• Bulletin of the Korean Chemical Society
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• 제16권5호
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• pp.398-400
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• 1995

Selective oxidation of cyclohexane in acetone solution has been studied using iron catalysts with hydrogen peroxide in-situ produced by palladium catalyst. Iron tetraphenylporphyrin chloride shows the highest activity among the tested chlorides and porphyrin complexes of some metals of the first transiton series. Iron chloride and iron tetraphenylporphyrin chloride were supported on four kinds of 4-vinylpyridine copolymer with styrene or divinyl-benzene. Nitrogen 1s photoelectron spectra give the evidence that pyridyl nitrogens of the 4-vinyl pyridine copolymer act as ligands to bind iron species. The copolymer with styrene is the most efficient support for the binding because its solubility in catalyst preparation solvent (methylene chloride) gives the pyridyl group advantage to contact with the iron catalysts. However, better catalytic activity per iron atom could be obtained with a rigid crosslinked polymer due to active site isolation.

• Steel and Composite Structures
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• 제32권1호
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• pp.21-35
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• 2019

This study investigates the flexural behavior of steel-concrete composite beams strengthened with prestressed carbon fiber-reinforced polymer (CFRP) plates. An innovative mechanical anchorage system was developed. The components of the system can be easily assembled on site before applying a prestressing force, and removed from the structures after strengthening is completed. A total of seven steel-concrete composite specimens including four simply supported beams strengthened at the positive moment region and three continuous beams strengthened at the negative moment region were tested statically until failure. Experimental results showed that the use of prestressed CFRP plates enhanced the flexural capacity and reduced the mid-span deflection of the beams. Furthermore, by prestressing the CFRP laminates, the material was used more efficiently, and the crack resistance of the continuous composite specimens at the central support was significantly improved after strengthening. Overall, the anchorage system proved to be practical and feasible for the strengthening of steel-concrete composite beams. The theoretical analysis of ultimate bearing capacity is reported, and good agreement between analytical values and experimental results is achieved.

• 공업화학
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• 제34권2호
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• pp.99-105
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• 2023

Recently, 2D materials greatly impact in the various applications especially in the energy conversion and storage devices. Among the 2D materials, nowadays researchers are showing their propensity towards the MXenes due to their potential structural and physical properties as well as their use in various applications. Recently, MXenes have been used as filler in polymer electrolytes membranes and as catalytic support to increase the performance of fuel cells (FCs). But this review covers only recent progress and application of MXenes in proton and anion exchange membranes for FCs. Also, this review will provide a significant guidance and broad overview for future research in MXenes based polymer electrolyte membrane for FCs.

• 한국정밀공학회지
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• 제13권4호
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• pp.163-173
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• 1996

Stereolithography is a process used to rapidly produce polymer components directly form a computer representation of the part. There are several considerations to be made for the efficient use of the process. Especially, the build-up orientation of part critically affects the part accuracy, total build time and the volume of support structures. The purpose of tis study is to determine the optimal build-up part orientation for the SLA process with improving part accuracy, and minimizing total build time and the volume of support structures. The forst factor is related to the area of surfaces whioch have staircase protrusions after solidification, the second factor is related to the total number of layers, and the third factor is related to the area of the surfaces which need to be supported with support structures. An algorithm is developed to calculate the staircase area, quantifying the process errors by the volume of materials supposed to be removed or added to the part, and the optimal layer thickness for the SLA system which can handle the variable layer thickness. So the optima l part orientation is determined based on the user's selections of primary criter- ion and the optimal thickness of layers is calculated at any part orientations.

• 한국전기전자재료학회논문지
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• 제36권2호
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• pp.164-169
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• 2023

Nano Pt particles were dispersed on carbon-based supports by a polyol process for a catalyst application in a polymer electrolyte fuel cell. We tried to optimize the effect of pH on the electrostatic forces between the support and the Pt colloids. We investigated the relationship among the surface charges on the carbon support, the solution pH, and the concentration of a glycolate, and the Pt particle size. The produced catalyst with nano Pt particles on the support was evaluated by the long-term cyclic voltammetry (CV) performance test and compared with the results from a commercial catalyst. Our experimental results reveal that the pH-control can modify the particle size distribution and the dispersion of the nano Pt particles. This resulted in a cost-effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells better than a commercial catalyst system.

