• Title/Summary/Keyword: Polymer processing

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The advancing techniques and sputtering effects of oxide films fabricated by Stationary Plasma Thruster (SPT) with Ar and $O_2$ gases

  • Jung Cho;Yury Ermakov;Yoon, Ki-Hyun;Koh, Seok-Keun
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.216-216
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    • 1999
  • The usage of a stationary plasma thruster (SPT) ion source, invented previously for space application in Russia, in experiments with surface modifications and film deposition systems is reported here. Plasma in the SPT is formed and accelerated in electric discharge taking place in the crossed axial electric and radial magnetic fields. Brief description of the construction of specific model of SPT used in the experiments is presented. With gas flow rate 39ml/min, ion current distributions at several distances from the source are obtained. These was equal to 1~3 mA/$\textrm{cm}^2$ within an ion beam ejection angle of $\pm$20$^{\circ}$with discharge voltage 160V for Ar as a working gas. Such an extremely high ion current density allows us to obtain the Ti metal films with deposition rate of $\AA$/sec by sputtering of Ti target. It is shown a possibility of using of reactive gases in SPT (O2 and N2) along with high purity inert gases used for cathode to prevent the latter contamination. It is shown the SPT can be operated at the discharge and accelerating boltages up to 600V. The results of presented experiments show high promises of the SPT in sputtering and surface modification systems for deposition of oxide thin films on Si or polymer substrates for semiconductor devices, optical coatings and metal corrosion barrier layers. Also, we have been tried to establish in application of the modeling expertise gained in electric and ionic propulsion to permit numerical simulation of additional processing systems. In this mechanism, it will be compared with conventional DC sputtering for film microstructure, chemical composition and crystallographic considerations.

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Processing and Mode 1 Fracture Toughness of Carbon Fiber Composites Reinforced With Carbon Nanotubes (탄소나노튜브로 보강된 탄소섬유복합재의 제조 공정과 모드 1 파괴인성)

  • Kim, Han-Sang
    • Composites Research
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    • v.24 no.5
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    • pp.39-43
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    • 2011
  • For the last twenty years, nanocomposites composed of polymer matrices reinforced with carbon nanotubes (CNTs) have been an active research area. Also, the polymeric nanocomposites reinforced with CNTs are being investigated to be used matrices of carbon fiber composites. Carbon tiber composites have achieved advanced properties in the direction of carbon fibers due to enhanced carbon fiber properties. However, the matrix dominated properties need to be improved further to fully utilize the advanced carbon fiber properties. In particular, delamination is a typical and critical reason for fracture of carbon fiber composites. Mode I fracture toughness test which is also often called double cantilever beam (DCB) test shows the resistance to delamination of carbon fiber composites and this test is performed on carbon fiber composite samples incorporated with carbon nanotubes functionalized with various functional groups. The specimens with mat-like CNT layers showed the increased fracture toughness by 10.6%.

Preparation and Performance of Synthetic Organo-beidellite (유기 바이델라이트의 합성 및 거동 연구)

  • Ryu, Gyoung-Won;Jang, Young-Nam;Cho, Sung-Jun;Choi, Sang-Hoon
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.2 s.48
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    • pp.123-128
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    • 2006
  • Beidellite, a member of the dioctahedral smectite group, was synthesized hydrothermally from dickite. Organophilic [DEACOOH]-beidellite intercalation complex was formed by the cation exchange reaction between synthetic Na-beidellite and [DEACOOH]Br. The products dried in high vacuum were treated with various organic solvent such as methanol, ethanol, acetone, ether, acetonitrile and caprolactam in order to determine the swelling behaviour of the prepared complexes. After drying under high vacuum, basal spacing of [DEACOOH]-beidellite shows 15.1 ${\AA}$, and it changed to 19.4, 29.9, 15.9, 16.8, 14.8, 26.5 and 14.8 ${\AA}$ under distilled water, methanol, ethanol, acetone, ether, acetonitrile and caporlactam, respectively. Especially, the characteristics of the intercalation complexes and their swelling behavior of the synthetic beidellite and natural montmorillonite were compared.

