• Title/Summary/Keyword: Pore Control

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Synthesis of Double Mesoporous Silica Nanoparticles and Control of Their Pore Size (이중 다공성 실리카 나노입자 합성 및 공극 크기 조절)

  • Park, Dae Keun;Ahn, Jung Hwan
    • KEPCO Journal on Electric Power and Energy
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    • v.7 no.1
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    • pp.167-169
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    • 2021
  • In this study, monodispersive silica nanoparticles with double mesoporous shells were synthesized, and the pore size of synthetic mesoporous silica nanoparticles was controlled. Cetyltrimethylammonium chloride (CTAC), N, N-dimethylbenzene, and decane were used as soft template and induced to form outer mesoporous shell. The resultant double mesoporous silica nanoparticles were consisted of two layers of shells having different pore sizes, and it has been confirmed that outer shells with larger pores (Mean pore size > 2.5 nm) are formed directly on the surface of the smaller pore sized shell (Mean pore size < 2.5 nm). It was confirmed that the regulation of the molar ratio of pore expansion agents plays a key role in determining the pore size of double mesoporous shells.

Effects of Forest Fire on the Water Storage Characteristics of Forest Land (산불이 임지(林地)의 수저류(水貯留) 특성(特性)에 미치는 영향(影響))

  • Lee, Heon Ho
    • Journal of Korean Society of Forest Science
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    • v.85 no.1
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    • pp.66-75
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    • 1996
  • This study was carried out to examine the forest fire effect on water storage characteristics in the forests. Water storage capacity of the burned area was analyzed by several major factors, such as soil pore, maximum water content, effective water storage, and percolation rate. The results obtained from the analysis of major factors are as follows; The deeper soil depth, the less total pore, coarse pore, effective water storage, and percolation rate. However, fine pore increased slightly in both burned area and control plot. As compared with control plot, burned area showed lower percolation rate, coarse pore, and effective water storage, but higher values of fine pore. Directly after forest fire, the soil pore is little affected. But as the time passes, top soil structure changes and soil pore also is affected even in a deep soil. Estimated effective water storage was lower at top soil of Namcheon and at deep soil of Namha in all the burned areas, but slowly decreased in deep soil compared to control plots. Therefore it was concluded that forest water storage capacity was greatly affected by the forest fire.

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Preparation and Characterization of Pore-filled Membrane Based on Polypropylene with Poly(vinylbenzyl chloride) by Using in-situ Cross-linking Technique

  • Kwon, Byeong-Min;Ko, Moon-Young;Hong, Byung-Pyo;Byun, Hong-Sik
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.13-19
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    • 2008
  • Water softening is a very promising field for membranes and especially ultra low pressure membranes. Nanofiltration membranes based on pore-filling technology was prepared by using a new technique: the in-situ cross-linking. This route involves introducing a pre-formed polymer into the pores of a host membrane and then locking the polymer in the pores by in-situ cross-linking with an appropriate reagent. By this way, it is possible to make robust and competitive, pore-filled, anion-exchange membranes with excellent control over the properties of the incorporated gel without affecting the host membrane. In this paper, the possibilities of tuning such membranes for ultra low pressure water softening was examined by altering pore-filling chemistry (by changing cross-linking and aminating reagents). The results showed that tuning the chemistry of the pore-filling has important effects. In particularly, it had been shown that the correct selection of cross-linking reagent was not only essential to get pore-filled membranes but it could control their properties. Moreover, the aminating reagent could improve membrane performance. It was found that an increase in hydrophobicity could improve the Darcy permeability.

Evaluation of Humidity Control Ceramic Paint Using Gypsum Binder

  • Lee, Jong-Kyu;Kim, Tae-Yeon
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.74-79
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    • 2018
  • Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than those of bentonite and zeolite. It was effective to add white cement as well as a retarding agent to control the setting time of the ceramic paint. As the amount of added porous materials increases, the specific surface area and total pore volume of ceramic paint increase, but the average pore diameter decreases. The addition of porous materials having a high specific area and a large pore volume improves the moisture absorptive and desorptive performance of the ceramic paint. Therefore, in this experiment, the moisture absorptive and desorptive properties were best when active clay was added. Also, as the added amount of porous materials increases, the moisture absorptive and desorptive properties improve. In this experiment, when 70 mass% of active clay was added to ceramic paint, the hygroscopicity was highest at about $80g/m^2$.

Evaluation of Humidity Control Ceramic Board Using Gypsum Binder (석고계 바인더를 활용한 습도도절 세라믹 보드의 특성 평가)

  • Lee, Jong-Kyu;Kim, Tae-Yeon
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.62-67
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    • 2018
  • Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than bentonite and zeolite. The flexible strength of the gypsum board decreased with an increasing amount of porous material, and the flexible strength was lowest when active clay with a higher specific surface area than others porous materials was added. The specific surface area and total pore volume of ceramic boards containing porous material were highest at $102.25m^2/g$, $0.142cm^3/g$, respectively, when the active clay was added. In addition, as the amount of added porous materials increased, the specific surface area and total pore volume of the ceramic board increased, but the average pore diameter decreased. The addition of s porous materials with a high specific area and a large pore volume improved the moisture absorptive and desorptive performance of the ceramic board. Therefore, in this experiment, the moisture absorptive and desorptive properties were the best when active clay was added. Furthermore, as the amount of added porous materials increased, the moisture absorptive and desorptive properties improved. When 70 mass% of active clay was added to ${\alpha}$-type gypsum, the hygroscopicity was the highest, about $300g/m^2$, in this experiment.

