• 제목/요약/키워드: Polyvinylpyrrolidone

검색결과 194건 처리시간 0.025초

Electrical Characteristics of Organic Thin-film Transistors with Polyvinylpyrrolidone as a Gate Insulator

  • Choi, Jong-Sun
    • Journal of Information Display
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    • 제9권4호
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    • pp.35-38
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    • 2008
  • This paper reports the electrical characteristics of polyvinylpyrrolidone (PVPy) and the performance of organic thin-film transistors (OTFTs) with PVPy as a gate insulator. PVPy shows a dielectric constant of about 3 and contributes to the upright growth of pentacene molecules with $15.3\AA$ interplanar spacing. OTFT with PVPy exhibited a field-effect mobility of 0.23 $cm^2$/Vs in the saturation regime and a threshold voltage of -12.7 V. It is notable that there was hardly any threshold voltage shift in the gate voltage sweep direction. Based on this reliable evidence, PVPy is proposed as a new gate insulator for reliable and high-performance OTFTs.

사진용(寫眞用) 제라틴과 Polyvinylpyrrolidone으로 제조(製造)된 사진유제(寫眞乳劑)의 할로겐은(銀) 결정(結晶) 및 사진특성(寫眞特性) 연구(硏究) (A Study on the Photographic Characteristics and Crystalline Forms about Photographic Emulsion Prepared from Photographic Gelatine with Polyvinylpyrrolidone)

  • 강태성
    • 대한방사선기술학회지:방사선기술과학
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    • 제1권1호
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    • pp.55-59
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    • 1978
  • The photographic characteristics have been studied in relation with various molecular weights of Polyvinylpyrrolidone(PVP). The shape of silver halogen crystals by physical ripening of mixture of photographic gelatine and various molecular weights of PVP were observed. Then, the photographic characteristics have been studied by chemical ripening. Results were concluded as follows: 1. All of the crystals have formed in the shape of (100) or (111). 2. Photographic characteristics were inferior by using PVP of higher molecular weight. 3. Photographic characteristics were superior by using PVP of lower molecular weight. 4. Photographic characteristic were compared with various Emulsion thickness and Tested Resolving power.

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Effect of metal primers and tarnish treatment on bonding between dental alloys and veneer resin

  • Choo, Seung-Sik;Huh, Yoon-Hyuk;Cho, Lee-Ra;Park, Chan-Jin
    • The Journal of Advanced Prosthodontics
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    • 제7권5호
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    • pp.392-399
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    • 2015
  • PURPOSE. The aim of this study was to evaluate the effect of metal primers on the bonding of dental alloys and veneer resin. Polyvinylpyrrolidone solution's tarnish effect on bonding strength was also investigated. MATERIALS AND METHODS. Disk-shape metal specimens (diameter 8 mm, thickness 1.5 mm) were made from 3 kinds of alloy (Co-Cr, Ti and Au-Ag-Pd alloy) and divided into 4 groups per each alloy. Half specimens (n=12 per group) in tarnished group were immersed into polyvinylpyrrolidone solution for 24 hours. In Co-Cr and Ti-alloy, Alloy Primer (MDP + VBATDT) and MAC-Bond II (MAC-10) were applied, while Alloy Primer and V-Primer (VBATDT) were applied to Au-Ag-Pd alloys. After surface treatment, veneering composite resin were applied and shear bond strength test were conducted. RESULTS. Alloy Primer showed higher shear bond strength than MAC-Bond II in Co-Cr alloys and Au-Ag-Pd alloy (P<.05). However, in Ti alloy, there was no significant difference between Alloy Primer and MAC-Bond II. Tarnished Co-Cr and Au-Ag-Pd alloy surfaces presented significantly decreased shear bond strength. CONCLUSION. Combined use of MDP and VBATDT were effective in bonding of the resin to Co-Cr and Au-Ag-Pd alloy. Tarnish using polyvinylpyrrolidone solution negatively affected on the bonding of veneer resin to Co-Cr and Au-Ag-Pd alloys.

