• Title/Summary/Keyword: Polymeric effect

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Characteristics of micro-dimple formed on polyoxymethylene surface by Nd:YAG laser texturing technique (Nd:YAG 레이저를 이용한 polyoxymethylene 표면의 마이크로 딤플가공 및 특성에 관한 연구)

  • Cho, Min-Haeng;Lee, Jae-Bong;Lee, Seong-Hyuk;Kim, Joo-Han
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.193-197
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    • 2008
  • Array of micro-dimple on polyoxymethylene (POM) surface was fabricated using Q-switched Nd:YAG laser and its characteristics were studied in terms of heat affected zone (HAZ), dimple geometry, and the effect of specimen surface roughness. Process parameters such as lamp current, process time, and the stream of air in order to minimize HAZ and flow of molten polymer into cavity were extensively studied in this work. Dimple geometry was further investigated by 3-D optical microscopy to provide deep insight into morphological analysis near the dimples. This paper also presents the applicapability of micro-dimples in polymeric tribological system, such as a thrust bearing. Micro-dimples were expected to provide low coefficient of friction and enhanced lubricity at the sliding interface.

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Simultaneous determination of bisphenol A, chlorophenols and alkylphenols by solid-phase extraction and HPLC

  • Lee, Taejoon;Park, Keun-Young;Pyo, Dongjin
    • Analytical Science and Technology
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    • v.30 no.1
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    • pp.20-25
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    • 2017
  • An analytical method for determining potential endocrine disruptors (bisphenol A, 2-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, pentachlorophenol, p-t-butylphenol, p-pentylphenol, p-hexylphenol, p-t-octylphenol, p-heptylphenol, nonylphenol) by solid-phase extraction (SPE) and High Perfomance Liquid Chromatography(HPLC) equipped with fluorescence and variable wavelength detector has been developed. The SPE process for sample concentration was performed on a commercially available Oasis HLB cartridge packed with polymeric sorbents. The effect of elution solvent and elution volume on the recoveries of the analytes were investigated with HPLC. Average recovery of >85% was achieved with 60mg sorbents using 5mL of methanol as elution solvent. Phenolic compounds in canned drinks, beverages and water samples were surveyed by this proposed method.

Early Strength and Properties of EVA Powder Modified High Strength Concrete (EVA Powder 개질 고강도 콘크리트의 초기강도 및 수밀특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.123-127
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    • 2005
  • EVA Powder modified high strength concretes were prepared by varying polymer/binder mass ratio with a constant water/binder mass ratio of 0.3. The effect of EVA powder on the slump, hydration heat, compressive and flexural strength, toughness and water absorption ratio was studied. In hydration heat test, temperature of hydration reaction displayed almost fixed level regardless of containing rate of EVA powder, but peak time of hydration reaction displayed late inclination as containing rate of powder increases. With the same water/binder mass ratio, the compressive strength and water absorption of EVA powder modified concretes decreased slightly when EVA powder was added and the flexural strength of EVA powder modified concretes rised slightly when EVA powder was added. Also, the toughness of the modified concretes can be improved markedly. The interpenetrating structure between the polymeric phase and cement hydrates formed at a $2{\sim}6%$(containing rate of EVA powder). The properties of the polymer modified concretes were influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases.

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On bending, buckling and vibration responses of functionally graded carbon nanotube-reinforced composite beams

  • Tagrara, S.H.;Benachour, Abdelkader;Bouiadjra, Mohamed Bachir;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • v.19 no.5
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    • pp.1259-1277
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    • 2015
  • In this work, a trigonometric refined beam theory for the bending, buckling and free vibration analysis of carbon nanotube-reinforced composite (CNTRC) beams resting on elastic foundation is developed. The significant feature of this model is that, in addition to including the shear deformation effect, it deals with only 3 unknowns as the Timoshenko beam (TBM) without including a shear correction factor. The single-walled carbon nanotubes (SWCNTs) are aligned and distributed in polymeric matrix with different patterns of reinforcement. The material properties of the CNTRC beams are assessed by employing the rule of mixture. To examine accuracy of the present theory, several comparison studies are investigated. Furthermore, the effects of different parameters of the beam on the bending, buckling and free vibration responses of CNTRC beam are discussed.

Fabrication of Sub-$10{\mu}m$ Screen Printed Organic Thin-Film Transistors on Paper

  • Jo, Jeong-Dai;Yu, Jong-Su;Yun, Seong-Man;Kim, Dong-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.896-898
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    • 2009
  • The printed electrodes of organic thin-film transistors (OTFTs) were fabricated by screen printing using nanoparticle silver pastes. The screen printed OTFT corresponds to channel lengths between 7.6 to 82.6 ${\mu}m$ (designed L=10 to 80 ${\mu}m$) on the $150{\times}150mm^2$ paper. The channel length deviations for 40 to 80 ${\mu}m$ patterns were less than 5 %. However, the channel lengths for 10 to 30 ${\mu}m$ patterns were increased by 20 %. The screen printed bis(triisopropyl-silylethynyl) pentacene (TIPS-pentacene) OTFTs obtained had a field-effect mobility as large as 0.08 (${\pm}0.02$) $cm^2$/Vs, an on/off current ratio of $10^5$ and a subthreshold slope of 1.95 V/decade.

