• Title/Summary/Keyword: Polymer volume fraction

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Thermoelastic dynamic analysis of wavy carbon nanotube reinforced cylinders under thermal loads

  • Moradi-Dastjerdi, Rasool;Payganeh, Gholamhassan
    • Steel and Composite Structures
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    • v.25 no.3
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    • pp.315-326
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    • 2017
  • In this work, thermoelastic dynamic behavior of functionally graded carbon nanotube reinforced composite (FG-CNTRC) cylinders subjected to mechanical pressure loads, uniform temperature environment or thermal gradient loads is investigated by a mesh-free method. The material properties and thermal stress wave propagation of the nanocomposite cylinders are derived after solving of the transient thermal equation and obtaining of the time history of temperature field of the cylinders. The nanocomposite cylinders are made of a polymer matrix and wavy single-walled carbon nanotubes (SWCNTs). The volume fraction of carbon nanotubes (CNTs) are assumed variable along the radial direction of the axisymmetric cylinder. Also, material properties of the polymer and CNT are assumed temperature-dependent and mechanical properties of the nanocomposite are estimated by a micro mechanical model in volume fraction form. In the mesh-free analysis, moving least squares shape functions are used to approximate temperature and displacement fields in the weak form of motion equation and transient thermal equation, respectively. Also, transformation method is used to impose their essential boundary conditions. Effects of waviness, volume fraction and distribution pattern of CNT, temperature of environment and direction of thermal gradient loads are investigated on the thermoelastic dynamic behavior of FG-CNTRC cylinders.

Optimal Design of Laminate Composites with Gradient Structure for Weight Reduction

  • Back, Sung-Ki;Kang, Tae-Jin;Lee, Kyung-Woo
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.68-72
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    • 1999
  • In an effort to construct a structure under the design principle of minimal use of materials for maximum performances, a discrete gradient structure has been introduced in laminate composite systems. Using a sequential linear programming method, the gradient structure of composites to maximize the buckling load was optimized in terms of fiber volume fraction and thickness of each layer. Theoretical optimization results were then verified with experimental ones. The buckling load of laminate composite showed maximum value with the outmost [$0^{\circ}$] layer concentrated by almost all the fibers when the ratio of length to width(aspect ratio) was less than 1.0. But when the aspect ratio was 2.0, the optimum was determined in a structure where the thickness and fiber volume fraction were well balanced in each layer. From the optimization of gradient structure, the optimal fiber volume fraction and thickness of each layer were proposed. Experimental results agreed well with the theoretical ones. Gradient structures have also shown an advantage in the weight reduction of composites compared with the conventional homogeneous structures.

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Free vibration responses of nonlinear FG-CNT distribution in a polymer matrix

  • Zerrouki, Rachid;Hamidi, Ahmed;Tlidji, Youcef;Karas, Abdelkader;Zidour, Mohamed;Tounsi, Abdelouahed
    • Smart Structures and Systems
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    • v.30 no.2
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    • pp.135-143
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    • 2022
  • The object of this paper is to investigate the free vibration behavior under the effect of carbon nanotube distribution in functionally graded carbon nanotube-reinforced composite (FG-CNTRC) by using higher-order shear deformation theories. In this work, we present a novel distribution method for carbon nanotubes in the polymer matrix by using a new exponential power law distribution of carbon nanotube volume fraction. It is assumed that the SWCNTs are aligned along the beam axial direction and the distribution of the SWCNTs may vary through the thickness of the beam with different patterns of reinforcement. The rule of mixtures is used in order to obtain material properties of the CNTRC beams. Hamilton's principle is used in deriving the equations of motion. The validity of the free Vibration results is examined by comparing them with those of the known data in the literature. The results that obtained indicate that the carbon nanotube volume fraction distribution play a very important role on the free vibrations characteristics of the CNTRC beam.

