• Title/Summary/Keyword: Polymer networks

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Metal Grids Embedded Transparent Conductive Electrode with Flexibility and Its Applications

  • Jung, Sunghoon;Lee, Seunghun;Kim, Jong-Kuk;Kang, Jae-Wook;Kim, Do-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.314-314
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    • 2013
  • Recently, flexibility is one of the hottest issues in the field of electronic devices. For flexible displays or solar cells, a development of transparent conductive electrodes (TCEs) with flexibility, bendability and foldability is an essential element. Hundreds of nanometers indium-tin-oxide (ITO) films have been widely used and commercialized as a transparent electrode, but their brittleness make them difficulty to apply flexible electronics. Many researchers have been studying for flexible TCEs such as a few layers of graphene sheets, carbon nanotube networks, conductive polymer films and combinations among them. Although gained flexibility, their transmittance and resistivity have not reached those of commercialized ITO films. Metal grids electrode cannot act as TCEs only, but they can be used to lower the resistance of TCEs with few losses of transmittance. However, the possibility of device shortage will be rise at the devices with metal grids because a surface flatness of TCEs may be deteriorated when metal grids are introduced using conventional methods. In our research, we have developed hybrid TCEs, which combined tens of nanometers ITO film and metal grids which are embedded in flexible substrate. They show $13{\Omega}$/${\Box}f$ sheet resistance with 94% of transmittance. Moreover, the sheet resistance was maintained up to 1 mm of bending radius. Also, we have verified that flexible organic light emitting diodes and organic solar cells with the TCEs showed similar performances compared to commercial ITO (on glass substrate) devices.

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Additive Manufacturing for Sensor Integrated Components (센서 융합형 지능형 부품 제조를 위한 적층 제조 기술 연구)

  • Jung, Im Doo;Lee, Min Sik;Woo, Young Jin;Kim, Kyung Tae;Yu, Ji-Hun
    • Journal of Powder Materials
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    • v.27 no.2
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    • pp.111-118
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    • 2020
  • The convergence of artificial intelligence with smart factories or smart mechanical systems has been actively studied to maximize the efficiency and safety. Despite the high improvement of artificial neural networks, their application in the manufacturing industry has been difficult due to limitations in obtaining meaningful data from factories or mechanical systems. Accordingly, there have been active studies on manufacturing components with sensor integration allowing them to generate important data from themselves. Additive manufacturing enables the fabrication of a net shaped product with various materials including plastic, metal, or ceramic parts. With the principle of layer-by-layer adhesion of material, there has been active research to utilize this multi-step manufacturing process, such as changing the material at a certain step of adhesion or adding sensor components in the middle of the additive manufacturing process. Particularly for smart parts manufacturing, researchers have attempted to embed sensors or integrated circuit boards within a three-dimensional component during the additive manufacturing process. While most of the sensor embedding additive manufacturing was based on polymer material, there have also been studies on sensor integration within metal or ceramic materials. This study reviews the additive manufacturing technology for sensor integration into plastic, ceramic, and metal materials.

Functional Integration of Serial Dilution and Capillary Electrophoresis on a PDMS Microchip

  • Chang, Jun-Keun;Heo, Yun-Seok;Hyunwoo Bang;Keunchang Cho;Seok Chung;Chanil Chung;Han, Dong-Chul
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.4
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    • pp.233-239
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    • 2003
  • For the quantitative analysis of an unknown sample a calibration curve should be obtained, as analytical instruments give relative, rather than absolute measurements. Therefore, researchers should make standard samples with various known concentrations, measure each standard and the unknown sample, and then determine the concentration of the unknown by comparing the measured value to those of the standards. These procedures are tedious and time-consuming. Therefore, we developed a polymer based microfluidic device from polydimethylsiloxane, which integrates serial dilution and capillary electrophoresis functions in a single device. The integrated microchip can provide a one-step analytical tool, and thus replace the complex experimental procedures. Two plastic syringes, one containing a buffer solution and the other a standard solution, were connected to two inlet holes on a microchip, and pushed by a hydrodynamic force. The standard sample is serially diluted to various concentrations through the microfluidic networks. The diluted samples are sequentially introduced through microchannels by electro-osmotic force, and their laser-induced fluorescence signals measured by capillary electrophoresis. We demonstrate the integrated microchip performance by measuring the fluorescence signals of fluorescein at various concentrations. The calibration curve obtained from the electropherograms showed the expected linearity.

