Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
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Simultaneous determination of bisphenol A, chlorophenols and alkylphenols by solid-phase extraction and HPLC

  • Received : 2016.10.28
  • Accepted : 2017.02.05
  • Published : 2017.02.25
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Abstract

An analytical method for determining potential endocrine disruptors (bisphenol A, 2-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, pentachlorophenol, p-t-butylphenol, p-pentylphenol, p-hexylphenol, p-t-octylphenol, p-heptylphenol, nonylphenol) by solid-phase extraction (SPE) and High Perfomance Liquid Chromatography(HPLC) equipped with fluorescence and variable wavelength detector has been developed. The SPE process for sample concentration was performed on a commercially available Oasis HLB cartridge packed with polymeric sorbents. The effect of elution solvent and elution volume on the recoveries of the analytes were investigated with HPLC. Average recovery of >85% was achieved with 60mg sorbents using 5mL of methanol as elution solvent. Phenolic compounds in canned drinks, beverages and water samples were surveyed by this proposed method.

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References

  1. J. S. Gandara, S. P. Abuin, P. P. Losada, and J. S. Lozano, J. Chrom. Sci., 31, 450-454 (1993). https://doi.org/10.1093/chromsci/31.11.450
  2. W. Summerfield, A. Goodson, and I. Cooper, Food Addit. Contam., 15, 818-830 (1998). https://doi.org/10.1080/02652039809374716
  3. J. E. Biles, T. P. McNeal, T. H. Begley, and H. C. Hollifield, J. Agric. Food Chem., 45, 3541-3544 (1997). https://doi.org/10.1021/jf970072i
  4. H. Bagheri, A. Mohammadi, and A. Salemi, Anal. Chim. Acta, 513, 445-449 (2004). https://doi.org/10.1016/j.aca.2004.03.020
  5. O. Jauregui and M. T. Galceran, Anal. Chim. Acta, 340, 191-199 (1997). https://doi.org/10.1016/S0003-2670(96)00504-1
  6. C. Lambert and M. Larroque, J. Chromatogr. Science, 35, 57-62 (1997). https://doi.org/10.1093/chromsci/35.2.57
  7. K. Miyabe, N. Nomura, F. Morishita, S. Kurata, H. Asamura, and Y. Imada, Anal. Sci. 14, 355-360 (1998). https://doi.org/10.2116/analsci.14.355
  8. D. Barceló and M. C. Hennion, Anal. Chim. Acta, 318, 1-14 (1995). https://doi.org/10.1016/0003-2670(95)00423-8
  9. V. Pichon and M. C. Hennion, J. Chromatogr. A, 665, 269-281 (1994). https://doi.org/10.1016/0021-9673(94)85057-7
  10. J. E. Bils, K. D. White, T. P. McNeal, and T. H. Begley, J. Agric. Food Chem., 47, 1965-1969 (1999). https://doi.org/10.1021/jf9810867

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