• Title/Summary/Keyword: Polypropylene solution

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A Research on Reflectivity of Microcellular Polypropylene (MCPs의 반사 특성에 관한 연구)

  • Seo Jung-Hwan;Cha Sung-W.;Kim Hak-Bin
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1367-1370
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    • 2005
  • Microcellular foam processing of polymers requires a nucleated cell density greater than $10^9\;cells/cm^3$ so that the fully grown cells are smaller than 10 mm. A microcellular foam can be developed by first saturating a polymer sample with a volatile blowing agent, followed by rapidly decreasing its solubility in the polymer. In general, the cellular structure of crystalline polymer foams is difficult to control, compared to that of amorphous polymer foams. Since the gas does not dissolved in the crystallites, the polymer/gas solution formed during the microcellular processing is nonuniform. Moreover, the bubble nucleation is nonhomogeneous because of the heterogeneous nature of the crystalline polymer. In this paper, the effects of the crystallinity and morphology of crystalline polymers on the microcellular foam processing and on reflectivity of products are investigated. First, polymer specimens with various morphology and amount of solved blowing agent were prepared by varying the saturation pressure, saturation time and foaming condition. Then, cell morphologies according to several conditions were studied. The specimens with differing gas amount of solved and morphologies were foamed and their cellular structures were compared. The experimental results of reflectivity are compared to raw specimen and another specimen of different experimental conditions. After the experiments, recognize whether how reflectivity changes according to solved gas amount. And the effect of cell density and cell size on reflectivity is studied

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Microstructure-Sound Absorption Relationships of Polyurethane Foam and Application of Low Monos Polyol (폴리우레탄 폼의 미세구조와 흡음 관계 밑 Low Monos 폴리올의 응용)

  • Lee, Boo-Youn;Kim, So-Yeon;Lee, Kwang-Hee;Jin, Byung-Suk
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.289-296
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    • 2007
  • The material factors influencing the sound absorption of the polyurethane foam were investigated with FT-IR, small-angle X-ray scattering (SAXS), and dynamic mechanical thermal analyzer (DMTA). The measurements were performed using the samples which had a similar cell structure but different absorption coefficients. It was found that the ability of the sound absorption of the polyurethane foams was closely related to the damping behavior over the transition range. In order to confirm the use of the low monol polyol (LMP) in high-performance applications, the polyurethanes based on LMP and polypropylene oxide polyol (PPG) were prepared by the solution polymerization method. The microstructure and the physical properties of these polyurethanes were compared. The PPG-based polyurethane showed a higher level of the phase-separated structure because the considerable amount of monol presented in PPG made a contribution to the increased chain mobility. However the short chains formed due to the monol species deteriorated the damping property. As a result, the LMP-based polyurethane showed the superior damping behavior as compared with the PPG-based one.

Elasticity of the Funnel Ribs and Hydrodynamic Characteristics on the Sea Eel Pots (장어통발의 깔대기 탄성과 유체역학적 특성)

  • Kim, Yong-Hae;Ha, Jeong-Sik
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.23 no.4
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    • pp.157-162
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    • 1987
  • The basic experiments on the plastic sea eel pots used in fishing were carried out in order to investigate the elasticity of the funnel ribs, hydrodynamic resistance, sinking time and diffusion of the bait from June to October, 1987. The elasticity of the bamboo funnel ribs was higher than that of the polypropylene ribs up to the load 150g. The hydrodynamic resistance R (kg) of the pots towing to the head direction horizontally in relation to towing velocity V (m/sec) was expressed as following formula; R=0.36V super(2.01) and coefficient of drag C sub(D) was 0.52. The sinking times of the covered pots by tape fully or partially were late 1-2 second than the typical pots within the water depth 7.5m. The diffusion tendency through the covered pots using dye and sardine extracts solution was concentrated to the entrance more than the typical pots. However, fishing efficiency as number and weight of fish per pots for nine times fishing operation was revealed no difference between the covered pots and the typical pots.

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Study on the High Temperature Properties of Fireproof Mortar Using Various Types of Fine Aggregate (잔골재 종류에 따른 내화피복용 모르타르의 고온 성상에 관한 연구)

  • Lim, Seo-Hyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.2
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    • pp.100-106
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    • 2014
  • High strength concrete has a structural advantage as well as superior usability and durability, so that its application in building is being steadily augmented. However, in the high temperature like in a fire, the high strength concrete has extreme danger named explosive spalling. It is known that the major cause of explosive spalling is water vapour pressure inside concrete. General solution for preventing concrete from spalling include applying fire protection coats to concrete in order to control the rising temperature of members in case of fire. The purpose of this study is to investigate the high temperature properties of fireproof mortar using organic fiber and various types of fine aggregate for fire protection covering material. The results showed that addition of perlite and polypropylene fiber to mortar modifies its pore structure and reduces its density. This causes the internal temperature to rise. As a results, it is found that a new fireproof mortar can be used in the fire protection covering material in high strength concrete.