Studies on the Control of Porosity and Mean Pore Size in Cordierite Ceramics (Cordierite의 기공률 및 기공경조절에 관한 연구)

  • Yang, Jin
    • Journal of the Korean Ceramic Society
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    • v.35 no.4
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    • pp.399-405
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    • 1998
  • The effect of each factor on the porosity and mean pore size of cordierite(2Mg$.$2{{{{ {Al}_{2 } {O }_{3 } }}$.$5{{{{ {SiO}_{2 } }}) ceram-ics which have been mainly used for hot gas filter was investigated by using orthogonal array. The poros-ity was observed to increase with the content of graphite added as pore-forming material and decrease with increasing talc size. The effects of the other factors the graphite size sintering temperature and hold-ing time at sintering temperature were observed to be small relatively. In case of mean pore size the ef-fect of talc size on the mean pore size of cordierity was investigated to be the largest. The mean pore size was observed to increase with increasing talc size.

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Adsorption of Carbon Dioxide onto Tetraethylenepentamine Impregnated PMMA Sorbents with Different Pore Structure

  • Jo, Dong Hyun;Park, Cheonggi;Jung, Hyunchul;Kim, Sung Hyun
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.382-390
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    • 2015
  • Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.

Development of Scent Display Device using Micro-pore Piezo Actuator (마이크로 다공성 압전 진동자를 이용한 발향장치 설계)

  • Lee, Young-Joon;Lim, Seung-Ju;Kim, Min-Ku;Lee, Hae-Lyong;Kim, Jeong-Do
    • Journal of Sensor Science and Technology
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    • v.25 no.6
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    • pp.399-405
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    • 2016
  • Scent diffuser using micro-pore piezo actuator achieved a commercial success because of its cheap production cost, but it is easy to be use for IT-based contents due to difficulty of scent intensity control. To solve this problem, we control the emission amount of scent diffuser by changing amplitude and frequency of input voltage applied to micro-pore piezo actuator. And, we analyzed the effect of density of cotton core on emission amount and a relationship between hole-size of mesh in piezo actuator and viscosity of scents to design a mechanically optimal scent device.

Advances in the design of macroporous polymer scaffolds for potential applications in dentistry

  • Bencherif, Sidi A.;Braschler, Thomas M.;Renaud, Philippe
    • Journal of Periodontal and Implant Science
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    • v.43 no.6
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    • pp.251-261
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    • 2013
  • A paradigm shift is taking place in medicine and dentistry from using synthetic implants and tissue grafts to a tissue engineering approach that uses degradable porous three-dimensional (3D) material hydrogels integrated with cells and bioactive factors to regenerate tissues such as dental bone and other oral tissues. Hydrogels have been established as a biomaterial of choice for many years, as they offer diverse properties that make them ideal in regenerative medicine, including dental applications. Being highly biocompatible and similar to native extracellular matrix, hydrogels have emerged as ideal candidates in the design of 3D scaffolds for tissue regeneration and drug delivery applications. However, precise control over hydrogel properties, such as porosity, pore size, and pore interconnectivity, remains a challenge. Traditional techniques for creating conventional crosslinked polymers have demonstrated limited success in the formation of hydrogels with large pore size, thus limiting cellular infiltration, tissue ingrowth, vascularization, and matrix mineralization (in the case of bone) of tissue-engineered constructs. Emerging technologies have demonstrated the ability to control microarchitectural features in hydrogels such as the creation of large pore size, porosity, and pore interconnectivity, thus allowing the creation of engineered hydrogel scaffolds with a structure and function closely mimicking native tissues. In this review, we explore the various technologies available for the preparation of macroporous scaffolds and their potential applications.

Effects of Soil Compaction and Artificial Pore Space on the Shoot Density of Tall Fescue (Tall fescue의 밀도변화에 미치는 토양경화와 공극률의 영향)

  • 이주삼;윤용재;김성규;윤익석
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.7 no.2
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    • pp.109-112
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    • 1987
  • This experiment was to study the effects of soil compaction and artificial pore space on the shoot density of tall fescue (Festuca arundinacea Schreb.). Tall fescue subjected to compaction treatments with control, 10, 20 and 40 kg power roller, used for two times bi-weekly during six months. Artificial pore space treatments were control, 13.5, 37.5 and 84.5% at 0-lOcm depth, respectively. 1. Soil compaction increased soil hardness and soil bulk density.2. Compaction level of lOkg (soil hardness 2.5kg/$cm^3$) showed the highest shoot density than that of other treatments. 3. Artificial pore space was positive significant correlated (p<0.01) with shoot density. 4. When over the 37.5% of total pore space could be mainternance for high shoot density after the soil compacted.

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