• Title/Summary/Keyword: Polymeric

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Molecular Orbital Calculation for Polymeric Beryllium Hydride, Polyeithylene and Polymeric Boron Hydride According to the Pseudo-Lattice Method

  • Oh, Seok-Heon;Jhang, Man-Chai;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.1
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    • pp.37-41
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    • 1984
  • The pseudolattice calculations in the CNDO/2 level of approximation are carried out for polymeric beryllium hydride, polyethylene and polymeric boron hydride. Since there is no evidence on the geometry for polymeric boron hydride, the two possible geometries are assumed. One is a polyethylene-type geometry and the other is a polymeric beryllium hydride-type geometry. In order to compare their relative stability, we calculate polyethylene and polymeric beryllium hydride and then compare with polymeric boron hydride having the assumed structures. The total energy calculation indicates that a polymeric beryllium bydride-type geometry is more stable than a polyethylene-type geometry. Our results obtained for polyethylene are in good agreement with those given by CNDO/2 crystal orbital. From the convergence problem with respect to the number of unit cells (M), the calculation with value of 4 for M can be considered to give the convergence limit results.

Functional Polymeric Materials for Biomedical Application (생체의료용 기능성 고분자 재료의 개발)

  • Sung, Yong-Kiel;Song, Dae-Kyung;Sung, Jung-Suk
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.1-9
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    • 2006
  • The development of functional polymeric materials for biomedical application has progressed on the basis of functionality, biocompatibility and biodegradability. In this paper we review the functional polymeric biomaterialsbased systems and propose a range of biomedical applications in the near future. These systems include the functional biodegradable polymers synthesized in our research laboratory, biodegradable polymeric materials, thermosensitive polymeric materials, cationic polymeric materials, non-condensing polymeric biomaterials, bio-polymeric DNA matrix for tissue engineering, and polymeric biomaterials for RNA interference (RNAi) technology.

Investigations of Accelerated Aged Polymeric Insulators Using Partial Discharge Signal Measurement and Analysis

  • Mekala, K.;Chandrasekar, S.;Ravindran, R. Samson
    • Journal of Electrical Engineering and Technology
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    • v.10 no.1
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    • pp.299-307
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    • 2015
  • Reduction in pollution performance of polymeric insulators, aged due to water absorption stress and thermal stress, is a major threat to the reliable operation of power transmission and distribution system. Formation of partial discharges on the surface of wet polluted insulator plays a major role in determining the life time and pollution performance of outdoor polymeric insulators. However, reports on partial discharge characteristics of water absorption stress aged and thermal aged polymeric insulators are scanty. This paper discusses the pollution performance characteristics of accelerated aged polymeric insulators using the advanced ultra wide band PD signal measurement and analysis. Laboratory experiments on accelerated aged polymeric insulators were carried out as per IEC 60507 under AC voltage, at different humidity and contamination levels using NaCl as a contaminant. PRPD pattern and Time-Frequency map analysis of PD signals were carried out. From the results, it can be speculated that PD analysis is a well suited technique to understand the pollution performance of aged polymeric insulators.

Characteristics of ITO/polymeric Films with Change of Oxygen Partial Pressure (산소분압의 변화에 따른 ITO/polymeric 박막의 특성)

  • 신성호;김현후
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.8
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    • pp.846-851
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    • 2004
  • Transparent conducting indium tin oxide (TC-ITO) thin films on polymeric substrates have been deposited by a dc reactive magnetron sputtering without heat treatments. The polymeric substrates are acryl (AC), poly carbornate (PC), and polyethlene terephthalate (PET) as well as soda lime glass is also used to compare with the polymeric substrates. Sputtering parameters are an important factor for high quality of TC-ITO thin films prepared on polymeric substrates. Furthermore, the material, electrical and optical properties of as-deposited ITO films are dominated by the ratio of oxygen partial pressure. As the experimental results, the surface roughness of ITO films becomes rough as the oxygen partial pressure increases. The electrical resistivity of as-deposited ITO films decreases initially, and then increases with the increase of oxygen partial pressure. The optical transmittance at visible wavelength for all polymeric substrates is above 82 %.

Temperature and Leakage Current Characteristics of Polymeric Surge Arrester with Housing (폴리머 피뢰기의 구조에 따른 온도와 누설전류 특성)

  • Cho, Han-Goo;You, Dae-Hoon;Lee, Un-Yong;Kim, Ha-Na
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.3
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    • pp.273-280
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    • 2007
  • In this paper, the ZnO surge arrester performance of power distribution class has been studied under different manufacturing conditions such as housing materials(polymeric, porcelain), interface sealants and one-body molding type. In the recent years, the polymeric ZnO surge arresters have been developed and put into operations based on their excellent characteristics. For polymeric surge arresters, the inner gas volume is extremely small, especially in solid insulation polymeric arresters there are not any gas volume inside arresters in the structure due to polymeric materials are filled into the internal gas volume. The sealing integrity is related to safe operation of surge arrester, the prime failure reason of porcelain housed arresters is moisture ingress. In this paper, the sealing integrity of polymeric surge arresters is investigated with moisture multi-aging test and ingress test. The evaluation techniques are used to inspect the sealing integrity of polymeric arresters, including leakage current, surface temperature, reference voltage and dissipation factor.