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Electrical Characteristics of Bottom-Contact Organic Thin-Film-Transistors Inserting Adhesion Layer Fabricated by Vapor Deposition Polymerization and Ti Adhesion Metal Layer

  • Park, Il-Houng;Hyung, Gun-Woo;Choi, Hak-Bum;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.958-961
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    • 2007
  • The electrical characteristics of organic thin-filmtransistor (OTFTs) can be improved by inserting adhesion layer on gate dielectrics. Adhesion layer was used as polymeric adhesion layer deposited on inorganic gate insulators such as silicon dioxide $(SiO_2)$ and it was formed by vapor deposition polymerization (VDP) instead of spin-coating process. The OTFTs obtained the on/off ratio $of{\sim}10^4$, threshold voltage of 1.8V, subthreshold slop of 2.9 V/decade and field effect mobility about $0.01\;cm^2/Vs$.

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Effect of laminate configuration on the free vibration/buckling of FG Graphene/PMMA composites

  • Zeverdejani, Mehran Karimi;Beni, Yaghoub Tadi
    • Advances in nano research
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    • v.8 no.2
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    • pp.103-114
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    • 2020
  • In this research, buckling and free vibration of rectangular polymeric laminate reinforced by graphene sheets are investigated. Various patterns are considered for augmentation of each laminate. Critical buckling load is evaluated for different parameters, including boundary conditions, reinforcement pattern, loading regime, and laminate geometric states. Furthermore, vibration analysis is investigated for square laminate. Elastic properties of the composite are calculated using a combination of both molecular dynamics (MD) and the rule of mixture (MR). Kinematics of the plate is approximated based on the first shear deformation theory (FSDT). The current analysis is performed based on the energy method. For the numerical investigation, Ritz method is applied, and for shape functions, Chebyshev polynomials are utilized. It is found that the number of layers is effective on the buckling load and natural frequency of laminates which made from non-uniform layers.

Preparation and characterization of ZnWO4 nanocrystallines and single crystals

  • Lim, Chang-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.5
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    • pp.197-201
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    • 2010
  • $ZnWO_4$ nanocrystallines were prepared from polymeric complex method using microwave irradiation. The average nanocrystalline sizes were 18~25 nm showing an ordinary tendency to increase with the temperatures from 400 to $600^{\circ}C$. Bulk type single crystals of $ZnWO_4$ were grown successfully in the [100], [010] and [001] directions using the Czochralski method. The effect of the growth parameters, such as the rotation speed, pulling rate and diameter of the grown crystals, were examined. The hardness, thermal expansion coefficients and dielectric constants of the crystals were evaluated.

Facile Preparation of Silver Nanoparticles and Application to Silver Coating Using Latent Reductant from a Silver Carbamate Complex

  • Kim, Kyung-A;Cha, Jae-Ryung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.505-509
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    • 2013
  • A low temperature ($65^{\circ}C$) thermal deposition process was developed for depositing a silver coating on thermally sensitive polymeric substrates. This low temperature deposition was achieved by chemical reduction of a silver alkylcarbamate complex with latent reducing agent. The effects of acetol as a latent reducing agent for the silver 2-ethylhexylcarbamate (Ag-EHCB) complex and their blend solutions were investigated in terms of reducing mechanism, and the size and shape of silver nanoparticles (Ag-NPs) as a function of reduced temperature and time, and PVP stabilizer concentration were determined. Low temperature deposition was achieved by combining chemical reduction with thermal heating at $65^{\circ}C$. A range of polymer film, sheet and molding product was coated with silver at thicknesses of 100 nm. The effect of process parameters and heat treatment on the properties of silver coatings was investigated.

Photopolymers for 3D optical recording (3차원 광기록용 포토폴리머)

  • Lee, Hyo-Jin;Kim, Jeong-Hun;Kim, Eun-Gyeong
    • Proceedings of the Optical Society of Korea Conference
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    • 2006.07a
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    • pp.411-412
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    • 2006
  • Photopolymers have been of considerable due to their easy of processing and high sensitivity. Exposure of photopolymers to optical source produce recroding mark where the light initiates a photoreaction that occurs preferentially in regions of high illumination. The photoreaction typically involves polymerization of an acrylic or epoxy monomer dispersed together with a photoinitiators in a polymeric binder. A number of photopolymerizable materials have been developed to apply them in 3D optical recording such as holographic or 3-dimensional data storage. In this presentation, photopolymers derived from sol-gel matrix and transparent polymer binder are summarized. The effect of monomer composition and plasticizers on optical recording will be discussed based on the monomer transport during the photopolymerization.

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