• 제목/요약/키워드: Polymer science

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Effect of Nano-sized Silicas in HPDLC Based on PUA

  • Kim, Eun-Hee;Woo, Ju-Yeon;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1212-1215
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    • 2004
  • Diffraction modes of holographic grating were fabricated with polyurethane acrylates(PUA). Two types of silica (AEROSIL 200 and AEROSIL R812) were added to reduce the shrinkage of polymer matrix. It was founded that shrinkage of PUA composite film was reduced with the addition of silica. HPDLC based PUA/silica composite also showed high diffraction efficiency. The morphology of the resultant gratings was analyzed by using scanning electron microscopy(SEM) and Tg of the polymer matrix by dynamic mechanical thermal analysis(DMTA).

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Characterization of Specific Interactions in Organoclay Nanocomposites

  • Lim, Sang-Kyun;Lee, Eun-Hee;Chin, In-Joo
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.292-292
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    • 2006
  • A two-step process of the solution blending and the subsequent melt mixing in a Brabender mixer was used to prepare clay nanocomposites of SAN/PVC and of ABS, respectively. It was found that the new method was effective in obtaining well-dispersed nanocomposites for both cases. The glass transition behavior of the organoclay nanocomposites were analyzed by using theoretical equations. The interaction characteristics were evaluated by using the solubility parameters estimated from the group molar attraction constants.

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Fully Aliphatic Polyimides- Influence of adamantane and siloxane moieties

  • Ha Chang-Sik;Kim Il;Mathews Anu Stella
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.336-336
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    • 2006
  • The present work is focused on the synthesis of a series of fully aliphatic polyimides and the incorporation of adamantane moieties and siloxane groups to them and studies the deviation in the basic traits of the fully aliphatic polyimides. In this work, we wish to discuss how adamantyl group and siloxane moieties influence the basic properties of aliphatic polyimides (APIs), by synthesizing various fully aliphatic polyimides and polyimidesiloxanes (APISiO).

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Electro-optic Properties of Reflective HPDLC with Fluorinated Polymer Matrices

  • Woo, Ju-Yeon;Kim, Eun-Hee;Kim, Byung-Kyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.516-519
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    • 2003
  • We modified the molecular structure of urethane acrylate oligomer by varying raw materials. Also fluorination of the host polymer matrices has been found to influence the morphological and the electrooptical properties of the resulting HPDLC grating. The incorporation of fluorinated monomers in HPDLC formulation enhance the LC phase separation and improved elctro-optical properties.

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Characterization and Improvement of Dissolution Rate of Solid Dispersion of Celecoxib in PVP K30/Eudragit EPO (PVP K30/Eudragit EPO에 의한 셀레콕시브 고체분산체의 용출률 향상 및 특성)

  • Jeon, Dae Yeon;Jang, Ji Eun;Lee, Jeong Hwan;Yang, Jae Won;Park, Sang Mi;Lim, Dongkwon;Khang, Gilson
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.434-440
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    • 2014
  • We prepared nanoparticles containing insoluble celecoxib by the method of solid dispersions using a spray dryer to improve solubility of celecoxib. We used PVP K30 and Eudragit EPO as water-soluble carriers for the solid dispersion, and poloxamer 407 as a surfactant. Characterization of celecoxib solid dispersion was performed by scanning electron microscope (SEM), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). The results of SEM, DSC and XRD demonstrated that celecoxib is amorphous in solid dispersion. The dissolution rate measured in intestinal juice showed that the method of solid dispersion improved celecoxib solubility as compared with a conventional drug (Celebres$^{(R)}$). In conclusion, solid dispersion formulation prepared by a spray dryer would improve the solubility of celecoxib in oral administration.

Preparation and Characterization of Zaltoprofen-Loaded Polyoxalate Microspheres for Control Release (방출제어를 위한 잘토프로펜이 함유된 폴리옥살레이트 미립구의 제조와 특성)

  • Kim, Kyoung Hee;Lee, Cheon Jung;Jo, Sun A;Lee, Jung Hwan;Jang, Ji Eun;Lee, Dongwon;Kwon, Soon Yong;Chung, Jin Wha;Khang, Gilson
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.702-710
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    • 2013
  • Zaltoprofen loaded polyoxalate (POX) microspheres were prepared by an emulsion solvent-evaporation/extraction method like oil-in-water (O/W) for sustained release of zaltoprofen. The influence of several preparation parameters such as fabrication temperature, stirring speed, intensity of the sonication, initial drug ratio, molecular weight ($M_w$) of POX, concentration of POX and concentration of emulsifier has been investigated on the zaltoprofen release profiles. Physicochemical properties and morphology of zaltoprofen loaded POX microspheres were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), differential scanning calorimeter (DSC) and Fourier transform infrared (FTIR). Through the analyzed results, it was demonstrated that the characteristics of the microspheres greatly affected by the prepared condition. The releases behavior of zaltoprofen was investigated for 10 days in vitro. It was confirmed that the release behavior of zaltoprofen can be controlled by the manufacturing factor of solvent-evaporation/extraction method.

Synthesis and Characterization of Acrylic Polymer Containing Silk Protein

  • Zhongmin Chen;Kim, Mutsumi ura;Masahiro Suzuki;Yoshiyuki Kondo;Kenji Hanabusa;Hirofusa Shirai
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.87-87
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    • 2003
  • Three kinds of acrylic polymers containing silk protein were synthesized, which are (1) blending of silk fibroin (SF) fiber and polyacrylonitrile (PAN); (2) graft-copolymer of PAN onto SFs; (3) random-copolymer synthesized by copolymerization of acrylonitrile (AN) and silk fibroin peptide (SFP) with vinyl groups, and their solubility, thermal property, and moisture absorption was investigated, respectively. These polymers have difference solubility and attributable to their structure. Their excellent thermal stabilities and better moisture absorptions were indicated.

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Study on electro-optical characteristics of FFS mode with high $d{\Delta}n$ according to the electrode position (높은 위상지연값을 갖는 FFS mode에서 전극 위치에 따른 전기광학적 특성 연구)

  • Ha, Kyung-Su;Jo, Eun-Mi;Park, Ji-Woong;Kim, Seong-Su;Jung, Jun-Ho;Kim, Min-Su;Kim, Mi-Young;Lee, Myong-Hoon;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.310-311
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    • 2008
  • We have studied electro-optical characteristics of fringe-field switching (FFS) mode with high $d{\Delta}n$ according to the electrode position. In this device, the fringe-electric field drives the LCs to rotate so that the dielectric torque is electrode-positional dependent, which results in electrode-position dependency in the LC's rotating angle. We confirmed polarization microscope image and chromaticity diagram at the different electrode position with LC that have high $d{\Delta}n$. Since the FFS mode is influenced by horizontal and vertical electric field, the FFS mode modulates light using both phase retardation and polarization rotation effect, which had already been verified with previous studies. However, from another point of view, tight modulation of FFS mode has been demonstrated by performing experiment and calculated simulation at the high $d{\Delta}n$ LC cell.

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