Effect of Fiber Orientation on the Tensile Strength in Long-Fiber Reinforced Polymeric Composites (장섬유강화 고분자 복합재료에서 인장강도에 미치는 섬유배향의 영향)

  • Lee, Dong-Gi;Sim, Jae-Ki;Han, Gil-Young;Kim, Hyuk;Kim, Jin-Woo;Lee, Jung-Ju
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.55-60
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    • 2003
  • Case that long-fiber reinforced polymeric composites of fiber orientation situation of a direction state is J=1 that is direction of tensile strength of another state appeared highest. And theoretical tensile strength value of long-fiber reinforced polymeric composites board of fiber orientation situation of a direction state appeared similarly with tensile strength value that long-fiber reinforced polymeric composites board of fiber orientation situation of a direction state. Also, than case that efficiency of fiber orientation situation of long-fiber reinforced polymeric composites is J=1 in it is J=0.1 of fiber orientation situation effect of long-fiber reinforced polymeric composites about 60% high appear.

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Pyrolytic Carbon Membranes for Air Separations (공기 분리용 열분해 탄소막)

  • Singh, Anshu;Koros, W.J.
    • Membrane Journal
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    • v.7 no.1
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    • pp.15-21
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    • 1997
  • Carbon molecular sieve (CMS) membranes were synthesized by the pyrolysis of polymeric precursors. The CMS materials had oxygen-nitrogen selectivities much higher than those observed for the polymeric precursors. Typically molecular sieving materials have diffusion selectivities much higher than polymeric materials. This has been identified as a result of higher entropic selectivity of the molecular sieving materials. A study of the development of molecular sieving properties as the polymeric precursor is pyrolyzed into a CMS material will offer us an insight into polymeric molecular structures needed for enhanced entropic selectivity membrane materials.

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Methotrexate-Incorporated Polymeric Micelles Composed of Methoxy Poly(ethylene glycol)-Grafted Chitosan

  • Jeong, Young-Il;Seo, Dong-Hyuk;Kim, Don-Gon;Choi, Chang-Yong;Jang, Mi-Kyeong;Nah, Jae-Woon;Park, Yoon-Kyung
    • Macromolecular Research
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    • v.17 no.7
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    • pp.538-543
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    • 2009
  • In this study, methotrexate (MTX)-encapsulated polymeric micelles using methoxy poly(ethylene glycol) (MPEG)-grafted chitosan (ChitoPEG) copolymer were prepared. The MIX-incorporated polymeric micelles of ChitoPEG copolymer has a particle size of around 50-100 nm. In 1H nuclear magnetic resonance (NMR) study, the specific peaks of MTX disappeared in heavy water ($D_2O$) and only the specific peak of MPEG was observed, while all of the peaks were confirmed in dimethyl sulfoxide (DMSO). These results indicated that MTX was complexed with chitosan and then formed an ion complex inner-core of the polymeric micelle in an aqueous environment. The drug contents of the polymeric micelle were around $4{\sim}12%$ and the loading efficiency of MTX in the polymeric micelles was higher than 60% (w/w) for all of the formulations. The cytotoxicity of MIX and MTX-incorporated polymeric micelle against CT26 tumor cells was not significantly changed.

Diffusional Behaviors of the Fabricated Polymeric Films Containing Various Excipients (다양한 첨가제를 함유하는 고분자 필름의 확산거동)

  • Lee, Beom-Jin;Jung, Hyun;Cui, Jing-Hao;Kim, Soo-Hee
    • Journal of Pharmaceutical Investigation
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    • v.29 no.3
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    • pp.185-191
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    • 1999
  • The polymeric films containing drug and various excipients were fabricated using aqueous-based $Eudragit^{\circledR}$ RS 30D dispersions. The diffusional behaviors and mechanism of the fabricated polymeric film were investigated using Keshary-Chien diffusion cell. The melatonin was used as a model drug. The diffusion behaviors of drug through the fabricated polymeric films were highly dependent on drug concentration in donor part, polymer contents and drug concentration, and the types of plasticizers and solubilizers. The fabricated polymeric films containing excipients and solubilizers could be applied for the controlled release of poorly water-soluble drug and for the preparation of drug-containing latex films for topical or oral drug delivery.

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