The Redundancy Reduction Using Fuzzy C-means Clustering and Cosine Similarity on a Very Large Gas Sensor Array for Mimicking Biological Olfaction (생물학적 후각 시스템을 모방한 대규모 가스 센서 어레이에서 코사인 유사도와 퍼지 클러스터링을 이용한 중복도 제거 방법)

  • Kim, Jeong-Do;Kim, Jung-Ju;Park, Sung-Dae;Byun, Hyung-Gi;Persaud, K.C.;Lim, Seung-Ju
    • Journal of Sensor Science and Technology
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    • v.21 no.1
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    • pp.59-67
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    • 2012
  • It was reported that the latest sensor technology allow an 65536 conductive polymer sensor array to be made with broad but overlapping selectivity to different families of chemicals emulating the characteristics found in biological olfaction. However, the supernumerary redundancy always accompanies great error and risk as well as an inordinate amount of computation time and local minima in signal processing, e.g. neural networks. In this paper, we propose a new method to reduce the number of sensor for analysis by reducing redundancy between sensors and by removing unstable sensors using the cosine similarity method and to decide on representative sensor using FCM(Fuzzy C-Means) algorithm. The representative sensors can be just used in analyzing. And, we introduce DWT(Discrete Wavelet Transform) for data compression in the time domain as preprocessing. Throughout experimental trials, we have done a comparative analysis between gas sensor data with and without reduced redundancy. The possibility and superiority of the proposed methods are confirmed through experiments.

Increase in Discharge Capacity of Li Battery Assembled with Electrochemically Prepared V2O5/polypyrrole-composite-film Cathode

  • Kim, You-Na;Kim, Joo-Seong;Thieu, Minh-Triet;Dinh, Hung-Cuong;Yeo, In-Hyeong;Cho, Won-Il;Mho, Sun-Il
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3109-3114
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    • 2010
  • Flexible composite films of $V_2O_5$ and conductive polypyrrole ($V_2O_5$/PPy) were grown by facile electrochemical polymerization, wherein an anodization potential was applied to the substrate electrode in an electrolyte solution containing pyrrole monomer and dispersed $V_2O_5$ particles. The coating of polypyrrole (PPy) on the surface of $V_2O_5$ particles was induced by the oxidative catalytic action of $V_2O_5$ during the electrochemical polymerization of pyrrole. PPy in the composite film connects the isolated $V_2O_5$ particles. This results in the formation of conductive networks in the composite film cathode, thereby enhancing the Li+ ion diffusion to the surface of the isolated $V_2O_5$ particles and thus increasing the accessibility of the $Li^+$ ions. The specific capacity tests of the Li rechargeable batteries revealed that the discharge capacity of this composite film cathode was higher, i.e., $497\;mAhg^{-1}$, than that of $V_2O_5$/PPy powder or pristine $V_2O_5$.

Development of Binder Materials for Si-based Anode in Lithium-ion Batteries (리튬이온전지 실리콘계 음극 바인더 소재 개발)

  • Jihee, Yoon;Jung-Keun, Yoo
    • Composites Research
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    • v.35 no.6
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    • pp.365-370
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    • 2022
  • According to the rapid growth of electric vehicle (EVs) and E-mobility market, Li-ion batteries are one of the most progressive technologies. The demand of LIBs with high energy capacity, rate performance and fast charging is continuously increasing, hence high-performance LIBs should be developed. Si is considered as the most promising anode material to improve energy density because of its high theoretical capacity. However, Si suffers large volume chances during the charging and discharge process, leading to the fast degradation of cycle performance. Therefore, polymeric binders play a key role in electrochemical performance of Si anode by efficiently enduring the Si expansion and maintaining the binding networks in electrode. In this review, we explain the role of polymeric binders in electrode and introduce the anode binders with enhanced mechanical and chemical properties which can improve electrochemical performances of Si-based anode.

