• 대한화장품학회지
• /
• 제30권2호
• /
• pp.189-195
• /
• 2004

카본 블랙은 매우 낮은 밀도로 화장품에는 사용되지 않고 있지만 독성이 없고 안정한 물리적 특성과 검은색의 특성으로 이용 가치가 있다고 사료되는 바이다. 본 연구에서는 TEOS, a) PEO/ lecithin, b) PEO/polyethylene glycol, c) lecithin/polyethylene을 ethanol/water 수용액상에서 계면활성제를 탄화시켜 sol-gei반응에 의해 meso-porous silica샘플을 얻었고 N2 조건하 50$0^{\circ}C$에서 열처리된 organic-inorganic hybrid silica를 합성하였다. Pore안에 카본 블랙을 함유하는 meso-porous silica는 친수성, 소수성 용매에서 모두 좋은 분산성을 보여준다. 이 샘플은 BET에 의해 specific surface area (750$m^2$/g)과 pore size (4-6 nm)이고, XRD측정으로 pore structure (cylindrical type)를, 샘플의 SEM촬영으로 morphology(0.1-0.5$\mu\textrm{m}$ 입자 크기를 갖는 spherical powder)를 갖는다는 것을 알아냈다. 이렇게 합성한 카본-실리카 블랙 컬러를 마스카라에 적용하면 일반적으로 마스카라에 사용되던 블랙 컬러 사용시 보다 좀더 검은색을 보여주는 것은 물론이고 우수한 분산성도 갖는다. 무엇보다 이 파우더의 밀도 조절이 가능하여 마스카라 뿐 만 아니라 모든 화장품에의 사용이 가능하다.

• 한국의류학회지
• /
• 제21권1호
• /
• pp.206-216
• /
• 1997

The purpose of this study was to determine the pore size distributions (PSDs) of polyester woven fabrics by using liquid extraction method. Three types of PSDs-percent PSD, PSD per unit area of sample and PSD per unit weight of sample-were evaluated. Plain, twill and satin polyester fabrics with various fabric counts were used as specimens. Results showed that the interyarn PSDs reflected the fabric characteristics such as the fabric count and the weave type and the intrayarn PSDs reflected the thread characteristics such as the number of fibers, the fiber diameter, the thread diameter and the thread twist. Of three types of PSDs, the PSD per unit area of sample best reflect fabric and thread characteritics. As the fabric count decreased, rc increased and interyarn pore volume increased. The PSDs were skewed to the small pore sizes and the pore volumes decreased in the order of plain> twill> satin. As the number of fibers, the fiber diameter and the thread twist decreased, the intrayarn pore volumes were increased.

• Geomechanics and Engineering
• /
• 제12권4호
• /
• pp.707-721
• /
• 2017

The objective of this paper is to experimentally study the consolidation of saturated silty clay subjected to repeated heating-cooling cycles using a modified temperature-controlled triaxial apparatus. Focus is placed on the influence of the water content, confining pressure, and magnitudes and number of thermal loading cycles. The experimental results show that the thermally induced pore pressure increases with increasing water content and magnitude of thermal loading in undrained conditions. After isothermal consolidation at an elevated temperature, the pore pressure continues to decrease and gradually falls below zero during undrained cooling, and the maximum negative pore pressure increases as the water content decreases or the magnitude of thermal loading increases. During isothermal consolidation at ambient temperature after one heating-cooling cycle, the pore pressure begins to rise due to water absorption and finally stabilizes at approximately zero. As the number of thermal loading cycles increases, the thermally induced pore pressure shows a degrading trend, which seems to be more apparent under a higher confining pressure. Overall, the specimens tested show an obvious volume reduction at the completion of a series of heating-cooling cycles, indicating a notable irreversible thermal consolidation deformation.

• Geomechanics and Engineering
• /
• 제21권5호
• /
• pp.423-432
• /
• 2020

Hydraulic conductivity is one of the engineering properties of soil. This study focusses on the influence of cement content on the hydraulic conductivity of cemented sand, which is investigated based on the results from numerical analysis and laboratory testing. For numerical analysis the cemented samples were scanned using X-ray Computed Tomography (CT) while laboratory testing was carried out using a triaxial setup. Numerical analysis enables us to simulate flow through the sample and provides insight to the microstructure. It quantifies the pore volume, proportion of interconnected voids and pore size distribution in both cemented and uncemented samples, which could be computed only through empirical equations in case of laboratory testing. With reduction in global voids, the interconnecting voids within the samples also reduce with cement content. Gamma cumulative distribution function is used to predict the percentage of voids lesser than a given pore volume. Finally, the results obtained from both numerical analysis and laboratory testing are compared.

