• 대한약학회:학술대회논문집
• /
• 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
• /
• pp.107.2-107.2
• /
• 2003

Bisphenol A(BPA) is a monomer widely used in the manufacturing polycarbonate plastic or epoxy resin and Mancozeb (MCZ), a polymeric complex of zinc and manganese salts of ethylene bisthiocarbamate, is widely used in agriculture as fungicide, insecticide and herbcide. These chemicals have been recently known as endocrine disruptors. To investigate the effects of BPA and MCZ on LPS-induced cytokine production (TNF-${\alpha}$) in vivo, female ICR mice were administered to various concentration of these materials (BPA; 100, 500, 1000 mg/kg/day, and MCZ; 250, 500, 1000, 1500 mg/kg/day) for 30 days and serum cytokine levels were measured at 1h post LPS injection (day 32) in BPA- or MCZ-administered mice. (omitted)

• 한국정밀공학회지
• /
• 제28권7호
• /
• pp.777-782
• /
• 2011

Micro features on the surface are well-known to have significant effects on optical or mechanical properties such as the optical interference, reflectance at the surface, contact angle, interfacial friction, etc. These surface micro features are increasingly employed to enhance the functionality of the applications in various application areas such as optical components for LCD or solar panel. Diverse surface features have been proposed and some of them are showing excellent efficiency or functionality, especially in optical applications. Most applications employing the micro features need manufacturing process for mass production and the injection molding and roll-to-roll forming, which are typical processes for mass production adopting polymeric materials, may be also preferred for micro patterned plastic product. Since the functionality or efficiency of the surface structures generally depends on the shape and the size of the structure itself or the array of the structures on the surface, it would be very important to replicate the features very precisely as being designed during the molding the micro pattern applications. In this paper, a series of research activities is introduced for roll-to-roll forming of micro patterned film including filling of patterns with UV curable resin, demolding of surface structures from the roll tool, control of surface energy and cure shrinkage of resin and dispose time and intensity of the UV light for curing of UV curable resin.

• 한국산학기술학회논문지
• /
• 제19권11호
• /
• pp.24-30
• /
• 2018

식물유는 자연 유래 물질로 낮은 가격 및 친환경적이라는 장점으로 최근 다양한 연구가 진행되고 있다. 하지만 식물유 내의 이중결합의 낮은 반응성으로 인해 고분자 합성의 기반 물질로 사용하기 위해서는 반응성이 높은 관능기로 치환하여 사용하는 경우가 많다. Tung oil은 ${\alpha}$-eleostearic acid를 주성분으로 하는데, 이 구조는 3개의 이중결합이 공명구조로 되어있기 때문에 다른 식물유와는 달리 높은 반응성을 보인다. 본 연구에서는 이러한 tung oil을 styrene 및 divinylbenzene 등의 단량체와 양이온 중합을 통해 tung oil의 관능기 치환 과정이 없는 열경화성 수지를 합성하였으며, 각 단량체의 조성이 합성된 열경화성 수지에 미치는 영향을 확인하기 위해 열적 기계적 물성을 측정하였다. 그 결과, tung oil-styrene-divinylbenzene 공중합체는 단일 Tg를 갖는 균일(homogeneous)한 열경화성 고분자를 형성하는 것을 확인하였으며, 기계적 물성의 변화를 통해 tung oil 및 styrene은 soft segment로써 합성된 공중합체에 탄성(elasticity)을 부여하고, divinylbenzene은 hard segment로 작용하여 합성된 공중합체에 취성(brittleness)을 부여하는 것을 확인하였다.

