• Title/Summary/Keyword: Polyolefin

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Embedment Properties of Reflective Beads for Thermoplastic Road Markings (열가소성 차선도장에서 반사유리알의 함침특성)

  • Hong, In Kwon;Lee, Chang Geun;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.26 no.2
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    • pp.199-204
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    • 2015
  • Thermoplastic road markings are one of the most widely used road markings in the world. However, the durability of domestic road markings is relatively shorter than that of the global average of, approximately, three years. To overcome it, the conventional thermoplastic road markings were prepared by adding polyolefin and oxidized PE wax to conventional petroleum resin. In addition, the melting viscosity was designed below 500 cP at $220^{\circ}C$ as well as the optimum viscosity for spray painting, and embedding ratio of glass beads were controlled about 50~60% by spraying in an interval of 1 second. Also the glass bead adhesive ratio was improved by reducing the amount of $CaCO_3$ below 40 wt%. The retroreflectivity was tested under four different conditions to evaluate the abrasion resistance of thermoplastic road markings. The retroreflectivity coefficient satisfied the international standard ($150mcd{\cdot}m^{-2}{\cdot}lux^{-1}$) in this study, and TPRM-7 was determined as an optimal ratio.

A Study on the Efficiency Estimation of Halogen free Fire Resistance Cable (저독성 내화전선 케이블의 성능평가에 관한 연구)

  • 윤헌주;홍진웅;유동일;윤재선;곽동일
    • Fire Science and Engineering
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    • v.16 no.1
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    • pp.18-23
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    • 2002
  • Efficiency estimation of toxicity free resistance cable experiments were conducts to understand toxicity free fire ersistance polyolefin insulation material and smoke density characteristic and combustion gas corrosion analysis. A main cause of fire-growth and generating toxic gas when it burns, should be dealt with great care in life safety design. Similar patterned fire incidents such as, Inchon Live-Hof Pub Restaurant as, Sea-land Children Resort have proven that serious loss of lives were caused by hazardous gas generated fire resistance cable materials. In this paper, Referenced documents were ASTM E662 standard test method for specific Ds genalated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of 2.5$\pm40.04〔w/$\textrm{cm}^2$〕for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 25.2 to 37.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. Also, the fire gases was occurred carbon monoxide and decomposition than in polyolefin due to incomplete combustion of PVC which has high content of carbon in chemical compound.

Modified Atmosphere Packaging of Minimally Processed Cut Garlic (최소가공된 절단 마늘의 환경기체조절포장)

  • Kwon, Min-Ji;Shin, Yong-Jae;Lee, Dong-Sun;An, Duck-Soon
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.17 no.1
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    • pp.13-17
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    • 2011
  • There is a need in food industry to store minimally processed garlic for long time to have it be used just at the time of demand for final product processing. Optimal modified atmosphere packaging is expected to slow down the quality change extending its storage life. In order to find optimal packaging conditions, plastic films of different gas permeability properties (low density polyethylene (LDPE) $30{\mu}m$, polyolefin $50{\mu}m$ (PD 900), polyolefin $20{\mu}m$ (PD 941)) were used for packaging 400 g of minimally processed garlic. Perforated LDPE packages were prepared as control. The packaged products were stored at $1{\pm}1^{\circ}C$ for 52 days. Package treatments were compared in weight loss, decay, surface color, hardness and soluble solid content. While control package had normal atmosphere of air, LDPE, PD 900 and PD 941 packages attained internal concentration of $O_2$ 4.6% / $CO_2$ 12%, $O_2$ 0.9% / $CO_2$ 21% and $O_2$ 0.5% / $CO_2$ 13% after 45 days, respectively. Control packaging had rapid weight loss with high mold decay and great surface color change in 45 days. In PD 900 film packages of lowest gas permeability, the fresh-cut garlic could be stored without mold decay for 52 days. Except control packaging, there were no significant differences in surface color, hardness and soluble solid content among package treatments.

