• Title/Summary/Keyword: Polyol

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A Study for Polyol-in-Oil Type Lip Makeup Cosmetics with Natural Pigments (천연색소를 함유하는 유중폴리올(Polyol-in-Oil) 립메이크업 제품에 관한 연구)

  • Lee, Dong Won;Kim, Young Ho;Jung, Eun Ji;Lee, Sang Gil;Pyo, Hyeong Bae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.1
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    • pp.65-73
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    • 2013
  • Lip make-up products can be easily taken into body with food. For this reason, those products are requires to meet lots of qualifications compared with other cosmetic products. In addition, concerns about safety on synthesized tar pigments is constantly issued. Thus, demand of natural pigments is gradually increased and many kinds of natural pigments have been developed. However, there are some problems when natural pigments are applied to cometic products instead of synthetic ones. There is a reason that most of natural pigments consist of hydrophilic materials of sort of anthocyanin, but the existing lip make-up products is anhydrous oil dispersion type without water consisting oil and wax. Therefore, when watersoluble natural pigments are applied to anhydrous lip make-up products, color expression is lower and phase separation occurs due to the instability of the product. In addition, natural pigments have disadvantages that they can easily change by pH, heat and sunlight. There are troubles of stability because it is not easy to adjust for these factors in case of anhydrous forms. Aim of study is to develop lip make-up products which have not only safe to human but being high in expression of color by using natural pigments and securing stability of colorant as natural pigments are offered to polyol in oil emulsion. Then, lip make-up products which have heavy moisture while having not dryness that is created when the moisture evaporates are developed.

Comparison of the Hydrolysis Rate of Several Polyol Ester Oils as a Candidate for Environmentally Adapted Synthetic Base Oil (환경친화적인 합성기유 후보물질로서의 몇가지 폴리올에스터 오일의 가수분해속도 비교)

  • 한두희;마사부미마스꼬
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.162-177
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    • 2001
  • The hydrolysis rates of seven kinds of polyol ester base oils 〔POEs〕 of different branch shape were investigated by using a simple apparatus under mild acidic condition. Seven polyol ester base oils were made of poly hydric alcohols of two-four valence, normal or branched fatty acids of different carbon number. p-Toluene sulfonic acid was used as acid catalyst to accelerate the rate of hydrolysis. Partial esters and fatty acid produced by sequential hydrolysis of POEs were identified and their concentrations were determined by calibrated-internal standard method using Gas Chromatography. The rate constants of each step in sequential hydrolysis were determined by the least square method from rate equation and the concentration of each component, were compared with one another. It was shown that the rate of hydrolysis of POEs was strongly affected by whether molecular structure of fatty acid was straight chain or branch chain and which position was branched. The hydrolysis stability for all the POEs can be reasonably explained by using a steric hindrance effect anticipated fi:om their molecular structures affecting as water molecule makes an attack on the carbonyl carbon of POEs.

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Synthesis and Hydrolysis-Resistance Characterization of Waterborne Polyurethane (Waterborne Polyurethane의 합성 및 내가수분해 특성 연구)

  • Jeong, Booyoung;Cheon, Jungmi;Chun, Jaehwan
    • Journal of Adhesion and Interface
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    • v.13 no.3
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    • pp.116-120
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    • 2012
  • In this study, waterborne polyurethane was prepared from polyester polyol, $H_{12}MDI$, DMPA and sulfopropylated polypropyleneglycol-${\alpha}$,${\omega}$-diamine (SP). The $T_g$ of waterborne polyurethane was increased as the SP content increased, while it was decreased at the NCO/OH ratio of 1.8. Also the hydrolysis-resistance and tensile strength were increased as the SP content increased. The tensile strength decrement of WPU-SP was 2~5% with the exception of WPU-SP-1.

A Study on the Synthesis and Properties of Water-Dispersion Polyurethane for Garment Coating Using Nonionic Polyol (비이온 폴리올을 이용한 Garment 코팅용 수분산 폴리우레탄의 합성 및 물성에 관한 연구)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.83-90
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    • 2017
  • The polyurethane resin used for the garment skin leather surface coating was synthesized by varying the content of polyethylene glycol (PEG) in [NCO] / [OH] mole % ratio. The mechanical properties of the synthesized polyurethane resin were analyzed by SEM, FT-IR, UTM. As the [NCO] / [OH] mole % ratio of nonionic poly ethylene glycol (PEG) increased, there was no change in flexural resistance (dry, wet) and abrasion resistance and tensile strength measurement value were lowered. In contrast, the elongation property values were increased. The result of viscosity measurement showed that the viscosity became thinner with increasing [NCO] / [OH] mole % of PEG.

