• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.324-327
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• 2004

In this paper, fundamental properties of Polymer Concrete made from unsaturated polyester resin based on recycled PET and recycled aggregate(RPC) were investigated. Resins based on recycled PET and recycled aggregate offer the possibility of low source cost for forming useful products, and would also help alleviate an environmental problem and save energy. The results of test for resin contents and recycled aggregate ratio are showed that the strength of RPC increases with resin contents relatively, however beyond a certain resin content the strength does not change appreciably, and the relationship between the compressive strength and aggregate contents at resin $9\%$ has a close correlation linearly whereas there is no correlation between the compressive strength and the flexural strength of RPC with recycled concrete aggregate.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2004.11a
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• pp.43-48
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• 2004

• Bulletin of the Korean Chemical Society
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• v.10 no.4
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• pp.331-335
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• 1989

Polymer bound 1-phenyl-3-methyl-4-oximinopyrazoles were prepared through a series of chemical modifications of Merrifield's resin (chloromethylpolystyrene-$1{\%}$ DVB-copolymer). Several polymer active esters of N-blocked amino acids were prepared from the polymer bound 1-phenyl-3-methyl-4-oximinopyrazoles. Polymer bound active esters were found to be highly reactive in N-acylation reaction. The resins were tested for the preparation of several dipeptides. The peptides were obtained in high yields within 10 minutes and the progress of the reactions could be easily followed up by the color change of the resin. The resulting peptides were characterized by NMR and other physical methods.

• Magazine of the Korea Concrete Institute
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• v.8 no.5
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• pp.135-143
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• 1996

Diffusion of water in hardened cement concrete and mortar influences on the dry shrinkage. creep. modulus of' elasticity, etc. In general, water loss through drying process in polymer-modified concrete and mortar is small compared with that of unmodified concrete and mortar due to the films formed by polymer as cement modifieder. The purpose of this study is to investigate the diffusion process of water in the polymer-modified mortars. The polymer-modified mortars using three polymer dispersions and epoxy resin are prepared with various polymer-cement ratios, and water diffusion coefficient of polymer-modified mortars according to inside water content is calculated. From the test results, the water diffusion coefficient of polymer modified mortars i s smaller than that of unmodified mortars and decreases with increasing polymer cement ratio.

• Journal of Adhesion and Interface
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• v.11 no.4
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• pp.155-161
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• 2010

A series of ethylene vinyl acetate (EVA) based hot melt adhesives containing different types and compositions of tackifier resins were prepared to investigate their rheological behavior and T-peel adhesion strength on polyurethane (PU) elastomeric sheets. C5 aliphatic hydrocarbon resin (C5 resin), C9 aromatic hydrocarbon resin (C9 resin), hydrogenated dicyclopentadiene resin ($H_2$-DCPD resin), and dicyclopentadiene and acrylic monomer copolymer resin (DCPD-acrylic resin) were used as the tackifiers for the hot melt adhesives. To determine the polarity of the tackifiers, their oxygen contents were analyzed, and the DCPDacrylic resin was found to contain an oxygen content higher than the other tackifiers. Only the DCPD-acrylic resin showed complete miscibility with EVA and the homogeneous phase of the hot melt adhesive blends at all compositions. The T-peel adhesion strength between the hot melt adhesives and polyurethane elastomeric sheets was mainly affected by the polarity of the tackifier resins in the hot melt adhesives, rather than by the storage moduli, G', of the hot melt adhesives themselves.

• Journal of the Korean Society of Safety
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• v.27 no.5
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• pp.117-125
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• 2012

In recent years, polymer concrete based on polyester resin have been widely generalized and the research of polymer concrete have been actively pursued by the technical innovations. Polymer concrete is a composite consisting of aggregates and an organic resin binder that hardens by polymerization. Polymer concrete are stronger by a factor of three or more in compression, a factor of four to six in tension and flexural and a factor of two in impact when compared with portland cement concrete. In view of the growing use of polymer concrete, it is important to study the physical characteristics of the material, emphasizing the short term properties as well as long term mechanical behavior. If polymer concrete is to be used in flexural load-bearing application such as in beam, it is imperative to understand the deformation of the material under sustained loading conditions. This study is proposed to empirical and mechanical model of polymer concrete tension creep using long-term experimental results and mathematical development. The test results showed that proposed model has been used successfully to predict creep deformations at a stress level that was 20 percent of the ultimate strength and viscoelastic behavior of recycled-PET polymer concrete is linear of stress level up to 30 percent. It is expected that the present model allows more realistic evaluation of varying stresses in polymer concrete structures with a constant loading.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.2A
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• pp.177-184
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• 2010