• 한국분말재료학회지
• /
• 제18권6호
• /
• pp.488-495
• /
• 2011

This study was performed to fabricate the porous titanium foam by space holder method using NaCl powder, and to evaluate the effect of NaCl volume fractions (33.3~66.6 vol.%) on the porosities, compressive strength, Young's modulus and permeability. For controlling pore size, CP titanium and NaCl particles were sieved to different size range of 70~150 ${\mu}m$ and 300~425 ${\mu}m$ respectively. NaCl of green Ti compact was removed in water followed by sintered at $1200^{\circ}C$ for 2 hours. Total porosities of titanium foam were in the range of 38-70%. Pore shape was a regular hexahedron similar that of NaCl shape. Porous Ti body showed that Young's modulus and compressive strength were in the range of 0.6-6 GPa and 8-127 MPa respectively. It showed that pore size and mechanical properties of Ti foams was controllable by NaCl size and volume fractions.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2000년도 가을 학술발표회 논문집
• /
• pp.427-434
• /
• 2000

Hydraulic conductivity of soil-cement was measured as a function of some selected construction variables that are often encountered in practice. They are initial (or compaction) water content, delayed compaction after mixing, and repeated freezing and thawing. Sandy and clayey soils were used. The hardening agent used was a cement based soil stabilizer consisting of 80% of ordinary Portland cement and 20% of a combination of supplementary materials. Hydraulic conductivity of soil-cement with varying initial water content was, in trend, similar to that of compacted clay. Hydraulic conductivity of soil-cement decreased with increasing initial water content and reached its minimum when compacted wet of optimum water content. Pore size distributions of soil cement at different initial water contents were analyzed using mercury intrusion porosimetry. The analysis showed that dryer condition led to the formation of larger pores with lesser total pore volume; smaller pores with larger total pore volume at wetter condition. Hydraulic conductivity of soil-cement increased by orders in magnitude when specimen underwent delayed compaction of longer than 4 hours after mixing and repeated freezing and thawing.

• Journal of Advanced Marine Engineering and Technology
• /
• 제39권8호
• /
• pp.838-842
• /
• 2015

The Li-air battery is a promising candidate for the most energy-dense electrochemical power source because it has 5 to 10 times greater energy storage capacity than that of Li-ion batteries. However, the Li-air cell performance falls short of the theoretical estimate, primarily because the discharge terminates well before the pore volume of the air electrode is completely filled with lithium oxides. Therefore, the structure of carbon used in the air electrode is a critical factor that affects the performance of Li-air batteries. In a previous study, we reported a new class of carbon nanomaterial, named carbon nanoballs (CNBs), consisting of highly mesoporous spheres. Structural characterization revealed that the synthesized CNBs have excellent a meso-macro hierarchical pore structure, with an average diameter greater than 10 nm and a total pore volume more than $1.00cm^3g^{-1}$. In this study, CNBs are applied in an actual Li-air battery to evaluate the electrochemical performance. The formation mechanism and electrochemical performance of the CNBs are discussed in detail.

• 한국항공우주학회지
• /
• 제39권8호
• /
• pp.711-718
• /
• 2011

본 논문에서는 열화학적 분해 및 열기계학적 변형이 고려된 구성 방정식을 사용하여 다공성 탄소/페놀릭 복합재료의 열탄성 거동을 예측하였다. 다공성 복합재료의 온도 의존성 및 열화학적 분해 과정에서의 기공도, 분해 가스에 의한 기공 압력, 재료의 수축을 고려하였다. 기공도와 기공 압력이 고려된 대표 체적 요소 모델의 유한요소 해석을 통해 산출된 거시적 기공 탄성 계수를 구성 방정식에 적용하였다. 간단한 수치 실험을 통해 기공탄성 계수가 다공성 재료의 열탄성 거동에 미치는 영향을 분석하였으며, 재료 내부에 형성된 기공과 기공 압력에 의한 응력 구배 및 변형을 확인하였다.

• Carbon letters
• /
• 제15권1호
• /
• pp.45-49
• /
• 2014

In this study, synthetic viscose rayon fabric has been used for preparing activated carbon fabric (ACF), impregnated with different concentrations of $H_3PO_4$. The effect of $H_3PO_4$ impregnation on the weight yield, surface area, pore volume, chemical composition and morphology of ACF were studied. Experimental results revealed that both Brunauer-Emmett-Teller surface area and micropore volume increased with increasing $H_3PO_4$ concentration; however, the weight yield and microporosity (%) decreased. It was observed that samples impregnated at $70^{\circ}C$ (AC-70) give higher yield and higher microporosity as compared to $30^{\circ}C$ (AC-30). The average pore size of the ACF also gradually increases from 18.2 to 19 and 16.7 to $20.4{\AA}$ for $30^{\circ}C$ and $70^{\circ}C$, respectively. The pore size distribution of ACF was also studied. It is also concluded that the final ACF strength is dependent on the concentration of impregnant.

• Korean Chemical Engineering Research
• /
• 제49권6호
• /
• pp.851-856
• /
• 2011

본 연구에서는 하수슬러지의 열분해로 촤를 제조하였고, 열분해 반응 조건이 슬러지 촤의 특성에 미치는 영향을 조사하였다. 열분해 온도가 $300^{\circ}C$에서 $800^{\circ}C$로 증가함에 따라 슬러지 char의 비표면적은 증가하였으나, $700^{\circ}C$에서는 일시적으로 감소하였다. 열분해 속도는 char의 비표면적과 기공부피에 미치는 영향이 크지 않은 것으로 나타났다. 반면, 열분해 반응시간이 증가함에 따라 비표면적과 기공부피는 증가하였으나, 평균 기공크기는 감소하는 결과를 나타내었다.