Development of Long-Term Storage Technology for Chinese Cabbage - Physiological Characteristics of Postharvest Freshness in a Cooler with a Monitoring and Control Interface

  • Lim, Ki Taek;Kim, Jangho;Chung, Jong Hoon
    • Journal of Biosystems Engineering
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    • v.39 no.3
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    • pp.194-204
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    • 2014
  • Purpose: The aim of this study was to develop long-term storage technology for Chinese cabbage in order to extend the period of availability of freshly harvested products. The scope of the paper deals with the use of a cooler with a remote monitoring and control interface in conjunction with use of packaging film. Methods: A cooler with a real time monitoring system was designed as a low-temperature storage facility to control temperature and relative humidity (RH). The effects of storage in high-density polyethylene (HDPE) plastic boxes, 3% chitosan dipping solution, polypropylene film (PEF) with perforations, and mesh packaging bags on physiological responses were investigated. The optimal storage temperature and humidity for 120 days were below $0.5^{\circ}C$ and 90%, respectively. Physiological and biochemical features of cabbage quality were also analyzed: weight loss, texture, and sugar salinity, chlorophyll, reducing sugar, and vitamin C contents. Results: The cooler with a remote monitoring and control interface could be operated by an HMI program. A $0.5^{\circ}C$ temperature and 90% humidity could be remotely controlled within the cooler for 120 days. Postharvest freshness of Chinese cabbages could be maintained up to 120 days depending on the packaging method and operation of the remote monitoring system. In particular, wrapping the cabbages in PEF with perforations resulted in a less than a 5% deterioration in quality. This study provides evidence for efficient performance of plastic films in minimizing post-harvest deterioration and maintaining overall quality of cabbages stored under precise low-temperature conditions with remote monitoring and a control interface. Conclusions: Packaging with a modified plastic film and storage in a precisely controlled cooler with a remote monitoring and control interface could slow down the physiological factors that cause adverse quality changes and thereby increase the shelf life of Chinese cabbage.

A Time-temperature Indicator for A Vision Based-Detection System for Managing the Storage Temperature of Frozen Fish Products (냉동 수산물의 저장 온도 관리를 위한 Time-temperature Indicator와 비전 기반 Indicator 분석 프로그램 개발)

  • Jang, Myung-Kee;Hong, Chang-Wook;Choi, Jae-Hyuk;Kim, Koth-Bong-Woo-Ri;Choi, Jeong-Wook;Nam, Taek-Jeong;Ahn, Dong-Hyun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.51 no.1
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    • pp.91-94
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    • 2018
  • We develop a time-temperature indicator (TTI) that can determine whether thawing of fish and other fishery products has occurred during frozen storage. A polypropylene tube with an internal diameter of 3 mm was prepared and cut to a length of 14 to 20 mm. One end of the tube was thermally sealed and 0.1% acetic acid was injected into the other end; the tube was then frozen at $20^{\circ}C$. Then the open side of the frozen tube was blocked by sinking the tube into a 10% gelatin solution. The tube was attached to a polyvinyl packaging bag along blue litmus paper and the bag was put into a freezer at $-20^{\circ}C$. After freezing, the bag was removed to an ambient temperature of $20^{\circ}C$, and the time dependence of the color change of the litmus paper was observed. The color changed from blue to red, with the length of the red region increasing with time. Our TTI can be used as a part of a visible detection system and the detection program can conduct the elapsed time analysis on the length of the red region of the litmus paper indicating the degree of thawing. Thus, the TTI is a useful tool in the temperature management of frozen fish and fishery products.

Changes in postharvest quality of Pleurotus eryngii treated with different shelf temperature and browning inhibitors (큰느타리버섯 유통온도 및 갈변억제처리에 따른 품질 변화)

  • Lee, Yun-Hae;Jeoung, Yun-Kyeoung;Baek, Il-Sun;Lee, Han-Bum;Chi, Jeong-Hyun;Jhune, Chang-Sung
    • Journal of Mushroom
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    • v.11 no.4
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    • pp.297-302
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    • 2013
  • Pleurotus eryngii is one of the main export items in Korean mushroom industry. Whole mushrooms were packed with 30 um polypropylene anti-fog film without trimming. The range of package weight and oxygen permeability of film were 400 g and 2000 $c/m^2$, 24 h,atm, respectively. The anti-browning treatments were sprayed by 0.5%(w/w) solution of Sporix Sporix(Sodium polyphosphate and $ClO_2$ gas The weight loss ratio was increased with increasing shelf period and temperature. There were no big differences in weight loss ratio according to browning inhibitors. In case of $ClO_2$ treatment, the hardness and lightness of stem was showed higher than other treatment for shelf period. As results of freshness, the optimum browning inhibitor of P. eryngii was $ClO_2$ treatment and the shelf life was extended 36days at $10{\sim}15^{\circ}C$.

