• 제목/요약/키워드: Polymeric effect

검색결과 399건 처리시간 0.029초

납의 생물흡착에 미치는 세포외고분자물질의 영향 (Effect of Extracellular Polymeric Substances(EPS) on the Biosorption of Lead by Microorganisums)

  • 서정호;김동석;송승구
    • KSBB Journal
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    • 제14권1호
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    • pp.66-70
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    • 1999
  • A pullulans와 S Cerevisiae의 납 제거 특성을 비교하고, 미생물이 분비하는 세포외고분자물질의 영향에 대해 고찰하였다. A pullulans의 경우에 미생물의 보관시간이 증가할수록 미생물이 분비하는 세포외고분자물질의 양도 증가하였으며, 납 제거능도 우수해졌다. 그러나 세포외고분자물질을 제거한 A pullulans세포에서는 납 흡착량이 약 10%로 매우 적었다. S Cerevisiae의 경우에는 세포외고분자물질은 거의 분비되지 않았으며, 보관시간에 따른 납 흡착량의 변화는 거의 없었다. 또한 보관시간이 경과할수록 흡착 평형에 도달하는 시간은 점점 짧아졌다. 따라서 A pullulans와 S Cerevisiae의 납제거 기작은 세포외고분자물질의 유무에 따라 매우 달라짐을 알 수 있었다.

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초고압용 폴리머 애자의 산불영향 연구 (A study of the Influence of Forest Fire on Polymer Insulator for UHV)

  • 최인혁;최장현;정윤환;이동일
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2005년도 춘계학술대회논문집
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    • pp.254-259
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    • 2005
  • Big fire such as mountain fire my cause the prevention of the functions of the overhead cables and insulators, which may affect the operation of the transmission lines. Therefore, in order to understand the effect of the mountain fire on the polymeric insulator for transmission lines, the author observed the deformation of the sheds of the polymeric insulators and the change of the discs of the porcelain insulators under fire, and investigated the electrical and mechanical characteristics of the insulators after the ignition test. As the result the following conclusions were obtained. First, the porcelain insulator was degraded in electrical characteristics when the insulator was subjected to the fire for approximately 5 minutes; whereas, the polymeric insulator was not degraded though there were some damage on its sheds. Second, after 20 minute exposure to the fire, the polymeric insulator lost a lot of parts of sheds, but the electrical characteristics was lowered by around 20%, but the porcelain insulators were electrically degraded by more than 80%.

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섬유강화 고분자 복합재료의 압축성형에 있어서 분리 ${\cdot}$ 배향에 미치는 금형온도의 영향 (Effect of Mold Temperature on the Separation and the Orientation during Compression Molding of Fiber-Reinforced Polymeric Composites)

  • 이동기;한길영;김이곤
    • 한국해양공학회지
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    • 제9권2호
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    • pp.123-132
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    • 1995
  • During compression molding of fiber-reinforced polymeric composites, microstructural changes such as the fiber-matrix separation and the fiber orientation are occurred by the flow of composite materials. Since the nonhomogeneity and anisotropy of composites are caused by the separation and orientation of fibers. On the other hand, the separation and the orientation of fibers are inseparably related to each other. In this paper the degree of nonhomogeneity which is a measure of the separation is obtained using one-dimensional rectangular shaped part compression molding. And the orientation function is measured by the image processing using soft X-rayed photograph and image scanner. We study effects of the mold temperature on the degree of nonhomogeneity and the orientation function.

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Relationship between Replication and Structure of Micro/Nano Molded Parts

  • Ito, Hiroshi;Kazama, Kunihiko;Kikutani, Takeshi
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.368-368
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    • 2006
  • Micro-molded parts can be defined as parts with microgram weight, parts with micro-structured surface, and parts with micro-precision. In this study, various micro-scale molded parts for various polymers were produced by using a precision micro-molding machine. Molded parts with nano-structure surface were also produced to analyze the effect of molding conditions on replication of surface pattern and higher-order structure development of molded parts. Replication of molded parts was influenced by material properties, molding conditions and size of surface pattern. Higher-order structure of molded parts was investigated by using polarized microscope. Skin-shear-core regions inside the molded parts were observed and shear region affected to surface replication.

