• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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• pp.116-120
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• 2005

In this study, composites with polypropylene(PP) and Jute fiber were prepared by compression molding technique. Generally, hydrophilic jute fibers do not adhere well to PP, which is hydrophobic. Maleic anhydride grafted polypropylene(MAPP) had been widely used as a coupling agent to improve the bonding between ligno-cellulosic fibers and PP. The coupling agent improved the tensile and flexural properties when the mechanical properties were tested by using a UTM. The mechanical properties of natural fiber composites(NFCs) by modified thermoplastics were higher than those of NFCs by unmodified thermoplastics. Fracture surfaces of the composites and the fiber orientations were investigated by scanning electron microscopy. The mechanical performance of NFCs by modified thermoplastics appeared to be improved by the enhanced interface adhesion between the fiber and the matrix.

• Korea-Australia Rheology Journal
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• 제13권2호
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• pp.61-65
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• 2001

Thermoplastic nanocomposites based on the copolymers of polypropylene (PP)-polystyrene (PS) and organically modified montmorillonite (org-MMT) were produced by using power ultrasonic wave in an intensive mixer. Owing to the unique action of the ultrasonic wave, free radicals of styrene monomers and macroradicals of PP were generated, by which copolymers of PP and PS were formed. Another important aspect of using ultrasonic wave during the mixing process was to enhance nano-scale dispersion of org-MMT by destructing the agglomerates of org-MMT in the polymer matrix. Optimum conditions for the in-situ copolymerization and melt intercalation were studied with various concentrations of styrene monomer, sonication time and different kinds of clay. It was found that a novel attempt carried out in this study yielded further improvement in the mechanical performance of the nanocomposites compared to those produced by the conventional melt mixing process.

• 한국안전학회지
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• 제25권4호
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• pp.48-60
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• 2010

The fire resistance performance of 2 RC slabs after exposure to the ISO-834 fire standard without loading has been experimentally investigated. A Comparison is made of the fire resistance performance between RC slabs without PP(polypropylene) fibers and RC slabs with PP fibers. From the fire test results, the presence of PP fibers in RC slabs can reduce spalling and enhance their fire resistance. Until now, the determination of fire resistance of reinforced concrete(RC) slabs has essentially been based on tabulated data. According to ACI 216 code and EUROCODE 2, the design of concrete structures is essentially based on tabulated data for appropriate concrete cover and various fire durations. From the comparison between fire test results and codes, current fire design provisions of codes such as the ACI 216 and the EUROCODE 2 are unconservative for estimating mechanical properties of RC slabs at elevated temperatures.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.375-375
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• 2006

The preparation methods are to be used as "melting method" and "absorption method", respectively. The reaction mixture in the reaction container was heating up the reaction mixture to $200^{\circ}C$ for 2 hour. The mixing time of lab scale preparation should be provided quit long, instead of the short working time in a compounder vessel. And The PP-PCM mixture in the reaction container was heating up the mixture around $60-80^{\circ}C$ for 2 hour. A melting method of frozen gel with 50/50 weight ratio of polypropylene-normal octadecane was prepared by adding PP chip and normal octadecane. An absorption method of frozen gel with 70/30 weight ratio of PP 4.8-normal n-octadecane was prepared by adding PP powder and normal octadecnae.

• 유변학
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• 제4권2호
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• pp.148-160
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• 1992

폴리프로필렌(PP)과 폴리에틸렌(PE)혼합물의 용융방사에 있어서 불안정성을 연구하 였으며 혼합물의 유변학적 성질, 혼합물의 형태학적 특성과 연신공명과의 관계를 고찰한 것 이다. 신장점도는 spinline rheometer를 사용하여 측정하여 섬유직경은 광센서를 이용하여 방사공정에서 on-line 측정하였고 연신공명의 주기는 Fourier 변환을 이용하여 분석하였다. PP와 PE혼합물의 용융방사에 있어서 PP 함유량이 많을수록 연신공명이 발생하는 임계연신 비가 줄어들고 그 주기는 길어진다. 정상상태에서 구한 유변학적 성질을 이용하여 Shah와 Pearson의 이론식과 Fisher와 Denn의 이론식으로부터 구한 임계연신비값이 실험치와 많은 차이를 보여주었다. 연신공명에 의하여 형성된 섬유의 가는 부분의 배향도는 굵은 부분에 비하여 크게 향상되었으며 PP 함유량이 많을수록 배향도가 크게 증가하였다.

• 폴리머
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• 제25권2호
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• pp.226-232
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• 2001

The properties of poly(ethylene terephthalate) (PET)/maleic anhydride-grafted polypropylene (MAgPP)/poly(styrene-co-maleic anhydride)(PScMA) ternary blend were investigated. The ternary blend was immiscible based on the glass transition temperatures measured by dynamic mechanical analyzer (DMA). The degradation of MAgPP during melt mixing for 30 min at 280$^{\circ}C$ did not affect the properties of the ternary blend. The interaction among the components was confirmed from the rheological properties, which was increased with the PSCMA contents. In terms of the mechanical properties, it was observed to satisfy the mixture rule for a multiple system.

