• Title/Summary/Keyword: Polymerization Shrinkage

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Studies on Methacrylate Finish with Silk Fabrics and their Anticrease (Methacrylate 견직물가공과 방추도개선에 대한 연구)

  • 최병희;이양후
    • Journal of Sericultural and Entomological Science
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    • v.28 no.2
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    • pp.65-73
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    • 1986
  • These studies are carried out to improve silk availability for anticrease by useing methacrylate monomer polymerization method with in silk fiber. For this purpose, degree of anticrease, stiffness and shrinkage of various silk fabrics, included finish or not, after repeat of washings and polyster fabric was compared as standard. The adopted samples are ; 1. Polyester, Georgette, Woven density…90cm-85g/m 2. Silk, Twill, Degumed, Light, Woven density…90cm-90g/m 3. Silk, Twill, Degumed, Heavy, Woven density…90cm-200g/m 4. Silk, Stain, Degumed, Light, Woven density…90cm-90g/m The reached results are as followings. 1. The results of improving on anticrease by the finished method were about ten per cent increase against their original samples. 2. The light density silks showed satisfactory improve for anticrease, but the heavy one remained as rather poor condition. 3. The results for degree of textile stiffness were investigated to make sure reserve their textile feeling and observed to be good condition upon the finish work. 4. Textile shrinkage after the repeat of soap wash was investigated on indivisual test sample and silk fabrics showed more shrinkage than polyester which it seemed to be tentering shrinkage druning their general finishing processes. 5. The investigation showed that anticrease, stiffness and shrinkage of the sample textile were more or less deteriorated regardless silk or polyester by the repeat of washings. These matters are considered that such results were obtained because of the fiber fatigue nature. 6. The report reached that silk textiles should be used by dry cleaning methed after finish of any resin finish to reserve their improved anticrease nature.

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Setting Shrinkage, Thermal Expansion Coefficient and Compressive Strength of Recycled PET Polymer Concrete with Montmorillonite (몬모릴로라이트를 이용한 재활용 PET폴리머 콘크리트의 경화수축, 온도팽창계수, 압축강도)

  • Jo Byong-Wan;Tae Ghi-Ho;Lee Du-Wha
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.205-212
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    • 2004
  • Recently, as concerns over environmental issues are raised more and more trend to use recycled waste for producing construction materials is also raised. Especially, a case of waste resin is considerably destroying the environment due to disposal way that most waste resin produced is disposed of landfill. This study is performed by polymer concrete with recycled PET resin in terms of obtaining safely clean construction resources and protection of environment. High setting shrinkage and sensitivity to heat are main disadvantages of Polymer Concrete (PC) despites of a lot merits. The aim of this study is to investigate basic properties such as setting shrinkage, length change and sensitivity to heat about PET recycled polymer concrete. The other is to check the possibility of use of Montmorillonite as one of a lot of additive without special coupling agent. As results of experiments, various properties of polymer concrete with recycled PET resin are similar with conventional PC except that polymerization time is longer. Montmorillonite was efficiently used to reduce setting shrinkage, length change and coenicient of thermal expansion related to heat with enhanced strength

Indirect Composite Restoration (임상가를 위한 특집 1 - 간접 복합레진 수복의 이론과 실제)

  • Hwang, In-Nam;Jang, Ji-Hyun
    • The Journal of the Korean dental association
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    • v.50 no.7
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    • pp.368-376
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    • 2012
  • The demand for tooth-colored restorations has grown considerably during the last decade. Posterior composite restorations have risen in popularity as a result of the development of improved resin composites, bonding systems and operating techniques. A major limitation of direct composite restoration is the difficulty of controlling the polymerization shrinkage. To overcome this limitation, the indirect fabrication of a composite restoration and cementation with resin cement has been advocated. Unfortunately, the current available resin cements with indirect restorations do not always bond to dentin as strongly as dentin adhesive systems bond with direct resin composite restorations. Several procedural strategies have been proposed for indirect composite restoration. In this regard, the rationale for the indication, characteristics and clinical application is described in this paper. As a result, we will try to suggest the evidence-based guidelines for indirect composite restorations by reviewing each available indirect composite products, technical procedure and pronosis.

Analysis of Chemically and Thermally Induced Residual Stresses in Polymeric Thin Film

  • Lee, Sang Soon
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.1-5
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    • 2015
  • This paper deals with the residual stresses developed in an epoxy film deposited on Si wafer. First, chemically induced residual stresses due to the volumetric shrinkage in cross-linking resins during polymerization are treated. The curvature measurement method is employed to investigate the residual stresses. Then, thermally induced stresses are investigated along the interface between the epoxy film and Si wafer. The boundary element method is employed to investigate the whole stresses in the film. The singular stress is observed near the interface corner. Such residual stresses are large enough to initiate interface delamination to relieve the residual stresses.

Mechanical Properties of PMMA Mortars without Crosslinking Agent (가교제 무첨가 PMMA 모르타르의 역학적 특성)

  • 최낙운;김완영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.425-428
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    • 2003
  • This study deals with the mechanical properties of polymethyl methacrylate(PMMA) mortars without crosslinking agent. Waste expanded polystyrene(EPS) is used as a multifunctional admixture such as a thickener, a extender, a shrinkage reducing agent, a assistant to polymerization. PMMA mortars are prepared with various EPS contents of binder and subjected to a dry and a dry/heat combined curing, and tested for working life, flexural and compressive strengths. From the test results, the working life of PMMA mortars without crosslinking agent is shortened with raising EPS content of binder. The flexural and compressive strengths of the PMMA Mortars are decreased somewhat with increase in the EPS content. PMMA mortars with good mechanical properties could be manufactured without any crosslinking agent and their properties would be controled by adjusting EPS content of binder.