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내열성 에나멜 바니쉬 (Heat-resistant Enamel Varinish)

  • 김양국;배헌재
    • 공업화학
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    • 제4권2호
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    • pp.264-272
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    • 1993
  • 소형화되는 전기, 전자 제품의 효율성과 신뢰성를 제고시키기 위해서 주요 부품인 마그네트 와이어의 내열성에 대한 연구가 진행되고 있다. 마그네트 와이어의 내열성은 주로 에나멜 바니쉬로부터 형성되는 고분자 피막의 물성과 밀접한 관계가 있다. 내열성 에나멜 바니쉬의 설계와 도막 형성과정이 와이어의 물성과 관련지어 논의되었다. 아울러 내열성에 영향을 주는 요인들을 완성 와이어의 물성 평가방법을 통하여 고찰하였다.

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Drug-Release Behavior of Polymeric Prodrugs of Ibuprofen with PEG and Its Derivatives as Polymeric Carriers

  • Lee, Chao-Woo
    • Macromolecular Research
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    • 제12권1호
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    • pp.71-77
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    • 2004
  • We have synthesized various types of poly(ethylene glycol) (PEG)-ibuprofen conjugates by nucleophilic substitution of bromo-terminated PEG with ibuprofen-Cs salt. The conversion of the terminal hydroxyl groups to bromo-termini was quantitative, as was the drug conjugation process, which suggests that the present synthetic method is very useful for the preparation of PEG-based prodrugs from pharmaceuticals having carboxyl functionalities. The drug-release behavior of the prodrugs was examined in both phosphate buffer (PBS, pH 7.4) and rat plasma. From the drug-release behavior in PBS, we determined that each prodrug has high storage stability. The drug-release rate was observed to be much faster in rat plasma than in buffer solution as a result of the acceleration effect provided by enzymes present in the plasma. The drug-release rate in rat plasma depends on the degree of molecular aggregation of the prodrugs, which can be changed effectively by the nature of their spacer groups or by the use of Pluronic as the polymer carrier.

고분자 애자 하우징용 HTV 실리콘 고무의 자외선 조사에 따른 표면열화 (Surface Degradation of HTV silicone Rubber used for a Polymeric Insulator by UV Irradiation)

  • 연복희;이상용;허창수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.173-176
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    • 2000
  • In this paper, we investigated the surface degradation of HTV silicone rubber used for a polymeric insulator by UV irradiation. To study the surface ageing properties by W irradiation, we used the corona discharge charging and contact angle. Therefore, we observed the change of surface charge retention and decrease of surface hydrophobicity. Also, we discussed the chemical change in the surface range using the analytic equipment such as SEM, ATR-FTIR, ESCA. Therefore, it is found that the scissor of characteristic bonding and the reattachment of oxidant bonding was developed by UV rays radiation. As discussing the corona ischarge charging and the change of contact angle, it is found the effect of UV irradiation and the mechanism of chemical reaction

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Influences of Ionizing Radiation on Mechanical and Electrical Properties of Polymer Composites Based on Poly (vinyl ether of ethyleneglycol)

  • V.A. Kovtunets;A.I. Kupchishin;G.A. Mun;Z.S. Nurkeeva;G.T. Akhmetkalieva;V.V. Khutoryanskiy;Soh, Dea-wha
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2004년도 SMICS 2004 International Symposium on Maritime and Communication Sciences
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    • pp.85-87
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    • 2004
  • Radiation technology is an effective way for regulating polymeric materials to physicochemical and mechanical properties. New polymeric hydrogels based on vinyl ethers have been synthesized by the ${\gamma}$-initiated polymerization method. In this paper, we have studied the effect of radiation on mechanical and electrochemical properties of new rubber-like polymeric composite materials based on poly (vinyl ether of ethyleneglycol: PVEEG).

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Controlled Release of Epidermal Growth Factor (EGF) from EGF-loaded Polymeric Nanoparticles Composed of Polystyrene as Core and Poly(methacrylic acid) as Corona in vitro

  • Park, In-Kyu;Seo, Seog-Jin;Akashi, Mitsuru;Akaike, Toshihiro;Cho, Chong-Su
    • Archives of Pharmacal Research
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    • 제26권8호
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    • pp.649-652
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    • 2003
  • Polymeric nanoparticles composed of polystyrene (PS) as core and poly(methacrylic acid) (PMA) as corona were prepared by the dispersion copolymerization. The potential of the nanoparticles as carriers for recombinant human epidermal growth factor (EGF) was investigated. The nanoparticles showed monodispersity and good water-dispersibility. The loading content of EGF to the nanoparticles was very high due to electrostatic interaction between EGF and nanoparticles. EGF was released as a pseudo-zero order pattern after initial burst effect. The nanoparticles were sufficient for A431 cells proliferation.