• International Journal of Automotive Technology
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• 제7권4호
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• pp.485-492
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• 2006

The AA5182/polypropylene/AA5182(AA/PP/AA) sandwich sheets have been developed for application to automotive body panels in future lightweight vehicles with significant weight reduction. It has been reported that the AA5182 aluminum sheet shows $L\"{u}ders$ band because of dissolved Mg atoms that cause fabrication process problem, especially surface roughness. The examination of serration behavior has been made after the tensile deformation of the AA/PP/AA sandwich sheets as well as that of the AA5182 aluminum skins at room and elevated temperatures. All sandwich sheets and the AA5182 aluminum skin showed serration behavior on their flow curves. However, the magnitude of serration was significantly diminished in the sandwich sheet with high volume fraction of the polypropylene core. According to the results of the analysis of the surface roughness following the tensile test, $L\"{u}ders$ band depth of the sandwich sheet evidently showed lower than that of the AA5182 aluminum skin. The strain rate sensitivity, m-value, of the AA5182 aluminum skin was -0.006. By attaching these skins to the polypropylene core, which has relatively large positive value of 0.050, m-value of the sandwich sheets changed to the positive value. The serration mechanism of the sandwich sheets was quantitatively investigated in the point of the effect on polypropylene thickness variation, that on the strain rate sensitivity and that on the localized stress state.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 가을 학술발표회 논문집
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• pp.307-308
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• 2003

Improved wettability and dyeability of Polypropylene(PP) fabrics were obtained using glow discharge plasma by grafting nitrogen-containing active groups on the surface. Few studies of glow discharge plasma on PP fabrics exist. The objective of this study was to give a fabric a good affinity for water. (omitted)

• 공업화학
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• 제22권6호
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• pp.679-684
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• 2011

고상(solid state) 반응과 용융(melt state) 반응을 이용하여 장쇄분지(long chain branch, LCB)를 가지는 분지화된 폴리프로필렌(branched polypropylene, LCB-PP)을 제조하였다. 분지제(branching agent)로는 divinylbenzene (DVB), 1,4-benzenediol (RES), furfuryl sulphide (FS)가, LCB-PP/실리케이트 복합체를 제조하기 위해서는 층상 실리케이트가 사용되었다. LCB-PP의 화학구조, 열적특성, 유변학적 특성을 적외선 분광기(FT-IR), 시차주사열용량분석기(DSC, TGA), 그리고 동적유변측정기(ARES)를 이용하여 분석하였다. LCB-PP의 화학구조는 $3100cm^{-1}$에서 나타나는 분지제의 =C-H 신축진동을 이용하여 확인하였다. DSC와 TGA의 결과로부터 고상반응보다 용융반응이 LCB-PP 제조에 보다 효과적이었고, 유변학적 특성을 통하여 추가 확인되었다. 분지제 중에서는 FS가 가장 효과적이었다. LCB-PP의 경우 낮은 전단속도 영역에서 점도와 shear thinning tendency가 증가하였고, G'-G" plot으로부터 탄성특성의 증가와 LCB의 도입에 의한 용융상태의 불균일성(heterogeneousness)을 확인할 수 있었다. LCB-PP/실리케이트 복합체의 실리케이트 함량에 따른 유변학적 특성을 관찰하였다. 실리케이트의 함량이 5 wt%인 경우 면찰 담화(shear thinning)와 G'-G" plot에서의 기울기 변화가 가장 크게 나타났다.

• 폴리머
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• 제39권1호
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• pp.64-70
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• 2015

열팽창 캡슐은 코어에 위치한 발포가스가 기화온도 이상이 될 경우 캡슐을 팽창시켜 상온상태보다 큰 부피를 지닌 형태를 이루게 되는데 이러한 특성을 이용하여 플라스틱의 발포소재로 적용이 가능하다. 본 연구에서는 자동차 내외장재 용도로 가장 많이 사용되는 폴리프로필렌(polypropylene, PP)을 베이스 원료로 하여 기존 화학발포제와 열팽창 캡슐을 이용하여 PP 폼을 제조하였으며, 제조된 시편의 물리적인 특성을 비교하였다. 화학 발포제와 열팽창 캡슐을 적용하여 제조된 PP 폼은 모두 첨가된 발포제 및 열팽창 캡슐 함량 증가에 따라 시편의 밀도가 감소하였고, 인장강도를 포함한 기계적 물성 또한 감소하였다. 하지만, 열팽창 캡슐을 이용해 제조된 PP 폼의 경우는 화학 발포제를 적용하여 만들어진 시편대비 충격강도 감소량이 크지 않았다. 발포제 종류별로 상이한 물리적 특성을 분석하기 위하여 PP 폼의 매트릭스를 분석하였으며, 다른 형상의 모폴로지를 관찰하였다.