• 대한토목학회논문집
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• 제37권2호
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• pp.507-512
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• 2017

유인 행성 탐사를 위해 인류는 행성에서 반영구적으로 거주할 수 있는 기술을 개발하고 있으며, 이에 거주에 기본적인 3대 요소인 의식주(衣食住)는 건설 분야의 필수적인 기술의 뒷받침이 요구된다. 국제적으로 인프라 구축 기술을 개발하기 위해 현지 시멘트화, 황, 알루미늄 등의 다양한 재료와 방법으로 시도되고 있다. 본 연구에서는 폴리머를 이용한 건설 인프라 재료 기술을 개발하기 위해 유인 탐사에 요구되는 조건에 부합하는 폴리머 콘크리트 시공성 검증 기술을 제안하고자 한다. 하부에서 가열하는 방식으로 제작된 중량비 10%의 폴리머를 사용한 콘크리트 시험체는 가열 후 2시간이 지났을 때 안정화 되었으며, 상부 가열 방식에 비해 강도는 낮았지만 고착속도가 2배 빠른 것으로 나타났다. 이러한 결과는 향후 유인 탐사를 위한 달 시설물 의 건설에 적용할 수 있을 뿐만 아니라 먼지방지를 위한 도로나 제방과 같은 인프라 시설의 시공성 향상에도 활용 가능하다고 기대된다.

• 한국화재소방학회논문지
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• 제19권3호
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• pp.70-75
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• 2005

고분자물질의 연소열은 고분자를 취급하는 공정에서 잠재적인 화재 위험성을 예측하기 위해 다른 화재 매개변수와 함께 사용될 수 있는 중요한 화재 특성치이다. 본 연구의 목적은 건축내장재 등으로 다양하게 사용되고 있는 고분자물질의 연소열을 예측하고자 한다. 다중회귀분석과 문헌자료를 사용하여 고분자물질의 연소열을 예측할 수 있는 식을 제시하였다. 산소소비열량과 완전연소 시 화학양론계수에 의한 연소열의 예측값과 문헌값의 평균절대퍼센트오차(A.A.p.E.)는 4.46, 평균절대편차(A.A.D.)는 1.09 그리고 상관계수는 0.972이다 제시한 예측식에 의한 계산값은 문헌값과 일치하였다. 따라서 본 연구에서 제시된 식이 다른 고분자 내장재의 연구에도 이용되기를 기대한다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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• pp.691-696
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• 2000

Shear strengthening method by steel plates and fiber reinforced polymer lamination has recently been favorably selected due to its efficiencies of duration and performance. Shear failure being brittle and difficult to predict, reinforced concrete structures must have sufficient capacity to absorb the energy for shear failure and to support temporarily the overload which may result due to the loss of shear capacity to the structure. These respects being considered, this research has carried out with the purpose of the experimental verification of the shear strengthening effect and ductility evaluation.

• Bulletin of the Korean Chemical Society
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• 제32권1호
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• pp.225-228
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• 2011

Poly(4-vinylpyridine)-supported $Br{\phi}nsted$ acids (P4VP-HX) were prepared by wet impregnation technique. These supported acids were found as efficient heterogeneous green catalysts for acetylation of alcohol, amine and phenol with different catalytic activities. The wide application of P4VP-HX as reusable solid acid catalyst in organic reactions is possible because of its simple preparation and handling, stability, simple work up procedure.

• Applied Microscopy
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• 제50권
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• pp.21.1-21.3
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• 2020

Sample preparation is significantly important to the high-resolution transmission electron microscopy (HRTEM) characterization of nanomaterials. However, many general organic solvents can dissolve the necessary organic polymer support layer in TEM grid, which causes it difficult to obtain high-quality samples of oil-soluble nanomaterials. In this study, a new sample preparation method for oil-soluble nanomaterials has been developed by using the sublimable material as a transition layer. Experiments also show that there is no damage to TEM grids and high-quality HRTEM images can be obtained via this method. This approach paves the way to applicable HRTEM sample preparation of oil-soluble nanomaterials.