• Restorative Dentistry and Endodontics
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• 제26권2호
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• pp.134-140
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• 2001

The polymerization shrinkage of composite resins is an important drawback although the composites have many advantages-more esthetic and conservative than metallic restoratives etc. The purposes of this research were to develop a new measurement method and to manufacture an instrument that can measure the initial dynamic volumetric shrinkage of composite resins during polymerization. The instrument was basically an electromagnetic balance that constructed with a force transducer using position sensitive photo detector(PSPD) and a negative feedback servo amplifier of proportional-derivative(PD) controller. The volumetric change of composites during polymerization was detected continuously as buoyancy change in distilled water by means of Archimedes's principle. It was converted to continuous electrical voltage signal in real time. The signal was properly conditioned and filtered and then it was stored in computer by a data acquisition(DAQ) board. By using this electronic instrument. the dynamic patterns of the polymerization shrinkage of eight commercial(Z-100, DenFil, AeliteFil, Z-250, P-60, SureFil, Synergy compact, and Tetric ceram) composite resins were measured and compared. The results were as follows. 1. From this project of developing instrument, the ability has been achieved that can acquire and process data of electrical signal transformed from various physical phenomenon by using temperature, displacement. photo. and force transducer. As a consequence, the instrumentation and measurement system used to analyze the physical characteristics of various dental materials in dental research field can be designed, manufactured and implemented in lab. 2. This instrument has some advantages. It was insensible to temperature change and could measure true dynamic volumetric shrinkage in real time without complicated process. It showed accuracy and high precision results with small standard deviation. 3. The polymerization shrinkage of composites was significantly different between brands and ranged from 2.47％ to 3.89％, The order of polymerization shrinkage was as follows, in order of increasing shrinkage, SureFil, P60, Z250, Z100, Synergy compact. DenFil, Tetric ceram, and AeliteFil. 4. The polymerization shrinkage rate per unit time, dVol％/dt, showed that the instrument can provide an indirect research method for polymerization reaction kinetics.

• 한국안전학회지
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• 제25권3호
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• pp.61-65
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• 2010

Most of the chemical reactions performed in the chemical industry are exothermic, meaning that thermal energy is released during the reaction. It is also important to understand the thermal hazards such as thermal stabilities and runaway reactions, which are governed by thermodynamics and reaction kinetics of the mixed materials. The paper was described the evaluation of thermal behavior caused by an exothermic batch process in manufacture of the vinyl acetate resin. The aim of the study was to evaluate the thermal stabilities of raw materials with operating conditions such as a reaction inhibitor, heating rate, reaction atmosphere and the mount of methanol charged in the vinyl acetate polymerization process. The experiments were performed in the differential scanning calorimeter(DSC), C 80 calorimeter, and thermal screening unit($TS^u$). It was suggested that we should provide the thermal characteristics for raw materials to present safe precautions with operating conditions in the vinyl acetate polymerization process.

• 한국막학회:학술대회논문집
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• 한국막학회 1998년도 추계 총회 및 학술발표회
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• pp.63-65
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• 1998

1. Introduction : Atmospheric discharge of VOC-contaminated streams in chemical plants and air streams from chemical processes poses a serious environmental problem and entails large financial losses. Such emissions may be reduced by i) adsorption process, ii) absorption process and iii) incineration process. These processes only forbids the air pollutions. Throughout the recent decade, another technique-membrane process has emerged. The separation and recovery of organic vapors by membrane process may have great economic potential. Most of the published research works on the separation of organic vapors from air were performed using silicon rubber membranes. However, it is very difficult to fabricate very thin membranes with less than 1 $u m thickness. Plasma polymerization could be a good technique to generate a thin polymer film. The objective of this work is to find out the optimum condition of plasma polymerization for producing VOC separation membrane. For the objective, composite membranes are prepared through plasma polymerization of hexamethyldisiloxane onto porous substrates under different conditions. The membrane is then subjected to the permeation of permanent gases and VOCs to find the correlations between the physical properties of the penetrant and permeability and selectivity.

• Macromolecular Research
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• 제16권4호
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• pp.293-302
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• 2008

In our previous publication, the problem of particle deformation and coagulation at the nucleation stage in the presence of cross-linker was intensely studied by seeded batch dispersion polymerization of methyl methacrylate (MMA). In the present work, highly cross-linked, monodisperse PMMA particles were prepared under various reaction conditions by seeded semi-continuous process. Monodisperse, $6.5{\mu}m$-diameter PMMA particles containing up to 8 wt% of DVB or EGDMA were successfully made by seeded semi-continuous process and multi-semi-continuous addition process, respectively. Therefore, this study shows that seeded semi-continuous process is more effective and efficient to prepare highly cross-linked, monodisperse particles than non-seeded and seeded batch processes.

