원;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.123-128
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    • 1999
  • Recently, as a performance based design concept is introduced, assurance of expected performances on serviceability and safety in the whole span of life is exactly requested. So, quantitative assessments about durability related properties of concrete in early-age long term are come to necessary, Especially in early age, deterioration which affects long-term durability performance can be occurred by hydration heat and shrinkage, so development of reasonable hydration heat model which can simulate early age behavior is necessary. The micor-pore structure formation property also affects shrinkage behavior in early age and carbonations and chloride ion penetration characteristic in long term, So, for the quantitative assessment on durability performance of concrete, modelings of early age concrete based on hydration process and micor-pore structure formation characteristics are important. In this paper, a micromechanics based hydration heat evolution model is adopted and a quantitative model which can simulate micro-pore structure development is also verified with experimental results. The models can be used effectively to simulate the early-age behavior of concrete composed of different mix proportions.

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Syunthesis of Silica Aerogel at Ambient Pressure and Characterization (I) (실리카에어로겔의 상압합성 및 특성연구(I))

  • 강신규;최세영
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1394-1402
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    • 1996
  • The Silica gel with the density of 0.2g/cm3 and porosity of 90% was synthesized. The silica wet gel was dried and heat-treated under the ambient pressure after modification of the wet gel surface by TMCS. Specific surface area total pore volume and mean pore radius of dried gel were all increased with increasing heat treatment temperature and confirmed about 1400m2/g, 4.5cc/g and 8 nm respectively after heat treatment above 25$0^{\circ}C$. But the pore size distribution of dried gel was in the range of 1-100nm and was almost indepen-dent of temperature. As the result of external shape pore characteristics and microstructure of gel using SEM similar properties were observed between the silica gel synthesized in this study and the silica aerogel through the super critical drying.

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Cyclic Threshold Shearing Strains of Sands Based on Pore Water Pressure Buildup and Variations of Deformation Characteristics (간극수압증가와 동적변형특성 변화에 근거한 사질토 지반의 반복한계전단변형률)

  • Kim, Dong-Soo;Choo, Yun-Wook
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.274-281
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    • 2004
  • In this paper, the existing Stokoe type torsional shear equipment is modified to saturate the specimen and measure excess pore water pressure during undrained testing. Two types of sands, Geumgang and Toyoura sands, were collected and TS tests were performed at various densities drainage conditions, and confining pressures. The cyclic threshold shearing strains were estimated based on the variations of shear modulus, material damping ratio and pore pressures with loading cycles. The effects of relative density, confining pressure, and drainage condition on the cyclic threshold shearing strains were investigated.

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Properties of Antimicrobial Membrane Using an N-Halamine Material (N-Halamine을 이용한 항균 멤브레인의 특성)

  • Baek, Ji-Yoon;Kim, Sam-Soo;Lee, Jae-Woong
    • Textile Coloration and Finishing
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    • v.21 no.4
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    • pp.57-62
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    • 2009
  • N-Halamines are compounds which have covalent bonding between nitrogen and halogen. N-Halamine materials possess strong antimicrobial properties against wide spectrum of bacteria. The aim of this study is to prepare N-halamine membranes using m-aramid and poly(vinyl alcohol) (PVA). Surface characteristics using scanning electron microscope (SEM), pore size distribution, liquid permeability and mean pore size were measured to confirm feasibility as membrane. The results indicated that increased PYA portion up to 15% in the m-aramid/PVA blend resulted in improved pore size distribution, liquid permeability as well as mean pore size. Furthermore, antibacterial efficacy of the membranes after chlorination was confirmed and the results showed that bacteria in water were inactivated.