• 아시안잔디학회지
• /
• 제10권3호
• /
• pp.263-270
• /
• 1996

This experiment was conducted to investigate the loss of various herbicides by means of vola-tility from the turfgrass field and the hare ground with the different soil moisture contents and temperatures. Different herbicides were applied at the rates of 375 g a.i. /l0a of pendimethalin,250 g a.i. /l0a of napropamide, and 96.4 g a.i. /l0a of dicamba with 200 \ulcorner/10a of spray volume in the turfgrass(Zoysia japonica cut off 5cm) grown in pots(265.8 $cm^2$) and bared soil. The pots were placed in the growth chamber with 10,000 lux of light intensity(12h per day) at 25 and 35˚C for 7days. Amberlite XAD polymeric resin(20/50 mesh) was used as sampling media for herbicide airborne residues. Air flow was maintained at 10 \ulcorner /min by vacuum pump regulated with a factory calibrated flow meter. Herbicide airborne residues were extracted from the XAD resin with 300 ml of 1:1 acetone and hexane. The extracts were concentrated by rotary evaporation at 35˚C and dissolved in 1 ml MeCN for HPLC analysis. The airborne losses of the herbicide applied in the turfgrass and bare soil increased as the temperature and soil moisture contents were increased, regardless of the kinds of herbicide. Higher airborne residues was observed in the turfgrass pots than the bare soil pots. Pendimethalin and dicamba with higher vapor pressure gave rise to the increased loss of airborne herbicides, showing that 6.26 and 6.4% of average airborne loss in pendimethalin and dicamba, respectively, compared to 0.56% in napropamide. The amount of airborne losses in turfgrass was highest at one day after application and then a declined trend was observed as the time was prolonged. Key words. Herbicides, Turfgrass field, Bare ground, Volatility.

• Steel and Composite Structures
• /
• 제48권3호
• /
• pp.305-320
• /
• 2023

The mechanical properties of polymeric composites are degraded under elevated temperatures due to the effect of temperature on the mechanical behavior of the resin and resin fiber interfaces. In this study, the effect of temperature on the impact response of the carbon fiber reinforced plastics (CFRP) was investigated at low-velocity impact (LVI) using a drop-weight impact tester machine. All the composite plates were fabricated using a vacuum infusion process with a stacking sequence of [45/0_2/-45/90_2]s, and a thickness of 2.9 mm. A group of the specimens was exposed to an environment with a temperature cycling at the range of -30 ℃ to 65 ℃. In addition, three other groups of the specimens were aged at ambient (28 ℃), -30 ℃, and 65 ℃ for ten days. Then all the conditioned specimens were subjected to LVI at three energy levels of 10, 15, and 20 J. To assess the behavior of the damaged composite plates, the force-time, force-displacement, and energy-time diagrams were analyzed at all temperatures. Finally, radiography, optical microscopy, and scanning electron microscopy (SEM) were used to evaluate the effect of the temperature and damages at various impact levels. Based on the results, different energy levels have a similar effect on the LVI behavior of the samples at various temperatures. Delamination, matrix cracking, and fiber failure were the main damage modes. Compared to the samples tested at room temperature, the reduction of temperature to -30 ℃ enhanced the maximum impact force and flexural stiffness while decreasing the absorbed energy and the failure surface area. The temperature increasing to 65 ℃ increased the maximum impact force and flexural stiffness while decreasing the absorbed energy and the failure surface area. Applying 200 thermal cycles at the range of -30 ℃ to 65 ℃ led to the formation of fine cracks in the matrix while decreasing the absorbed energy. The maximum contact force is recorded under cyclic temperature as 5.95, 6.51 and 7.14 kN, under impact energy of 10, 15 and 20 J, respectively. As well as, the minimum contact force belongs to the room temperature condition and is reported as 3.93, 4.94 and 5.71 kN, under impact energy of 10, 15 and 20 J, respectively.

