• Title/Summary/Keyword: Polymeric material

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Synthesis of (Y,Sm)BCOpowder and Fabrication of a single crystal using Polymeric Complex Method (착체중합법에 의한 (Y,Sm)BCO 분말합성과 단결정 제조)

  • 안재원;최희락;한영희;한상철;정년호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.482-485
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    • 2002
  • We synthesize a (Y,Sm)BCO(its composition is (Y/Sm123+0.4Y/Sm211)+1wt%CeO$_2$) powders using polymeric complex method. (Y,Sm)BCO powders are prepared as heated at 970$^{\circ}C$. For measurement of this characterization, We measure XRD and SEM. We use TSMG method for fabricatlon of (Y,Sm)BCO single crystal. The manufactured VBCO single crystal is measured by a magnetic distribution device using 0.5 Tesla magnet. As the result of this measurement, we find that a trapped magnet fields are 550 Gauss.

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Electrochemical Characteristics of Aqueous Polymeric Gel Electrolyte for Supercapaictor (수퍼커패시터용 수용성 고분자 젤 전해질의 전기화학적 특성)

  • Kim, Han-Joo;Ishikawa, Masashi;Morita, Masayuki;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.93-96
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    • 2001
  • We have reported to make nanostructured cobalt oxide electrode that have large capacitance over than 400F/g (specific capacitance) and good cycleability. But, It had serious demerits of low voltage range under 0.5V and low power density. Therefore, we need to increase voltage range of cobalt oxide electrode. we report here on the electrochemical properties of sol-gel-derived nanoparticulate cobalt xerogel in 1M KOH solution and aqueous polymeric gel electrolyte. In solution electrolyte, cobalt oxide electrode had over than 250F/g capacitance consisted of EDLC and pseudocapacitance. In gel electrolyte, cobalt oxide electrode had around l00F/g capacitance. This capacitance was only surface EDLC. In solution electrolyte, potassium ion as working ion reacted with both of layers easily. However, In gel electrolyte, reacted with only surface-active layer. Its very hard to reach resistive layer. So, we have studied on pretreatment of electrode to contain working ions easily. We'll report more details.

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Application Technologies of Polymer Suspended Insulators for the Electric Track Line (전차 선로용 폴리머 현수애자의 적용 기술)

  • Han, Se-Won;Cho, Han-Goo;Song, Hong-Jun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.59-61
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    • 2001
  • Polymeric suspended insulators for the electric track line have been developed. The main elements to design polymeric insulators are the insulation ability related with materials of FRP core and housing, and the optimal structure related with fitting parts and interface characteristics. To confirm the design fitness of insulator samples the electric field distribution by FEM and mechanical stress distribution by NASTRAN program was analysed with housing shed shapes and fitting structure. The leakage distance and breakage voltage properties which are core parameters to determine electric insulation ability are selected according to the requirement values of user specification, then the power frequency wet withstand voltage was specified above 22kV and the leakage distance was required above 290mm. The contamination condition of the electric track line was the heavy class according to IEC 815 in order to retain the enough safety margin against overvoltages.

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UV Aging on EPDM rubber for use in polymer Insulators (폴리머 애자용 EPDM 고무의 자외선 열화특성)

  • Youn, Bok-Hee;Lee, Sang-Yong;An, Jong-Sik;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.62-65
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    • 2001
  • The effects of accelerated UV radiation on EPDM used for a polymeric insulator were investigated by contact angle, surface voltage decay after corona charging, SEM-EDX, ATR-FTIR and XPS. EPDM occurs as loss of hydrophobicity by UV treatment, which followed by surface cracking and chalking. The surface voltage decay on UV-treated EPDM show that the shorter decay time corresponded to the treated samples with a longer UV exposure time. The surface oxygen and aluminum content were found to increase and carbon decrease, as is observed in EDX analysis. The ATR-FTIR and XPS indicated that C-C and C-H groups decreased and the highly oxidized carbon bonds such as C-O, C=O and O-C=O increase with time. Also, the effects of surface charges on hydrophobicity based on our results is discussed.

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Electrical property of organic solvent dispersible poly(3,4-ethylenedioxythiophene) / polymeric ionic liquid complex (유기용제 분산형 poly(3,4-ethylenedioxythiophene) / 고분자 이온성 액체 복합체의 전기적 특성)

  • Lee, Tae-Hee;Kim, Tae-Young;Duong, Ha Thi Thuy;Suh, Min-Won;Kim, Jong-Eun;Suh, Kwang-S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.146-147
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    • 2008
  • Poly(3,4-ethylenedioxythiophene) (PEDOT) / poly(1-vinyl-3-ethylimidazolium bis(trifluoromethane sulfonyl)imide) (poly(ViEtIm $^+TFSI^-$) complex was prepared for organic solvent dispersible conductive nano particles. By molar ratio, PEDOT / poly(ViEtIm $^+TFSI^-$) complex was polymerized and dispersed in propylene carbonate by 1 wt%. The maximum conductivity of the complexes was $1.2\times10^{-1}$ S/cm.