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Preparation of $Li_2O-ZrO_2-P_2O_5-SiO_2$ based Glassy Solid Electrolytes by Sol-Gel Process and Their Ionic Conduction (솔-젤법에 의한 $Li_2O-ZrO_2-P_2O_5-SiO_2$계 유리 고체전해질의 제조와 그의 이온전도성)

  • 박강석;김기원;강은태
    • Journal of the Korean Ceramic Society
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    • v.31 no.6
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    • pp.660-670
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    • 1994
  • Transparent, crack-free dried gel monoliths with a composition of LiZr1.5Si2P2O12.5 have been synthesized by the low temperature polymerization of the Sol-Gel technique using metal alkoxides as starting materials. After initial reaction (20~40 min), each metal alkoxide closely paralleled each other during the hydrolysis reactions. The safe drying conditions of gels with no creaks the control of the shrinkage rate. The gels converted into the glass by heat treatment at 75$0^{\circ}C$. FTIR data indicated that the gels were phase separated into silicarich and phosphate-rich regions with the lithium. XRD results showed the formation of crystalline LiH2PO4. The gels dried at 15$0^{\circ}C$ or fired at 75$0^{\circ}C$ contained the residual water. The high ionic conductivity at room temperature for these gels was attributed to the motion of protons.

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Functional and aesthetic rehabilitation in posterior tooth with bulk-fill resin composite and occlusal matrix

  • Francisconi-dos-Rios, Luciana Favaro;Tavares, Johnny Alexandre Oliveira;Oliveira, Luanderson;Moreira, Jefferson Chaves;Nahsan, Flavia Pardo Salata
    • Restorative Dentistry and Endodontics
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    • v.45 no.1
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    • pp.9.1-9.7
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    • 2020
  • The restorative procedure in posterior teeth involves clinical steps related to professional skill, especially when using the incremental technique, which may fail in the long term. A recent alternative is bulk-fill resins, which can reduce polymerization shrinkage, decreasing clinical problems such as marginal leakage, secondary caries, and fracture. This scientific study aims to report a clinical case using bulk-fill resin with an occlusal matrix. As determined in the treatment plan, an acrylic resin matrix was produced to establish an improved oral and aesthetic rehabilitation of the right mandibular first molar, which presented a carious lesion with dentin involvement. The occlusal matrix is a simple technique that maintains the original dental anatomy, showing satisfactory results regarding function and aesthetic rehabilitation.

Monofunctional Monomer Effects of The Reflection Mode & Transmission Mode of Holographic Polymer Dispersed Liquid Crystals

  • Park, Min-Sang;Cho, Young-Hee;Kim, Byung-Kyu
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.75-80
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    • 2001
  • Holographic polymer dispersed liquid crystals (HPDLCs) have fabricated by irradiating an Ar-ion laser ( ${\lambda}$=514nm) at various intensity on LC/acrylate monomer mixtures which were sandwitched between two ITO coated glass plates. Monomer systems were composed of dipentaerythritol-hydroxy penta acrylate (DPHPA, f=5)/monofunctional acrylate monofunctional monomers. The LC used in this system was E7 (BL001, Merck). Gratings were fabricated by periodic interference of twobeams. Reflection efficiency-irradiation intensity-monomer type relationships were obtained from the UV-visible spectra of the HPDLC films. Peaks were found at a bit smaller wavelength than 514nm, due to the shrinkage of mixture volume upon polymerization. Real time measurements of diffraction efficiency have been obtained according to monomer types and LC contents.

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Furfurylation Effects on Discoloration and Physical-Mechanical Properties of Wood from Tropical Plantation Forests

  • HADI, Yusuf Sudo;HERLIYANA, Elis Nina;PARI, Gustan;PARI, Rohmah;ABDILLAH, Imam Busyra
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.1
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    • pp.46-58
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    • 2022
  • Wood from tropical plantation forests has lower physical and mechanical properties than mature wood. Furfuryl alcohol (FA) impregnation into the wood could help to enhance hydrophobic properties, dimensional stability, and structural strength. Furfurylation was applied to specimens of the following four fast-growing tropical wood species: jabon (Anthocephalus cadamba), sengon (Falcataria moluccana), mangium (Acacia mangium), and pine (Pinus merkusii). The discoloration and physical and mechanical properties were subsequently measured, and the results showed that furfurylated wood had a darker color and better physical and mechanical properties than untreated wood. Specifically, the furfurylated wood had higher density, modulus of elasticity, and hardness and lower moisture content, water absorption, swelling, and shrinkage. The furfurylation significantly enhanced physical and mechanical properties.

Dental Properties of Hydroxyapatite Filled Polymer Composite (수산화인회석이 충전된 고분자 복합체의 치과적 물성)

  • Seo, Kitaek;Yoon, Jingu;Kim, Juhwan;Kim, Ohyoung
    • Applied Chemistry
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    • v.9 no.2
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    • pp.25-28
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    • 2005
  • To evaluate the dental restorative application of polymer composites filled with hydroxyapatite (HAP) which is an inorganic component of human bone material, dental properties of the polymer composites were investigated. A visible light system was utilized to activate the acrylate resin matrix of the composites. Maximum loading percentage of HAP in composite was 65 wt% and the depth of cure was 6.0 mm which can be applicable for dental restoration. With increasing the HAP content, degree of conversion of polymer composites was slightly decreased, however, polymerization shrinkage value was not varied. Diametral tensile strength value was enhanced with an increase of HAP content, however, there was no strict trend between flexural strength and HAP concentration. Anyhow, polymer composites prepared herein have superior mechanical properties sufficient specifications applicable to dental materials.