Study of Single Screw Extrusion Conditions on the Formability of TPE-800L Tube (TPE-800L 튜브 성형성에 대한 단축 압출기의 제조공정에 관한 연구)

  • Yoon, Juil;Kang, Sang-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.77-83
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    • 2018
  • Thermoplastic elastomers are being used increasingly throughout industry owing to their superior properties, such as superior elasticity, formability, and recoverability. Currently, research related to thermoplastic elastomers is focused on the development of composite elastomers by combining with various materials and the development of equipment. On the other hand, in the field of small and medium sized companies, it is necessary to study not only the application of these new materials, but also the process conditions that enable the extrusion of thermoplastic elastomers in inexpensive uniaxial screwing equipment. If extrusion is performed in a single screw extruder, it is important to maintain a uniform thickness through process control of the extruder. This study examined the effects of the processing temperature, which is an extrusion process variable, on the formability of a tube in the thermoplastic elastomer TPE-800L uniaxial extrusion process. The nozzle zone temperature is the most important factor in the extrusion of thermoplastic elastomer TPE-800L; the most excellent moldability was confirmed at $165-170^{\circ}C$.

The Redundancy Reduction Using Fuzzy C-means Clustering and Cosine Similarity on a Very Large Gas Sensor Array for Mimicking Biological Olfaction (생물학적 후각 시스템을 모방한 대규모 가스 센서 어레이에서 코사인 유사도와 퍼지 클러스터링을 이용한 중복도 제거 방법)

  • Kim, Jeong-Do;Kim, Jung-Ju;Park, Sung-Dae;Byun, Hyung-Gi;Persaud, K.C.;Lim, Seung-Ju
    • Journal of Sensor Science and Technology
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    • v.21 no.1
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    • pp.59-67
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    • 2012
  • It was reported that the latest sensor technology allow an 65536 conductive polymer sensor array to be made with broad but overlapping selectivity to different families of chemicals emulating the characteristics found in biological olfaction. However, the supernumerary redundancy always accompanies great error and risk as well as an inordinate amount of computation time and local minima in signal processing, e.g. neural networks. In this paper, we propose a new method to reduce the number of sensor for analysis by reducing redundancy between sensors and by removing unstable sensors using the cosine similarity method and to decide on representative sensor using FCM(Fuzzy C-Means) algorithm. The representative sensors can be just used in analyzing. And, we introduce DWT(Discrete Wavelet Transform) for data compression in the time domain as preprocessing. Throughout experimental trials, we have done a comparative analysis between gas sensor data with and without reduced redundancy. The possibility and superiority of the proposed methods are confirmed through experiments.

Physical Property Evaluation of Chitosan Mordanted Green Tea Dyed Cellulose - Focusing on the physical property changes upon the repetition of treatment -

  • Jung, Hye-Kyung;Kim, Sin-Hee
    • Journal of Fashion Business
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    • v.12 no.6
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    • pp.61-72
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    • 2008
  • The UV-protection effect of green-tea dyed fabrics was reported in our previous studies. The chitosan was used as a natural mordant of cellulose fiber for green tea extract because chitosan is a natural bio-polymer. The increase in the UV protection property of summer cellulose fabrics, cotton and linen, upon the repetition of chitosan mordanting and green tea dyeing was observed. However, the physical property change would be followed by this repeated wet processing of the cellulose fabric. Therefore, the physical changes of the chitosan mordanted and green tea dyed cotton and linen fabrics were evaluated by KES-FB system. Tensile, shear, bending, compression, and surface characteristics were tested upon the repetition of mordanting and dyeing treatments. Linearity of tensile force increased in the treated cotton and linen samples. Tensile energy and resilience decreased in all treated fabrics. Shear stiffness increased in the treated cotton and linen in general. Shear hysteresis was increased in all cotton samples and some linen samples. In cotton, the bending rigidity in all treated cottons increased except C3G3. As the chitosan mordanting numbers increased, the bending rigidity tended to decrease. In linen, the bending rigidity and hysteresis increased in all treated samples. Compressional energy and resilience increased as the number of chitosan mordanting increased both in cotton and linen. This could be the result of the increase in thickness upon chitosan mordanting. Surface coefficient of friction increased in the treated cotton and linen in general. Surface roughness tended to increase in cotton.

Glycosyl-linkages of Acid Soluble Polysaccharide from Green Laver, Enteromopha prolifera (가시파래 산성 수용성 다당의 구성당 결합 특성)

  • Koo Jae Geun;Choi Yong Seok;Ha Jin Hwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.5
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    • pp.524-528
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    • 2002
  • Green layer, Enteromorpha prolifera, is regarded as one of important materials for food processing in Korea. The acidic water-soluble polysaccharide (CPC-PS) isolated from the alga with hot water and cetylpyridium chloride was mainly constituted of rhamnose, xylose, uronic acid and sulfate. To determine the glycosyl-linkages and positions of sulfate by methylation, the CPC-PS was reduced and/or sulfates. A marked increase of glucose content in the reduced polysaccharide indicated that glucuronic acid was a major sugar in the polymer and sulfation was deduced to occur on O-3 of rhamnose and O-2 of xylose. According to the methylation analysis of the native, reduced, desulfated and reduced-desulfated polymers, CPC-PS mainly composed of 1,4- and 1,2,3-linked rhamnose 3-sulfate, 1,4-linked xylose 2-sulfate, 1,4-linked xylose and 1,4-linked glucuronic acid. Minor 1,4-linked rhamnose and 1,4,6-linked galactose residues were also detected.