• Corrosion Science and Technology
• /
• 제17권2호
• /
• pp.74-80
• /
• 2018

The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

• Journal of Applied Biological Chemistry
• /
• 제44권4호
• /
• pp.190-193
• /
• 2001

Genipin, aglycone of geniposide isolated from fruits of Gardenia jasminoides, was transformed into blue pigments through reaction with glycine and methylamine. The blue pigments formed from glycine-reacted genipin were passed through Bio-Gel P-2 resin yielding fractions GG1 and GG2, and those from methylamine-reacted genipin were separated into fractions GM1-GM4. The first eluted higher molecular-weight fractions, GG1 and GM1, had higher tinctorial strength than the later eluted lower molecular-weight fractions, GG2 and GM2-GM4, respectively. $^1H-NMR$ spectra of GG1 and GM1 showed very broad peaks indicating that structures of the pigments were highly polymeric. $^1H-NMR$ spectra of GG2, GM3, and GM4 showed several sharp peaks at aliphatic and aromatic regions with accompanying broad peaks, although the spectrum of GM2 was rather simple. Determination of the structural and physical nature of the isolated pigments is in progress.

• Carbon letters
• /
• 제14권1호
• /
• pp.40-44
• /
• 2013

The bipolar plate is the most important and most costly component of proton exchange membrane fuel cells. The development of a suitable low density bipolar plate is scientifically and technically challenging due to the need to maintain high electrical conductivity and mechanical properties. Here, bipolar plates were developed from different particle sizes of natural and expanded graphite with phenolic resin as a polymeric matrix. It was observed that the particle size of the reinforcement significantly influences the mechanical and electrical properties of a composite bipolar plate. The composite bipolar plate based on expanded graphite gives the desired mechanical and electrical properties as per the US Department of Energy target, with a bulk density of 1.55 $g.cm^{-3}$ as compared to that of ~1.87 $g.cm^{-3}$ for a composite plate based on natural graphite (NG). Although the bulk density of the expanded-graphite-based composite plate is ~20% less than that of the NG-based plate, the I-V performance of the expanded graphite plate is superior to that of the NG plate as a consequence of the higher conductivity. The expanded graphite plate can thus be used as an electromagnetic interference shielding material.

• International Journal of Automotive Technology
• /
• 제6권6호
• /
• pp.665-670
• /
• 2005

Nanocomposites of polypropylene with organically modified clays were compounded on a twin-screw extruder by two-step melt compounding of three components, i.e., polypropylene, maleic anhydride grafted polypropylene (PP-g-MA), and organically modified clay. The effect of PP-g-MA compatibilizers, including PH-200, Epolene-43, Polybond-3002, Polybond-3200, with a wide range of maleic anhydride (MA) content and molecular weight was examined. Morphologies of nanocomposites and their mechanical properties such as stiffness, strength, and impact resistance were investigated. X-ray diffraction patterns showed that the dispersion morphology of clay particles seemed to be determined in the first compounding step and the further dispersion of clays didn't occur in the second compounding step. As the ratio of PP-g-MA to clay increased, the clay particles were dispersed more uniformly in the matrix resin. As the dispersibility of clays was enhanced, the reinforcement effect of the clays increased, however impact resistance decreased.

• 한국생물공학회:학술대회논문집
• /
• 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
• /
• pp.520-523
• /
• 2000

Phenol and other phenolic compounds are common constituents of aqueous effluents from processes such as polymeric resin production, oil refining and cokeing plants. Phenol is a both toxic and lethal of fish at relatively low concentrations e.g. 5-25 mg/L and imparts objectionable tastes to drinking water at far lower concentration. Therefore, the treatment of phenol effluent is important. Among the various techniques of phenol wastewater treatment, microbial teratment is a popular process. The breakdown of phenols by microorganisms has recived considerable attention, because of its biochemical interest and its industrial importance in effluent treatment. This research was performed to investigate the dynamics of microbial community, biofilm growth and the comparison of phenol removal efficiency by RBC (Rotating Biological Contactor) using Rhodococcus sp. EL-GT The experiment was carried out at rotating speed of 10ppm and hydraulic retention time of 7 hours. As time passed, phenol removal efficiency was gained highly. The RBC using Rhodococcus sp. EL-GT completely degraded 15 mM.