A Study on the Proper Pore pressure ratio in Continuous Loading Consolidation tests (연속재하 압밀시험에서 적정 간극수압비에 관한 연구)

  • Chae, Sum-Sik;Lee, Song
    • Proceedings of the KSR Conference
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    • 2002.05a
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    • pp.271-276
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    • 2002
  • Continuous loading is applied the sample has been developed to overcome some of the problems associated with the incremental loading consolidation test. Therefore, it is able to reduce the test time and provide a well defined the curve of effective stress versus strain due to continuous stress-strain points. Also, the constant rate of strain consolidation(CRSC) test has been accepted widely as a standard method in foreign countries because of its many advantages. However, in Korea the CRSC test has not been used in engineering practice and experimentally verified. Because there is not a precise criterion of testing despite consolidation characteristics are influenced on strain rate and Pore pressure ratio. Consequently, it is difficult to apply in engineering practice. In this study, artificial neural networks are applied to the estimation of th proper strain rate and pore pressure ratio of the CRSC test. This study shows the possibility of utilizing the artificial neural networks model of estimation of the strain rate and pore pressure ratio in the CRSC test.

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Multi-Region Model of Solute Transport in Soil for the Preferential Flow (Preferential 흐름에 의한 토양내의 다영역 용질이동 모델)

  • 안병기
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.42 no.2
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    • pp.71-77
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    • 2000
  • A multi-region model for solute transport through saturated soils has been developed to describe preferential flow. The model consists of numerous discrete pore groups, which are characterized by a discrete dispersion coefficient, flow velocity, and porosity . The hydraulic properties for each pore group are derived from a soil's hydraluic conductivity and soil water characteristic functions . Flow in pore group is described by the classical advection-disersion equation (ADE). An implict finite difference scheme was applied to the governing equation that results in a block-tridiagonal system of equations that is very efficient and allows the soil to be divided into any number of pore groups. The numerical technique is derived from methods used to solve coupled equations in fluid dynamics problems and can also be applied to the transport of interacting solutes. The results of the model are compared to the experimental data from published papers. This paper contributes on the characteristics of the method when applied to the parallel porosity model to describe preferential flow of solutes in soil.

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Synthesis and Carbonization of Crosslinked Spherical Styrene-Divinylbenzene Copolymer Bead (스티렌-디비닐벤젠 가교결합을 갖는 구형 공중합수지의 합성 및 탄화)

  • Hongkyeong Kim
    • Journal of Institute of Convergence Technology
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    • v.13 no.1
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    • pp.23-28
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    • 2023
  • Crosslinked spherical polystyrene particles with a particle diameter of 200-500 ㎛ were synthesized by using suspension copolymerization of styrene and divinylbenzene, and the effect of divinylbenzene content, poreforming agent on their spherical formation, thermal stability, specific surface area, and carbonization characteristics were examined. The spherical copolymer beads were collapsed during carbonization up to 45% of divinylbenzene content. Toluene was used as pore-forming agent since it is more soluble in monomer phase rather than dispersion media during suspension polymerization, and the specific surface area and total pore volume increased with content of pore-forming agent.

Characteristics of Heavy Metal Releases from the Abandoned Dogog Mine Tailing in Korea (도곡광산 광미의 중금속 용출 특성)

  • Park, Chang-Jin;Kim, Won-Il;Jeong, Goo-Bok;Lee, Jong-Sik;Ryu, Jong-Su;Yang, Jae-E.
    • Korean Journal of Environmental Agriculture
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    • v.25 no.4
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    • pp.316-322
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    • 2006
  • Objective of this research was to assess the release characteristics of metals from the mine tailing to base the prediction of metal load potential from tailing to soils. Water-soluble concentrations of Cd, Cu, Pb and Zn released from mine tailing after 2 hrs were 2.31, 129.38, 17.17, and 287.53 mg/kg, respectively, as compared to 1.6, 128, 108, and 142 mg/kg that were extractable by 0.1 M HCl. Kinetics of metal releases followed the power function model significantly indicating that more of water soluble fractions of those metals released at the initial short time, followed by a slow increase. Concentrations of metals released from tailing by water and 0.1 M HCl were in the orders of Zn > Cu > Pb > Cd. The breakthrough curve from the column experiment showed that concentrations of Cd, Cu, and Zn reached at highest after one pore volume, but that of Pb reached highest after five pore volumes when 0.1 M HCl was used as eluent. The release rate of Cd from mine tailing was the fastest but Pb was the slowest. The cumulative mass of metal released by 0.1 M HCl was in the order of Zn > Cu > Pb > Cd after nine pore volume elution.