Effects of Isothermal Stabilization Process and Ultrasonic Cleaning on the Characteristics of Rayon Fabrics (레이온직물의 특성에 미치는 등온 안정화공정 및 초음파세척의 영향)

  • Cho, Chaewook;Cho, Donghwan;Park, Jong Kyoo;Lee, Jae Yeol
    • Journal of Adhesion and Interface
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    • v.14 no.1
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    • pp.21-27
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    • 2013
  • Cellulose-based rayon fibers or fabrics can be thermally decomposed very fast within a narrow temperature window during stabilization process. Therefore the stabilization stage is critically important for producing rayon-based carbon fibers. Consequently, in the present study the effects of isothermal stabilization and ultrasonic cleaning on the weight loss, chemical composition, microstructure, and fabric texture of cellulose-based rayon fabrics were explored. The temperature of the isothermal stabilization process performed in the range of $200{\sim}240^{\circ}C$ influenced the processing time, carbon and oxygen contents, cellulose structural change, and fabric texture. The ultrasonic cleaning, which was conducted prior to the stabilization process, played a role in shortening the stabilization time, increasing the carbon contents, decreasing the oxygen contents, and changing the XRD pattern. Also, it was considered that the ultrasonic cleaning contributed to retarding the weight loss, to reducing the thermal shrinkage, and further to reducing the fast physical change of rayon fabrics.

Development of Stress Intensity Factor Equation for the Notched Ring Test (NRT) Specimen (Notched Ring Test 저속균열 시험편의 응력확대계수정식화)

  • Pyo, Sooho;Choi, Sunwoong
    • Korean Journal of Materials Research
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    • v.24 no.2
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    • pp.87-92
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    • 2014
  • The Notched Ring Test(NRT) has proven to be very useful in determining the slow crack growth behavior of polyethylene pressure pipes. In particular, the test is simple and an order of magnitude shorter in experimental times as compared to the currently used Notched Pipe Test(NPT), which makes this method attractive for use as the accelerated slow crack growth test. In addition, since the NRT specimen is taken directly from the pipe, having maintained the cross-section, processing induced artifacts that would affect the slow crack growth behavior are not altered. This makes the direct comparison to the slow crack growth specimen in pipe from more meaningful. In this study, for comparison with other available slow crack growth methods, including the NPT, the stress intensity factor equation for NRT specimen was developed and demonstrated of its accuracy within 3% of that obtained from the finite element analysis. The equation was derived using a flexure formula of curved beam bending along with numerically determined geometric factors. The accuracy of the equation was successfully tested on 63, 110, 140, 160, 250, and 400 mm nominal pipe diameters, with crack depth ranging from 15 % to 45 % of the pipe wall thickness, and for standard dimensional ratio(SDR) of 9, 11, and 13.6. Using this equation the slow crack results from 110SDR11 NRT specimen were compared to that from the NPT specimen, which demonstrated that the NRT specimen was equivalent to the NPT specimen in creating the slow crack, however in much shorter experimental times.

A Study on the Molding Characteristics of Injection Compression Molding Through Computer Simulation (컴퓨터 해석을 통한 사출압축성형의 성형특성에 관한 연구)

  • Chun, Y.H.;An, H.G.;Lyu, M.Y.
    • Elastomers and Composites
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    • v.47 no.4
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    • pp.341-346
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    • 2012
  • Injection molding is one of the widely used polymer processing operations. It is being used for not only conventional injection molding but gas injection molding, water injection molding, and injection compression molding. Injection compression molding involves injection and compression operation, and it gives uniform physical property and high dimensional quality of product. In this study, injection compression characteristics for various product shapes have been investigated by computer simulation. Product containing side wall showed not much effective in injection compression molding since wall thickness direction was perpendicular to the compression direction. Uniform and low shrinkage was observed in injection compression molding comparing conventional injection molding. Subsequently injection compression molding can be used for molding precise product. Optimal injection compression molding condition was obtained using design of experiment for plastic lens and the results were compared with conventional injection molding.