Rifampicin-Polyvinylpyrrolidone 공침물에 관한 생물약제학적 연구 (A Biopharmaceutical Study on Rifampicin-Polyvinylpyrrolidone Coprecipitate)

  • 김영일
    • 약학회지
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    • 제23권2호
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    • pp.81-94
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    • 1979
  • Rifampicin-polyvinylpyrrolidone coprecipitates were prepared by the solvent method to increase the solubility and dissolution rate, thereby improving absorption of rifampicin. It was found that the solubility and dissolution rate were greater with the 1 : 5 (w/w) coprecipitate than with the pure drug, physical mixtures or coprecipitates of any other ratio of the two components. The blood concentration data in non-fasted rats showed that the extent of absorption of rifampicin were significantly enhanced following the oral administration of the 1 : 5 coprecipitate; The area under the serum concentration curve (0-8hr) was 1.3 times greater with the 1 : 5 coprecipitate than with the pure drug. The blood concentration reached its peak (4. 38$\pm$1.36mcg/ml) within two hours in the case of oral administration of the 1 : 5 coprecipitate and, on the other hand, it reached the maximum (3.77$\pm$0.90mcg/ml) after four hours of oral administration of the pure drug. It was observed that there was no significant difference between the 1 : 5 coprecipitate and the pure drug in the extent and rate of absorption of rifampicin when fasted rats were used. When the 1 : 5 coprecipitate was orally administered to human subjects 20 minutes after meal, it was found that the blood concentration reached the maximum after one hour; in the case of the pure drug, it reached its peak after four hours.

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연료전지용 Pt/C 촉매 합성에 있어서 PVP가 Pt 나노입자의 분산 및 촉매 활성에 미치는 영향 (Effect of PVP on the Dispersity of Pt Nanoparticles and Catalytic Activity in Synthesis of Pt/C Catalysts for Fuel Cell)

  • 임영민;박남희;유연태
    • 한국재료학회지
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    • 제18권8호
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    • pp.401-405
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    • 2008
  • Pt-loaded carbon black for the catalyst of a PEM fuel cell was synthesized with different molar ratios of polyvinylpyrrolidone and $H_2PtCl_6$ solution to improve the dispersion of Pt nanoparticles on carbon black and decrease the size of Pt nanoparticles. From transmission electron microscopy results, Pt nanoparticles of a size of approximately 2 nm were highly dispersed when the polyvinylpyrrolidone concentration was 10mM. The electrochemical activity of the synthesized Pt/C catalysts was investigated by cyclic voltammetry, showing that the as-synthesized Pt-loaded carbon black catalyst had the best activity at a polyvinylpyrrolidone concentration of 10 mM.

Polyvinylpyrrolidone 첨가가 돼지 체외 수정란의 발달과 세포수에 미치는 영향 (Effect of the Addition of Polyvinylpyrrolidone on In Vitro Development and Cell Number of Porcine Embryo after In Vitro Fertilizatin)

  • 박용수;김재영;박흠대
    • 한국수정란이식학회지
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    • 제21권2호
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    • pp.121-128
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    • 2006
  • 본 연구는 고품질의 돼지 체외 수정란을 생산하기 위하여 체외 성숙 배지에 첨가하는 polyvinylpyrrolidone(PVP)의 분자량, 첨가 농도 및 시간(실험 1)과 체외 성숙 수정 배양 단계에서 PVP의 첨가(실험 2)가 배 발생과 세포수에 미치는 효과를 검토하였다. 돼지 미성숙 난자의 체외 성숙은 NCSU 23 용액, 체외 수정은 mTBM 용액, 체외 배양은 PZM 3 용액을 이용하였다. 체외 성숙용 배지에서 PVP의 분자량, 농도 및 첨가 시간에 따른 수정율과 배반포 발달율은 차이가 없었다. 그러나 배반포의 부화율은 분자량 40,000(30.1%), 0.5%(28.6%) 및 $0{\sim}44$시간(37.5%) 첨가군이 다른 시험군에 비하여 유의하게 높았다(p<0.05). 분자량 40,000 0.5% PVP를 체외성숙, 수정 및 배양 배지에 각각 첨가(W) 또는 미첨가(W/O)한 결과, 수정율은 체외성숙 수정 배양에서 W-W/O-W 군이 69.3%, 배반포 발달율과 부화율은 W-W/O-W 및 W-W/O-W/O 군이 각각 12.6과 30.0% 및 14.0과 37.5%로서 다른 군에 비하여 유의하게 높았다(p<0.05). 총 세포 수와 Trophoblast 수는 처리군 간에 유사한 경향이었으나, Inner cell mass 수는 W/O-W/O-W 군이 평균 7.4개로서 가장 높았다 (p<0.05).

