• KEPCO Journal on Electric Power and Energy
• /
• 제7권1호
• /
• pp.167-169
• /
• 2021

In this study, monodispersive silica nanoparticles with double mesoporous shells were synthesized, and the pore size of synthetic mesoporous silica nanoparticles was controlled. Cetyltrimethylammonium chloride (CTAC), N, N-dimethylbenzene, and decane were used as soft template and induced to form outer mesoporous shell. The resultant double mesoporous silica nanoparticles were consisted of two layers of shells having different pore sizes, and it has been confirmed that outer shells with larger pores (Mean pore size > 2.5 nm) are formed directly on the surface of the smaller pore sized shell (Mean pore size < 2.5 nm). It was confirmed that the regulation of the molar ratio of pore expansion agents plays a key role in determining the pore size of double mesoporous shells.

• 한국산림과학회지
• /
• 제85권1호
• /
• pp.66-75
• /
• 1996

본 연구는 산불 발생이 임지의 수저류 특성에 미치는 영향을 알아보기 위해 실시했다. 비산불 지역과 산화적지를 대상으로 산림토양의 수저류능을 토양공극, 최대수분량, 이용가능수량, 그리고 투수율을 측정하여 비교 분석하였다. 주요 인자들의 측정에 의해서 얻어진 결과는 다음과 같다. 산화적지와 대조구에서 토성이 깊어질수록 전공극(全孔隙), 조공극(組孔隙), 이용가능 수량, 투수율은 모두 감소하는 경향을 나타내고, 세공극(細孔隙)은 약간 증가하는 경향이 있었다. 대조구에 비해 산화적지에서는 투수율, 조공극량 및 이용가능수량이 낮게 나타나는 반면, 세공극량은 높게 나타났다. 그리고 산불이 발생한 직후에는 산림토양의 공극량 분포에 큰 변화가 일어나지 않지만, 시간이 경과함에 따라 산화적지의 표토 공극분포에 변화를 일으키면서 서서히 토심 20-40cm까지 영향을 미치는 것으로 나타났다. 또한 토심변화에 따른 이용가능수량의 변화는 대조구에 비해 산화적지에서 상대적으로 큰 폭으로 감소하는 경향이 있었다. 이 결과로 산림의 수저류능은 산불에 의해 크게 영향을 받는 것을 알 수 있었다.

• Korean Membrane Journal
• /
• 제10권1호
• /
• pp.13-19
• /
• 2008

Water softening is a very promising field for membranes and especially ultra low pressure membranes. Nanofiltration membranes based on pore-filling technology was prepared by using a new technique: the in-situ cross-linking. This route involves introducing a pre-formed polymer into the pores of a host membrane and then locking the polymer in the pores by in-situ cross-linking with an appropriate reagent. By this way, it is possible to make robust and competitive, pore-filled, anion-exchange membranes with excellent control over the properties of the incorporated gel without affecting the host membrane. In this paper, the possibilities of tuning such membranes for ultra low pressure water softening was examined by altering pore-filling chemistry (by changing cross-linking and aminating reagents). The results showed that tuning the chemistry of the pore-filling has important effects. In particularly, it had been shown that the correct selection of cross-linking reagent was not only essential to get pore-filled membranes but it could control their properties. Moreover, the aminating reagent could improve membrane performance. It was found that an increase in hydrophobicity could improve the Darcy permeability.

• 한국세라믹학회지
• /
• 제55권1호
• /
• pp.74-79
• /
• 2018

Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than those of bentonite and zeolite. It was effective to add white cement as well as a retarding agent to control the setting time of the ceramic paint. As the amount of added porous materials increases, the specific surface area and total pore volume of ceramic paint increase, but the average pore diameter decreases. The addition of porous materials having a high specific area and a large pore volume improves the moisture absorptive and desorptive performance of the ceramic paint. Therefore, in this experiment, the moisture absorptive and desorptive properties were best when active clay was added. Also, as the added amount of porous materials increases, the moisture absorptive and desorptive properties improve. In this experiment, when 70 mass% of active clay was added to ceramic paint, the hygroscopicity was highest at about $80g/m^2$.