Preparation of Self-Cleaning Coating Films with Nano- and Microstructure (나노마이크로 구조의 자기세정 기능성 코팅막의 제조)

  • Jeong, A-Rong;Kim, Jun-Su;Yun, Jon-Do
    • Korean Journal of Materials Research
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    • v.22 no.8
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    • pp.416-420
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    • 2012
  • Recently nanoscience and nanotechnology have been studied intensively, and many plants, insects, and animals in nature have been found to have nanostructures in their bodies. Among them, lotus leaves have a unique nanostructure and microstructure in combination and show superhydrophobicity and a self-cleaning function to wipe and clean impurities on their surfaces. Coating films with combined nanostructures and microstructures resembling those of lotus leaves may also have superhydrophobicity and self-cleaning functions; as a result, they could be used in various applications, such as in outfits, tents, building walls, or exterior surfaces of transportation vehicles like cars, ships, or airplanes. In this study, coating films were prepared by dip coating method using polypropylene polymers dissolved in a mixture of solvent, xylene and non-solvent, methylethylketon, and ethanol. Additionally, attempts were made to prepare nanostructures on top of microstructures by coating with the same coating solution with an addition of carbon nanotubes, or by applying a carbon nanotube over-coat on polymer coating films. Coating films prepared without carbon nanotubes were found to have superhydrophobicity, with a water contact angle of $152^{\circ}$ and sliding angle less than $2^{\circ}$. Coating films prepared with carbon nanotubes were also found to have a similar degree of superhydrophobicity, with a water contact angle of 150 degrees and a sliding angle of 3 degrees.

Modification and Properties of Polyolefin with Maleic Anhydride as a Functional Monomer (관능성 단량체로서 Maleic Anhydride를 이용한 Polyolefin의 개질 및 물성)

  • Mo, Jong-Hun;Lee, Jae-Seok;Choi, Im-Cheol;Lee, Won-Kee;Park, Sang-Bo;Min, Seong-Kee;Park, Chan-Young
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.162-167
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    • 2012
  • Surface modification of macromolecules renders a progressive and favorable method to enhance the properties of polymeric materials and improves conductivity, wettability, stability, adhesion, antibacterial properties, etc. of polymeric surfaces without deterioration of the polymer bulk properties. Polyolefins such as polyethylene and polypropylene were grafted with maleic anhydride(MAH) as a functional monomer in solution. Evidence for grafting was shown with FTIR measurement. The grafting ratio was determined from chemical titration. The higher MAH loading, the lower contact angle(${\theta}$) was obtained. With the increasing content of MAH, melting temperature($T_m$) of maleic anhydride grafted polymer decreased while decomposition temperature($T_d$) of maleic anhydride grafted polymer increased.

Advanced Water Treatment by Hybrid Process of Multi-channel Ceramic MF and Photocatalyst: Effect of Organic Materials (광촉매 및 다채널 세라믹 정밀여과 혼성공정에 의한 고탁도 원수의 고도정수처리: 유기물의 영향)

  • Amarsanaa, Bolor;Park, Jin-Yong
    • Membrane Journal
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    • v.21 no.4
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    • pp.351-359
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    • 2011
  • For advanced drinking water treatment of high turbidity water, we used the hybrid process that was composed of photocatalyst packing in space of between outside of multi-channel ceramic microfiltration membrane and membrane module inside. Photocatalyst was polypropylene (PP) beads coated $TiO_2$ powder by CVD (chemical vapor deposition) process. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, standard NOM solution was prepared with humic acid and kaolin. Water-back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling. Resistance of membrane fouling ($R_f$) increased and J decreased as concentration of humic acid changed from 2 mg/L to 10 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L. Then, treatment efficiency of turbidity and $UV_{254}$ absorbance were above 96.4% and 78.9%, respectively. As results of treatment portions by membrane filtration, photocatalyst adsorption, and photo-oxidation in (MF), (MF + $TiO_2$), (MF + $TiO_2$ + UV) processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of $UV_{254}$ absorbance by adsorption (MF + $TiO_2$) and photo-oxidation (MF + $TiO_2$ + UV) at humic acid of 4 mg/L and 6 mg/L were above 9.0, 9.5 and 8.1, 10.9%, respectively.