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Effect of Heat Conservation of Greenhouse Film on Growth and Quality in Oriental Melon (필름두께 및 적외선 흡수율 차이가 참외의 품질 및 수량에 미치는 영향)

  • Shin, Yong-Seub;Yeon, Il-Kweon;Do, Han-Woo;Lee, Ji-Eun;Cheung, Jong-Do;Kang, Chan-Ku;Choi, Chung-Don;Chun, Hee;Choi, Young-Ha;Chung, Doo-Seok
    • Journal of Bio-Environment Control
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    • v.16 no.3
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    • pp.167-173
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    • 2007
  • This study was conducted to improve light environment of oriental melon cultivation in winter season. Three polyolefin foreign films (J-1, J-2, J-3) and three polyethylene domestic films (K-1, K-2, K-3) with different film thickness, ultraviolet ray interception and infrared ray absorption were used. As the result of this experiment, soluble solid of oriental melon fruit in K-3 was $14.3^{\circ}Brix$, those in J-3 and J-2 were higher by 1.3 and $0.8^{\circ}Brix$, respectively. Chromaticity (a value) of pericarp in K-3 was 0.5, those in J-3, J-1 and J-2 were higher by 3.3, 2.3 and 1.9, respectively. Especially, fermented and malformed fruit rates in J-1, J-2 and J-3 were decreased and marketable fruit rates were increased. Marketable yield in K-3 was 1,622 kg per 10a, those in J-1, J-3 and J-2 were increased by 31.2%, 23.8% and 18.5% compare to K-3, respectively. In this study, Polyolefin films (J-1, J-2, J-3) with thickness and infrared ray absorption ratio keeping higher heat conservation, therefore, soluble solid and chromaticity of fruit were increased, fermented fruit rate was decreased, and marketable fruit rate and yield were increased.

Effect of Microporous Structure of Al2O3/PVdF_HFP Ceramic Coating Layers on Thermal Stability and Electrochemical Performance of Composite Separators for Lithium-Ion Batteries (Al2O3/PVdF_HFP 세라믹코팅층의 미세기공구조가 리튬이차전지용 복합분리막의 열 안정성 및 전기화학특성에 미치는 영향)

  • Jeong, Hyun-Seok;Kim, Kyu-Chul;Lee, Sang-Young
    • Journal of the Korean Electrochemical Society
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    • v.12 no.4
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    • pp.324-328
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    • 2009
  • The internal short-circuit between cathodes and anodes has been known to be a critical concern for the safety failures of lithium-ion batteries, which is strongly influenced by the thermal stability of separators. In this study, to effectively suppress the internal short-circuit failures, we developed a new composite separator with the improved thermal stability compared to conventional polyolefin-based separators. The composite separators were prepared by introducing a ceramic coating layer ($Al_2O_3$/PVdF-HFP) onto both sides of a polyethylene (PE) separator. The microporous structure of ceramic coating layers is determined by controlling the phase inversion of coating solutions and becomes more developed with the increase of nonsolvent (water) content. This structural change of ceramic coating layers was observed to greatly affect the thermal stability as well as the electrochemical performance of composite separators, which was systematically discussed in terms of phase inversion.

Current Status and Future Research Directions of Separator Membranes for Lithium-Ion Rechargeable Batteries (리튬이차전지용 분리막 이해 및 최신 연구 동향)

  • Kim, Jung-Hwan;Lee, Sang-Young
    • Membrane Journal
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    • v.26 no.5
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    • pp.337-350
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    • 2016
  • Lithium-ion rechargeable batteries (LIBs) have garnered increasing attention with the rapid advancements in portable electronics, electric vehicles, and grid-scale energy storage systems which are expected to drastically change our future lives. This review describes a separator membrane, one of the key components in LIBs, in terms of porous structure and physicochemical properties, and its recent development trends are followed. The separator membrane is a kind of porous membrane that is positioned between a cathode and an anode. Its major functions involve electrical isolation between the electrodes while serving as an ionic transport channel that is filled with liquid electrolyte. The separator membranes are not directly involved in redox reactions of LIBs, however, their aforementioned roles significantly affect performance and safety of LIBs. A variety of research approaches have been recently conducted in separator membranes in order to further reinforce battery safeties and also widen chemical functionalities. This review starts with introduction to commercial polyolefin separators that are currently most widely used in LIBs. Based on this understanding, modified polyolefin separators, nonwoven separators, ceramic composite separators, and chemically active separators will be described, with special attention to their relationship with future research directions of advanced LIBs.