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A Study on the Analysis of $1{\times}2$ Polymer Waveguide Thermo-optic switch ($1{\times}2$ 열광학 폴리머 광스위치의 해석에 관한 연구)

  • 곽혁용;김종헌
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.247-251
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    • 1998
  • This work presents the analysis of $1\times2$ polymer waveguide thermo-optic switch using asymmetric Y-splitter at the wavelength of 1300nm. Because of the high thermo-optic coefficient of polymeric materials the design of efficient switches were feasible. For the numerical simulation of these switches the finite difference beam propagation method has been employed. Design rules for a $1\times2$ polymeric switch have been defined by using the numerical techniques.

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Electrochemical Characteristics of Aqueous Polymeric Gel Electrolyte for Supercapacitor (수퍼커패시터용 수용성 고분자 젤 전해질의 전기화학적 특성)

  • ;Masashi ISHIKAWA;Masayuki MORITA
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.93-96
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    • 2001
  • We have reported to make nanostructured cobalt oxide electrode that have large capacitance over than 400F/g (specific capacitance) and good cycleability. But, It had serious demerits of low voltage range under 0.5V and low power density. Therefore, we need to increase voltage range of cobalt oxide electrode. we report here on the electrochemical properties of sol-gel-derived nanoparticulate cobalt xerogel in 1M KOH solution and aqueous polymeric gel electrolyte. In solution electrolyte, cobalt oxide electrode had over than 250F/g capacitance consisted of EDLC and pseudocapacitance. In gel electrolyte, cobalt oxide electrode had around 100F/g capacitance. This capacitance was only surface EDLC. In solution electrolyte, potassium ion as working ion reacted with both of layers easily. However, In gel electrolyte, reacted with only surface-active layer. Its very hard to reach resistive layer. So, e have studied on pretretmetn of electrode to contain working ions easily. We'll report more details.

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The Evaluation of Reliability through the Field Test of Pormeric Long Rod Insulator for Rail Way (전철용 고분자 장간애자의 실증 시험을 통한 신뢰성 평가)

  • 홍진영;김영성;백주흠;박찬기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.229-232
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    • 1997
  • In this paper, we describe about the field test of polymeric long rod insulator for rail way. For the test, insulators were mounted at the feeder line system at Kuro base station and were exposed to environmental, electric, and mechanical stress. During the test service, the leakage current was been monitoring and stored the data by the leakage current measuring system that was specially constructed. After about 6 months, diagnostic tests for evaluation of the installed insulators were conducted. The test results developed that the developed polymeric insulator is valid to use for rail way.

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Mixed matrix membranes for dye removal

  • Evrim Celik-Madenli;Dilara Kesiktas
    • Membrane and Water Treatment
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    • v.14 no.4
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    • pp.175-180
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    • 2023
  • Mixed matrix membranes (MMMs) can be a promising alternative for the solution of dye removal from coloured effluents. Polymeric membranes are widely used due to their good film-forming ability, flexibility, separation properties, and cost. However, they have low mechanical, chemical, and thermal resistances. Moreover, the fouling of polymeric membranes is high because of their hydrophobic nature. Hence, there is an increasing interest in organic-inorganic hybrid membranes as a new-generation membrane material. It has been shown that carbon nanotubes have the potential to increase the material properties of polymers with their low density, high strength, hardness, and exceptional aspect ratio. In this work, carbon nanotubes blended MMMs were prepared and methyl orange removal efficiency of them was investigated. Compared to the bare membranes, MMMs showed not only increased hydrophilicity, water content, and pure water flux but also increased methyl orange rejection and flux recovery

Numerical Analysis to Predict the Time-dependent Behavior of Automotive Seat Foam (자동차용 시트 폼의 시간 의존적 거동 예측을 위한 수치해석)

  • Kang, Gun;Oh, Jeong Seok;Choi, Kwon Yong;Kim, Dae-Young;Kim, Heon Young
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.6
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    • pp.104-112
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    • 2014
  • Generally, numerical approaches of evaluation for vehicle seat comfort have been studied without considering time-dependent characteristics and the only seating moment have been considered in seat design. However, the comfort not only at the seating moment but also in the long-term should be evaluated because the passengers are sitting repeatedly on the seat to drive the vehicle for hours. So, the aim of this paper is to carry out a quantitative evaluation of the time-dependent mechanical characteristics of seat foams and to suggest a process for predicting the viscoelastic deformation of seat foam in response to long-term driving. To characterize the seat materials, uniaxial compression and tension tests were carried out for the seat foam and stress relaxation tests were performed for evaluating the viscoelastic behavior of the seat foam. A unit solid element model was used to verify the reliability of the material model with respect to the compression behavior of the seat foam. It is not straightforward to evaluate the time-dependent compression of foams using the explicit solver because the viscoelastic material model is limited. To use the explicit solver, the material model must be modified using stress-degradation data. Normalized stress relaxation moduli were added to the stress-strain curves obtained under static conditions to achieve a time-dependent set of stress-strain relations that were compatible with the implicit solver. There was good agreement between the analysis results and experimental data.