Piezoelectric PZT/Polymer Composite with 3-3 Connectivity (3-3 결합으로 이루어진 PZT/고분자 압전복합체)

  • 윤기현;염상덕
    • Journal of the Korean Ceramic Society
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    • v.25 no.2
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    • pp.125-130
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    • 1988
  • The characteristics of the PZT/PMM and PZT/Butadiene composites with 3 dimensional network structure have been investigated as a function of the PZT volume fraction. The dielectric constants of the PZT composites increased linearly as the PZT volume fraction increased. However, they are not significantly affected by the polymer compliance. The piezoelectric d33 coefficients of the PZT/Butadiene are largest than the PZT/PMM because of the high elastic compliance which promotes stress transfer. The values of the mechanical quality factor adn frequency factor of the PZT/PMM composite are slightly larger, while the planar coupling factor is smaller, than the PZT/Butadiene composite. These results are due to strong interaction and mechanical coupling between PZT and PMM.

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Study on the Free Volume in Polymer by Positron Annihilation Lifetime Spectroscopy (PALS) (양전자소멸 수명시간 측정을 통한 폴리머소재의 자유부피에 관한 연구)

  • Kim, Yongmin;Shin, Jungki;Kwon, Junhyun
    • Journal of the Korean Society of Radiology
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    • v.6 no.6
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    • pp.489-493
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    • 2012
  • Positron Annihilation Lifetime Spectroscopy is a non-destructive technique to study voids and defects in solids by the measurement of gammas from electron-positron annihilation. In this study, we measured the lifetime of CR, EPDM, NBR, all of which are widely used polymer in various fields. A conventional fast-fast coincidence system in KAERI(Korea Atomic Energy Research Institute) has been used to measure the lifetime spectra, Three lifetime components were analyzed from each lifetime spectra. According to Tao-Eldrup model equation, the size and fraction of free-volume were calculated. Mean radius and free volume fraction of CR, EPDM NBR are $0.1217nm^3$(1.9103%), $0.14780nm^3$(5.3147%), $0.1216nm^3$(2.6381%), respectively. Through these measurements, we identified the feasibility of the PAL system for polymer analysis.

An Experimental study on Reduction Effect to Explosive spalling of high performance concrete by Fiber Type and Volume Fraction of Fiber (섬유종류 및 혼입량에 따른 고성능콘크트의 폭열저감에 관한 실험적 연구)

  • Na, Chul-Sung;Shin, Kwan-Soo;Kim, Young-Sun;Kwon, Young-Jin;Kim, Gyu-Yong;Kim, Moo-Han
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2005.11a
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    • pp.81-85
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    • 2005
  • Recently, fire resistance of high performance concrete for explosive spalling was issued as high performance concrete was vulnerable to the explosive spalling in initial fire. Therefore, in this study, an experiment about reduction effect to explosive spalling of high performance concrete is performed by adding several polymer fiber with various volume fraction, an then final fiber and volume fraction of that which reduce the explosive spalling of high performance concrete is presented. As the result of this study, the most fitted fiber volume fraction of reducing effect for explosive spalling at high performance concrete is under the 0.1%, as consider the flowability and efficiency.

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Fabrication of Polymeric Optical Fiber Array (정밀 고분자 광섬유 어레이 제작 연구)

  • Cho, Sang-Uk;Jeong, Myung-Yung;Kim, Chang-Seok;Ahn, Seung-Ho
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.5
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    • pp.82-88
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    • 2007
  • This work is to fabricate a precise optical fiber array using polymer composite for optical interconnection. Optical fiber array has to satisfy low optical loss requirement less than 0.4 dB according to temperature change. For this purpose, design criteria for an optical fiber array was derived. The coefficient of thermal expansion of silica particulate epoxy composites was affected by volume fraction of silica particles. And also, elastic modulus of silica particulate epoxy composites was affected by volume fraction of silica particles. To obtain the coefficients of thermal expansion below $10{\times}10E-6/^{\circ}C$ and elastic modulus more than 20 GPa , we chose the volume fraction more than 76%. Using silica particulate epoxy composites with the volume fraction 76%, 8-channel optical fiber array with dimensional tolerances below $1\;{\mu}m$ was manufactured by transfer molding technique using dies with the uniquely-designed core pin and precisely-machined zirconia ceramic V block. These optical fiber arrays showed optical loss variations within 0.4 dB under thermal cycling test and high temperature test.