• 한국재료학회지
• /
• 제28권1호
• /
• pp.62-67
• /
• 2018

Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than bentonite and zeolite. The flexible strength of the gypsum board decreased with an increasing amount of porous material, and the flexible strength was lowest when active clay with a higher specific surface area than others porous materials was added. The specific surface area and total pore volume of ceramic boards containing porous material were highest at $102.25m^2/g$, $0.142cm^3/g$, respectively, when the active clay was added. In addition, as the amount of added porous materials increased, the specific surface area and total pore volume of the ceramic board increased, but the average pore diameter decreased. The addition of s porous materials with a high specific area and a large pore volume improved the moisture absorptive and desorptive performance of the ceramic board. Therefore, in this experiment, the moisture absorptive and desorptive properties were the best when active clay was added. Furthermore, as the amount of added porous materials increased, the moisture absorptive and desorptive properties improved. When 70 mass% of active clay was added to ${\alpha}$-type gypsum, the hygroscopicity was the highest, about $300g/m^2$, in this experiment.

• 한국세라믹학회지
• /
• 제35권4호
• /
• pp.399-405
• /
• 1998

The effect of each factor on the porosity and mean pore size of cordierite(2Mg$.$2{{{{ {Al}_{2 } {O }_{3 } }}$.$5{{{{ {SiO}_{2 } }}) ceram-ics which have been mainly used for hot gas filter was investigated by using orthogonal array. The poros-ity was observed to increase with the content of graphite added as pore-forming material and decrease with increasing talc size. The effects of the other factors the graphite size sintering temperature and hold-ing time at sintering temperature were observed to be small relatively. In case of mean pore size the ef-fect of talc size on the mean pore size of cordierity was investigated to be the largest. The mean pore size was observed to increase with increasing talc size.

• Korean Chemical Engineering Research
• /
• 제53권3호
• /
• pp.382-390
• /
• 2015

Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.

• 센서학회지
• /
• 제25권6호
• /
• pp.399-405
• /
• 2016

Scent diffuser using micro-pore piezo actuator achieved a commercial success because of its cheap production cost, but it is easy to be use for IT-based contents due to difficulty of scent intensity control. To solve this problem, we control the emission amount of scent diffuser by changing amplitude and frequency of input voltage applied to micro-pore piezo actuator. And, we analyzed the effect of density of cotton core on emission amount and a relationship between hole-size of mesh in piezo actuator and viscosity of scents to design a mechanically optimal scent device.

• Journal of Periodontal and Implant Science
• /
• 제43권6호
• /
• pp.251-261
• /
• 2013

A paradigm shift is taking place in medicine and dentistry from using synthetic implants and tissue grafts to a tissue engineering approach that uses degradable porous three-dimensional (3D) material hydrogels integrated with cells and bioactive factors to regenerate tissues such as dental bone and other oral tissues. Hydrogels have been established as a biomaterial of choice for many years, as they offer diverse properties that make them ideal in regenerative medicine, including dental applications. Being highly biocompatible and similar to native extracellular matrix, hydrogels have emerged as ideal candidates in the design of 3D scaffolds for tissue regeneration and drug delivery applications. However, precise control over hydrogel properties, such as porosity, pore size, and pore interconnectivity, remains a challenge. Traditional techniques for creating conventional crosslinked polymers have demonstrated limited success in the formation of hydrogels with large pore size, thus limiting cellular infiltration, tissue ingrowth, vascularization, and matrix mineralization (in the case of bone) of tissue-engineered constructs. Emerging technologies have demonstrated the ability to control microarchitectural features in hydrogels such as the creation of large pore size, porosity, and pore interconnectivity, thus allowing the creation of engineered hydrogel scaffolds with a structure and function closely mimicking native tissues. In this review, we explore the various technologies available for the preparation of macroporous scaffolds and their potential applications.

• 한국초지조사료학회지
• /
• 제7권2호
• /
• pp.109-112
• /
• 1987

tall fescue의 밀도변화에 미치는 토양경화는 공극율의 영향에 대하여 조사하였다. 1. 토양경화에 따라서 토양경도와 용적중은 증가되었다. (Table 1). 2. 10kg 처리구(토양경도 2.5kg/$\textrm{cm}^3$)의 밀도가 타처리구보다 유의하게 높았다. (Table 2, Fig. 1). 3. 토양공성율과 밀도와는 상관계수가 0.9804로써 1%수준의 정상란이 인정되었다. 4. 경화된 토양에서는 공성율이 37.5% 이상일 때 높은 밀도를 나타내었다.