Efficient and Regioselective Ring-Opening of Epoxides with Alcohols and Sodium Azide by using Catalytic Amounts of GaCl3/Polyvinylpyrrolidone

  • Pourali, Ali Reza;Ghayeni, Samaneh;Afghahi, Fatemeh
    • Bulletin of the Korean Chemical Society
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    • 제34권6호
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    • pp.1741-1744
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    • 2013
  • A new polymeric catalyst was prepared by supporting $GaCl_3$ on cross-linked polyvinylpyrrolidone ($GaCl_3$/PVP). This catalyst was employed for efficient and regioselective ring-opening reaction of epoxides by various alcohols under solvent-free conditions at room temperature. In our procedure, this heterogeneous catalyst was used at neutral and mild reaction conditions to afford high yields of ${\beta}$-alkoxy alcohols. Also, regioselective conversion of epoxides to ${\beta}$-azidohydrines was accomplished by sodium azide in MeOH in the presence of $GaCl_3$/PVP at room temperature. $GaCl_3$/PVP is a non-hygroscopic and recoverable catalyst and is easily separated from reaction mixture by a simple filtration and re-used repeatedly. Also, this catalyst has good handling and can be stored for long time without any reducing of its reactivity.

Preparation of Silver Nanocolloids Using Silver Alkylcarbamate Complex in Organic Medium with PVP Stabilizer

  • Park, Hyung-Seok;Park, Heon-Su;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • 제31권9호
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    • pp.2575-2580
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    • 2010
  • We present a method for chemically reducing silver alkylcarbamate complex with hydrazine to synthesize silver nanocolloids in an organic solvent using polyvinylpyrrolidone (PVP) as the stabilizer. To determine the optimal conditions for preparing stable silver colloids of controlled size and shape, the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, hydrazine, and 2-propanol solvent concentrations in the reaction mixture were varied. The initial colloid has a mean particle diameter of 5-80 nm, and it exhibits an absorption band with various shapes in the UV region with a maximum near 420 nm. UV-vis spectroscopy, TEM, and X-ray diffraction techniques were used to investigate the formation and growth process of the metallic silver nanocolloids.

PVP가 첨가된 탄소나노유체의 특성에 대한 연구 (Characteristics of Carbon Nano Fluid Added PVP)

  • 서향민;박성식;김남진
    • 설비공학논문집
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    • 제22권5호
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    • pp.289-295
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    • 2010
  • In this study, the enhancement of the thermal conductivity of water in the presence of multi-walled carbon nanotubes, MWCNT, was investigated. Sodium Dodecyl Sulfate, SDS, and Polyvinylpyrrolidone, PVP, were employed as the dispersant. SDS or PVP was added in pure water. And then, MWCNT of 0.0005, 0.001, 0.002, 0.003, 0.004, 0.005, 0.01, and 0.02 vol% was dispersed respectively. The thermal conductivity and the viscosity were measured with a transient hot-wire instrument built for this study and the DV II+ Pro viscometer. The results showed that PVP had good thermal conductivity at 300 wt% and this was better than that of SDS 100 wt%, also, the viscosity of nano fluid added PVP rapidly increased until 0.02 vol%.