Changes in Light Transmittance of Greenhouse Covering Materials and Cucumber Growth as Affected by Particulate Matter (미세먼지 발생에 의한 온실 피복재의 광투과율 감소 및 오이 생육 변화)

  • Inseo Hong;Yoomin Ha;Yurina Kwack
    • Journal of Bio-Environment Control
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    • v.32 no.4
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    • pp.312-318
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    • 2023
  • In recent years, fine and yellow dust pollution has become serious in Korea and has negatively affected crop production. Particulate matter (PM) adheres to greenhouse coverings, and it reduces the amount of solar radiation transmitted into a greenhouse. A reduction in light transmittance can have a direct effect on crop photosynthesis and an indirect effect on air temperature in a greenhouse, which can lead to differences in crop yield. The objectives of this study were to investigate the changes in light transmittance of different cover materials by PM and to determine the changes in cucumber growth in a greenhouse due to reduced light transmittance. We measured the changes in light transmittance of polyethylene (PE) and polyolefin (PO) films in the PM generation chambers. Also, cucumber plants were cultivated in a greenhouse with four different light reduction treatments (0, 10, 20, and 30% reduction of light transmittance). The initial light transmittance of PO film was higher than that of PE film and the decrease in light transmittance of PO film due to PM was less than that of PE film. The vegetative growth of cucumber was promoted under the reduced light transmittance treatments; however, the yield of cucumber was highest in the control (0% reduction of light transmittance). From the results, we confirmed that PO film was less PM adhesion and that cucumber yield during the spring season can be reduced by the reduction in light transmittance due to PM.

The Characterization of Recycle PE/PET/TPE Blend with Compatibilizers (폐 PE/PET/TPE Blends 제조와 상용화에 따른 특성 분석)

  • Kim, Dong-Hyun;Hwang, In-Sung;Kim, Jeong-Hun
    • Journal of Digital Convergence
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    • v.10 no.10
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    • pp.423-430
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    • 2012
  • This study focused on the characterization of recycle PE/PET/TPE blend with compatibilizers. The heat resistance and impact strength of a weak point on PET/HDPE blend has been improved. TPE added polyester-based recycle heat-resistant properties to $150^{\circ}C$ showed more than $50^{\circ}C$ higher than HDPE added. Elastomer applied is a significant increase in the impact strength, and then it is possible to apply for safety materials in industries requiring heat-resistance and elasticity. Also using PET blend compatibilizer improves the strength of the polyolefin resin. The mechanical properties of recycle HDPE and PET blend has been greatly improved, and the reduction in the size of the dispersed phase by the addition of compatibilizers on morphology characteristics were observed uniformity becomes.

Study about decreasing methods of printing ink solvents residue amounts on plastic food package materials (플라스틱 포장재의 잔존 인쇄 용제 감소 방안)

  • An, Duek-Jun;Cho, Hoon-Il
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.10 no.1
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    • pp.1-6
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    • 2004
  • Amount of residual ink solvent on the packaging materials from Korea, Japan and Europe was measured and compared. The amount of packaging materials from Korea was much higher than that of Japan and Europe. To reduce the residual amounts of ink solvent, aging condition of printed packaging materials including aging time and temperature was modified and evaluated. Aging with high temperature and short time ($60^{\circ}C$ and 24 hours) was more effective for reduction of residual amount of ink solvent than that with low temperature and long time. To find out change of reduction pattern of residual amount of solvent according to plastic packaging material, several monolayer and multilayer packaging materials were selected. Among the monolayer packaging materials, the amount of EVOH and PET was lower than that of polyolefin plastic film including PE and PP. PP/EVOH/PET among the selected multilayer film showed the lowest amount of residual ink solvent on food packaging materials. Result of this research revealed that the residual amount of ink solvent can be reduced by proper selection of aging condition with and by appropriate application of mutilayer plastic film.

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Fire Resistance Characteristics of Polyolefin cable Insulating Materials for Flame Retardant (난연성 폴리 올레핀 케이블 절연재료의 내화특성)

  • Yoon, Hun-Ju;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.251-254
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    • 2001
  • In this paper, we analyzed the properties change of electric wire when the thermal stress was applied to NFR-8 and FR-PVC 600[V] wire. Messurement is made of the attenuation of a light beam by smoke accumulating with in a closed chamber due to nonflaming pyrolytic decomposition and flaming combustion. Results are expressed in terms of specific optical density which is derived from a geometrical factor and the measured optical density a measurement characteristic of the concentration of smoke. Referenced documents were ASTM E662 standard test method for specific Ds genalated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of $2.5{\pm}0.04[w/cm^{2}]$ for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 25.2 to 37.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. The amount of carbon monoxide generated was found to be much higher in FR-PVC decomposition than in NFR-8 due to incomplete combustion of FR-PVC which has high content of carbon in compound.

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