Evaluation of strength characteristics according to expansion amount of ground reinforced expanded polyol (지반보강 팽창약액의 팽창성능 및 밀도에 따른 강도특성 평가)

  • Kang, Hyounhoi;Kim, Kisung;Kim, Juho;Park, Jeongjun
    • Journal of the Society of Disaster Information
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    • v.13 no.1
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    • pp.35-42
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    • 2017
  • In this study, to quantitatively evaluate the strength characteristics of the inflatable liquid used for the recovery of soft ground or partial settlement, the inflatable liquids were prepared by dividing the inflatable capacity and the strength characteristics were analyzed according to the conditions. The experimental group was divided into two groups: relatively high expansion group and low expansion group. The specimens were prepared by controlling the volume of 10 ~ 30% of the maximum expansion volume, and the strength of the specimens were evaluated. The compressive strength of the high expansion group and low expansion group was about 2.1 times.

Synthesis of Polyurethane Foam with Soybean Oil (콩기름을 이용한 폴리우레탄 포옴의 합성)

  • Yang, Do Hyeon;Lee, Kwang Young;Shin, Jae Sup
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.731-736
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    • 1999
  • The polyol was synthesized from soybean oil. Soybean oil was epoxized with peracetic acid, and was reacted with methanol in a sulfuric acid catalyst. OH value of synthesized polyol was 186(mg KOH/g). The polyurethane foam was synthesized with silicon type B-8409 as a surfactant, distilled water as a blowing agent, dimethylcyclohexylamine as a catalyst, and polymeric MDI. The density, the compressive strength, the compressive modulus, and the cell structure of the synthesized foam were investigated. The foam was prepared with changing the mole ratio of MDI, and the amount of water, surfactant, and catalyst. As the MDI index was increased, the density and the compressive property of the foam were increased.

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Electrochemical Properties of Pd Nanocrystals by Shape Control (나노 형상 조절에 의한 Pd의 전기화학적 특성)

  • Lee, Young-Woo;Han, Sang-Beom;Lee, Jong-Min;Kim, Jy-Yeon;Ko, A-Ra;Park, Kyung-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.386-388
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    • 2009
  • 차세대 에너지로 연료전지가 각광을 받고 있는 현재, 세계 각국에서는 연료전지의 상용화를 위해 노력하고 있다. 그러나 촉매분야에서 백금계 촉매의 사용량의 문제에 따른 매장량 한계점과 귀금속이라는 문제점이 존재하기 때문에 이에 대하여 대책강구가 필요한 시점이다. 이에 백금 촉매의 활성을 증대하고자 나노 크기의 제어 연구가 진행되고 있다. 또한, 촉매의 구조적인 면에 따라 촉매의 활성이 달라지는 점을 착안하여 백금계의 나노 형상 조절 연구와 백금계 촉매를 대체할 비백금계의 촉매 개발 연구가 활발히 진행되어지고 있다. 이에 본 연구는 백금계 촉매 중 Pd을 polyol process에 의한 나노 형상 조절을 통하여 단위 질량당(or 단위 부피당) 촉매의 활성을 높이고자 하였다. Polyol process에서는 환원제, 계면활성제, 온도, 시간, 기타 첨가제에 따라 나노 형상이 다르게 조절되는데, 이에 계면활성제로 PVP를 사용하고, 반응속도 및 형상조절을 위해 다양한 첨가제를 이용하여 polygonal Pd NPs을 형성하였다. 본 나노 형상 조절에서는 첨가제와 온도가 가장 큰 영향을 미치는 요인으로 착안하여 그에 따른 polygoanl Pd NPs의 사이즈 조절을 통해 전기화학 특성이 차이의 연구에 중점을 두었다. 이에 따라 나노 형상 조절이 된 Pd촉매를 이용하여 상용화된 촉매(Pd/C(XC-72R))에 비하여 전기화학적인 특성의 차이와 Pd 촉매의 촉매적 특성의 효과를 보고자 한다.

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