• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.565-569
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• 1999

In these days, the silicone insulators have been increasingly studied and applied for outdoor insulators because it has superior characteristics than porcelain and glass insulators, which have been used for outdoor insulators. First of all, The excellent performance of the silicone rubber in polluted and wet conditions is attributed to the ability of the material to maintain the hydrophobicity of the surface in the presence of severe contamination and wet conditions. This is because of the presence of low molecular weight mobile fluid in the silicone rubber which diffuses to the surface and to above the contamination layer. But, the leakage current and some surface discharge occurs on surface of the composite polymeric insulation materials when the insulator is used for a long time with severe contaminative condition and it can lead the contamination flashover. So the leakage current and the discharge current are important to estimate the condition of the silicone rubber surface. In this paper, the average leakage current, the relation of surface discharge current and phase angle were study to investigate electrical conduction of silicone rubber surface with the salt fog condition.

• 한국전산구조공학회논문집
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• 제29권5호
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• pp.437-445
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• 2016

현재 많은 산업에서 구조물의 온도환경 유지를 위한 단열재로 폴리우레탄 폼이 사용되며, 수명 동안 정적 및 동적의 다양한 하중이 이에 부과된다. 폴리우레탄 폼은 고분자재료로써 다공성이며, 단열성능은 내부기공의 크기에 크게 의존한다. 또한, 폴리우레탄 폼의 기계적 거동은 변형률 속도 및 온도에 대한 의존성이 큰 동시에 압축에 대하여 큰 비선형 연성거동을 보인다. 이러한 비선형 연성 압축거동 중에 폴리우레탄 폼은 변형률의 증가에 따라 기공율과 탄성계수의 감소를 보인다. 따라서 본 연구에서는 상기 특성들을 포함한 폴리우레탄 폼의 변형률 속도 및 온도 의존 비선형 압축거동을 모사하기 위하여 온도 의존 손상 점소성 구성방정식이 개발되었다.

• Macromolecular Research
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• 제15권7호
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• pp.676-681
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• 2007

A process designed to synthesize rigid polyurethane foam (PUF) with insulative properties via the modulation of PUF cell size via the addition of clay and the application of ultrasound was assessed. The blowing agents utilized in this study include water, cyclopentane, and HFC-365mfc, all of which are known to be environmentally-friendly blowing agents. The rigid PUFs were prepared from polymeric 4,4'-diphenylmethane diisocyanate (PMDI) and polyether polyol with a density of $50kg/m^3$. In addition, rigid PUFs/clay nanocomposites were synthesized with clay modified by PMDI with and without the application of ultrasound. The PUF generated using water as a blowing agent evidenced the highest tensile strength. The tensile strength of the PUF/nanocomposites was higher than that of the neat PUF and the strength was even higher with the application of ultrasound. The cell size of the PUF/clay nanocomposites was less than that of the neat PUF, regardless of the type of blowing agent utilized. It appears that the higher tensile strength and lower cell size of the PUF/clay nanocomposites may be attributable to the uniform dispersion of the clay via ultrasonic agitation. The thermal conductivity of the PUF/clay nanocomposites generated with HCFC-141b evidenced the lowest value when PUF/clay nanocomposites were compared with other blowing agents, including HFC-365mfc, cyclopentane, and water. Ultrasound has also proven effective with regard to the reduction of the thermal conductivity of the PUF/clay nanocomposites with any of the blowing agents employed in this study. It has also been suggested that the uniformly dispersed clay particles in the PUF matrix function as diffusion barriers, which prevent the amelioration of the thermal insulation property.