• Fibers and Polymers
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• 제5권4호
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• pp.253-258
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• 2004

Living nature of photoinduced cationic polymerization of isobutyl vinyl ether (IBVE) in the presence of various combinations of diphenyliodonium halide (DPIX), a photocationic initiator and zinc halide $(ZnX_2)$ in methylene chloride has been investigated. Attainment of $100\%$ conversion and a linear relationship between $\%$conversion and number average molar mass of the resulting polymer, strongly suggests the living nature of this system. Livingness of the polymerization system was observed irrespective to the type of halide anion of the initiator and zinc salts unless the reaction temperature is not higher than $-30^{\circ}C$. The rate of polymerization decreases in the order of iodide > bromide > chloride when halide salt of DPIX and $ZnX_2$ are used. It is postulated that the cationic initiation is started by the insertion of weakly basic monomer in to the activated C-X terminal of the monomer adduct which is a reaction product of monomer and HX, a photolytic product of DPIX, formed in situ during the photo-irradiation process. It was concluded that polymerization is initiated by the insertion of weakly basic monomer into activated C- X terminal of monomer adduct due to the pulling action of$ZnX_2$, which successively producing a new polarized C-X terminal for the propagation in cationic nature. This led us to a conclusion that the living nature of this cationic polymerization is ascribable to the polarized C-X growing terminal, which is stable enough to depress the processes of chain transfer or termination process.

• Macromolecular Research
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• 제13권5호
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• pp.391-396
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• 2005

The polymerization of methyl methacrylate (MMA) was carried out using CuBr/bidentate phosphorus ligand catalyst systems. MMA polymerization with CuBr/phosphine-phosphinidene (PP) exhibited high conversion ($\~80\%$) in 5 h at $90^{\circ}C$ along with a linear increase of ln($[M]_0/[M]$) versus time, indicating constant concentration of the propagating radicals during the polymerization. The molecular weight of the prepared PMMA tended to increase with conversion, suggesting the living polymerization characteristic of the system. On the other hand, a large difference between the measured and theoretical molecular weight and a broad molecular weight distribution were observed, implicating possible incomplete control over the polymerization. This may have been caused by the low deactivation rate constant ($\kappa_{deact}$) of the system. The low $\kappa_{deact}$, would result in irreversible generation of radicals instead of reversible activation/deactivation process of ATRP. Polymerizations performed at different ligand to CuBr ratios and different monomer to initiator ratios did not afford better control over the polymerization, suggesting that the controllability of CuBr/phosphorus ligand system for ATRP is inherently limited.

• 한국정밀공학회지
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• 제21권6호
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• pp.160-166
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• 2004

In this study, a new algorithm, named as Contour Offset Algorithm(COA) is developed to fabricate precise features or patterns in the range of several micrometers by nano replication printing(nRP) process. In the nRP process, a femto-second laser is scanned on a photosensitive monomer resin in order to induce polymerization of the liquid monomer according to a voxel matrix which is transformed from the bitmap format file. After polymerization, a droplet of ethanol is dropped to remove the unnecessary remaining liquid resin and then only the polymerized figures with nano-scaled precision are remaining on the glass plate. To obtain more precise replicated features, the contour lines in voxel matrix should be modified considering a voxel size. In this study, the efficiency of the proposed method is shown through two examples in view of accuracy.

• Elastomers and Composites
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• 제33권2호
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• pp.110-116
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• 1998

A new technology was introduced to the emulsion polymerization. It is the ultrasonic activation method which replaced a chemical initiator and the environmentally benign process. In this study, free radicals were produced by a pulse type ultrasound energy irradiation, then polystyrene latex was polymerized without chemical initiator. With ultrasonic energy density, the degree of polymerization, average molecular weight, and particle size were increased, but the polydispersity index for the molecular weight and the particle size were decreased. The optimum condition of emulsifier concentration and temperature was found to be 1.0 wt.% SDS and $40^{\circ}C$, respectively. As a result, the emulsion polymerization process without chemical initiator was proved to be comparable to common latex properties such as average molecular weight, molecular weight distribution, particle size, etc.

• 한국염색가공학회지
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• 제15권3호
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• pp.127-131
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• 2003

Acrylonitrile(AN) was solution-polymerized in dimethyl sulfoxide(DMSO) and tertiary butyl alcohol(TBA) at 30, 40, $50^\circ{C}$ using a low temperature initiator, 2,2'-azobis(2,4-dimethylvaleronitrile) (ADMVN). The low temperature polymerization using ADMVN, DMSO, and TBA is to be successful in obtaining high molecular weight polyacrylonitrile(PAN) with less branches by solution polymerization. Throug a polymerization of AN in DMSO at $30^\circ{C}$, PAN having viscosity-average molecular weight$(M_v)$ of 931,000 was obtained. And then, during AN solution polymerization in DMSO and TBA using a cosolvent system the in-situ formation of microfibrillar structure has been discovered at the cosolvent composition of 24/1$(V_{DMSO}/V_{TBA})$. The simultaneous process of gelation and phase separation of long chain molecules may explain the in-situ formation of PAN fibers during polymerization.

• Macromolecular Research
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• 제15권3호
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• pp.244-255
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• 2007

Nucleation is the most sensitive stage in the preparation of highly cross-linked, monodisperse microspheres by dispersion polymerization, since the addition of a small amount of cross-linker results in particle deformation and coagulation. To overcome these problems, $5\;{\mu}m$ poly(methyl methacrylate) seed particles prepared by dispersion polymerization were used in the preparation of mono disperse, cross-linked PMMA particles containing up to 7 wt% divinylbenzene by seeded batch dispersion polymerization. Spherical particles with a narrow size distribution containing up to 8 wt% of EGDMA were prepared by seeded multi-batch dispersion polymerization processes. These particles were identified by scanning electron microscopy and DSC.