Structure and Properties of Polymer Infiltrated Alumina Thick Film via Inkjet Printing Process

  • Jang, Hun-Woo;Koo, Eun-Hae;Hwang, Hae-Jin;Kim, Jong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.207-207
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    • 2008
  • Modern industry has focused on processing that produce low- loss dielectric substrates used complex micron-sized devices using tick film technologies such as tape casting and slip casting. However, these processes have inherent disadvantages fabricating high density interconnect with embedded passives for high speed communication electronic devices. Here, we have successfully fabricated porous alumina dielectric layer infiltrated with polymer solution by using inkjet printing process. Alumina suspensions were formulated as dielectric ink that were optimized to use in inkjet process. The layer was confirmed by field emission scanning electron microscope (FE-SEM) for measuring microstructure and volume fraction. In addition, the reaction kinetics and electrical properties were characterized by FT-IR and the impedance analyzer. The volume fraction of alumina in porous dielectric alumina layer is around 70% much higher than that in the conventional process. Furthermore, after infiltration on the dielectric layer using polymer resins such as cyanate ester. Excellent Q factors of the dielectric is about 200 when confirmed by impedance analyzer without any high temperature process.

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Synthesis of nano-crystalline Si films on polymer and glass by ICP-assisted RF magnetron sputtering

  • Shin, Kyung-S.;Choi, Yoon-S.;Choi, In-S.;Han, Jeon-G.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.203-203
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    • 2010
  • Nano-crystalline Si thin films were deposited on polymer and glass by inductively coupled plasma (ICP) - assisted RF magnetron sputtering at low temperature in an argon and hydrogen atmosphere. Internal ICP coil was installed to increase hydrogen atoms dissociated by the induced magnetic field near the inlet of the working gases. The microstructure of deposited films was investigated with XRD, Raman spectroscopy and TEM. The crystalline volume fraction of the deposited films on polymer was about 70% at magnetron RF power of 600W and ICP RF power of 500W. Crystalline volume fraction was decreased slightly with increasing magnetron RF power due to thermal damage by ion bombardment. The diffraction peak consists of two peaks at $28.18^{\circ}$ and $47.10^{\circ}\;2{\theta}$ at magnetron RF power of 600W and ICP RF power of 500W, which correspond to the (111), (220) planes of crystalline Si, respectively. As magnetron power increase, (220) peak disappeared and a dominant diffraction plane was (111). In case of deposited films on glass, the diffraction peak consists of three peaks, which correspond to the (111), (220) and (311). As the substrate temperature increase, dominant diffraction plane was (220) and the thickness of incubation (amorphous) layer was decreased.

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Engineering Properties of Permeable Polymer Concrete for Pavement Using Polypropylene Fiber (폴리프로필렌섬유를 혼입한 포장용 투수성 폴리머 콘크리트의 공학적 성질)

  • Sung, Chan-Yong;Lee, Seung-Hoon
    • Korean Journal of Agricultural Science
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    • v.37 no.2
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    • pp.277-283
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    • 2010
  • Research on permeable pavement like asphalt and concrete pavement with porous structure has been increasing due to environmental and functional need such as reduction of run off and flood. This study was performed to evaluate void ratio, permeability coefficient, and compressive strength of permeable polymer concrete (PPC) using crushed and recycled coarse aggregate that is obtained from waste concrete. Also, 6 mm length of polypropylene fiber was used to increase toughness and interlocking between aggregate and aggregate surrounded by binder. Binder and filler used were unsaturated polyester resin and CaCO3, respectively. The mix proportions were determined to satisfy the requirement for the workability and slump according to aggregate sizes 5~10 mm. In the test results, regardless of kinds of aggregates and fiber contents, the void ratio, permeability coefficient and compressive strength of all types of PPC showed the higher than the criterion of porous concrete that is used in permeable pavement in Korea. Also, strengths of PPC with increase polypropylene fiber volume fraction showed slightly increased tendency due to increase binder with increase of fiber volume fraction. Accordingly, polypropylene fiber and recycled coarse aggregate can be used for permeable pavement.