This study was performed to determine the effects of filling materials on the physical properties of permeable polymer concrete. The filling materials were ground calcium carbonate, ground granulated blast furnace slag and fly ash. In this experiment, permeable polymer concrete mixtures with unsaturated polyester resin contents from 5 to 7 weight %, filler/resin ratio of 0~2.0 and crushed coarse aggregate passing 15 mm sieve were prepared and coefficient of permeability, void ratio, compressive strength and flexural strength were tested. As the test results, increase in the strength and decrease in the coefficient of permeability of the permeable polymer concrete were generally observed with increasing the resin contents and filler/resin ratio. The compressive and flexural strength of the permeable polymer concrete were in the range of 8.0 to 35.0 MPa and 2.0 to 9.0 MPa respectively and the highest strength was shown at the mixtures with 7 weight % unsaturated polyester resin contents, 2.0 ratio of filler/resin and filler of ground calcium carbonate. On the other hand, in the level of 20 MPa compressive strength, the mixtures with filler of fly ash was shown as the most economic permeable polymer concrete.

• Journal of the Korea Concrete Institute
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• v.25 no.3
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• pp.313-320
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• 2013

In this study, performance of fiber-reinforced polymer-modified mortar was studied for the development of eco-friendly materials for high performance repair and reinforcement. The general cement mortar and eco-friendly UM resin was mixed with a certain percentage for increased durability. To increase the strength of the polymer-modified mortar, PVA fiber, steel fiber and hybrid fiber were added at a constant rate. Hybrid fiber is contains the same percentage of PVA fiber and steel fiber. In order to determine the strength properties of fiber-reinforced polymer-modified mortar, the compressive strength test, the splitting tensile strength test and the flexural strength test were performed. And, in order to determine the durability properties of fiber-reinforced polymer-modified mortar, water absorption test and chemical resistance test were performed. From the experimental results, polymer-modified mortar using UM resin was improved durability. And the tensile strength and flexural strength increased, which were the vulnerability of fiber reinforced polymer-modified mortar. From this study, fiber-reinforced polymer-modified mortar using eco-friendly UM resin can be used to repair and reinforcement for the external exposure of concrete structures to improve the durability.

• Macromolecular Research
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• v.13 no.3
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• pp.194-205
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• 2005

The network structure of Ni-coated carbon black (NCB) composites filled with phenolic resin was investigated by means of using scanning electron microscopy, viscosity, interfacial tension, shrinkability, Flory-Huggins interaction parameters, and swelling index. The electrical properties of the composites have been characterized by measurement of the specific conductivity as a function of temperature. Additionally, the variation of conductivity with temperature for the composites has been reported and analyzed in terms of the dilution volume fraction, relative volume expansion, and barrier heights energy. The thermal stability of phenolic-NCB composites has been also studied by means of the voltage cycle processes. The experimental data of EMI wave shielding were analyzed and compared with theoretical calculations. The mechanical properties such as tensile strength, tensile modulus, hardness and elongation at break (EB) of NCB-phenolic resin composites were also investigated.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.8
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• pp.758-763
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• 2006

We has been studied the thin film encapsulation effect for organic light-emitting diodes (OLED). To evaluate the passivation properties of the passivation layer materials, we have carried out the fabrication of green light emitting diodes with ultra violet(UV) light absorbing polymer resin, $SiO_2,\;and\;SiN_x$, respectively. From the measurement results of shrinkage properties according to the exposure time to the atmosphere, we found that $SiN_x$ thin film is the best material for passivation layer. We have investigated the emission efficiency and life time of OLED device using the package structure of $OLED/SiN_x/polymer$ resin/Al/polymer resin. The emission efficiency of this OLED device was 13 lm/W and life time was about 2,000 hours, which reach 95 % of the performance for the OLED encapsulated with metal.