Data-driven prediction of compressive strength of FRP-confined concrete members: An application of machine learning models

  • Berradia, Mohammed;Azab, Marc;Ahmad, Zeeshan;Accouche, Oussama;Raza, Ali;Alashker, Yasser
    • Structural Engineering and Mechanics
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    • v.83 no.4
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    • pp.515-535
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    • 2022
  • The strength models for fiber-reinforced polymer (FRP)-confined normal strength concrete (NC) cylinders available in the literature have been suggested based on small databases using limited variables of such structural members portraying less accuracy. The artificial neural network (ANN) is an advanced technique for precisely predicting the response of composite structures by considering a large number of parameters. The main objective of the present investigation is to develop an ANN model for the axial strength of FRP-confined NC cylinders using various parameters to give the highest accuracy of the predictions. To secure this aim, a large experimental database of 313 FRP-confined NC cylinders has been constructed from previous research investigations. An evaluation of 33 different empirical strength models has been performed using various statistical parameters (root mean squared error RMSE, mean absolute error MAE, and coefficient of determination R2) over the developed database. Then, a new ANN model using the Group Method of Data Handling (GMDH) has been proposed based on the experimental database that portrayed the highest performance as compared with the previous models with R2=0.92, RMSE=0.27, and MAE=0.33. Therefore, the suggested ANN model can accurately capture the axial strength of FRP-confined NC cylinders that can be used for the further analysis and design of such members in the construction industry.

Evaluation of the Bending Moment of FRP Reinforced Concrete Using Artificial Neural Network (인공신경망을 이용한 FRP 보강 콘크리트 보의 휨모멘트 평가)

  • Park, Do Kyong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.5
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    • pp.179-186
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    • 2006
  • In this study, Multi-Layer Perceptron(MLP) among models of Artificial Neural Network(ANN) is used for the development of a model that evaluates the bending capacities of reinforced concrete beams strengthened by FRP Rebar. And the data of the existing researches are used for materials of ANN model. As the independent variables of input layer, main components of bending capacities, width, effective depth, compressive strength, reinforcing ratio of FRP, balanced steel ratio of FRP are used. And the moment performance measured in the experiment is used as the dependent variable of output layer. The developed model of ANN could be applied by GFRP, CFRP and AFRP Rebar and the model is verified by using the documents of other previous researchers. As the result of the ANN model presumption, comparatively precise presumption values are achieved to presume its bending capacities at the model of ANN(0.05), while observing remarkable errors in the model of ANN(0.1). From the verification of the ANN model, it is identified that the presumption values comparatively correspond to the given data ones of the experiment. In addition, from the Sensitivity Analysis of evaluation variables of bending performance, effective depth has the highest influence, followed by steel ratio of FRP, balanced steel ratio, compressive strength and width in order.

The physical properties of the cosmetic hydrogels affected by adding various celluloses (셀룰로오즈 첨가에 따른 미용용 하이드로겔의 물성 연구)

  • Byeon, Hong-Ju;Choi, Won-Seok;Lee, Hyang-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.702-708
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    • 2018
  • Hydrogels are natural polymer networks that can contain huge quantities of water and many cosmetical ingredients. Their hydrophilic functional groups creates a matrix, which allows high efficacy in delivering active ingredients into the skin. In industry, hydrating properties and strength of the hydrogels are of great interest in manufacturing hydrogel mask packs. We have used the cellulose in various forms such as powder, cotton fiber and cellulase treated cotton fiber to investigate the property changes of cellulose/hydrogel sheets. When 0.1% and 0.3% of cellulose powder were added to hydrogels, tensile strength of hydrogel sheets were decreased by 10% and 14% respectively. Vise versa, when 0.5 ~ 2 cm of cotton fibers were added, tensile strength of hydrogel sheets were significantly increased by about 20%. The hydrogels which contain cotton fibers also gave an excellent moisturizing effect. Especially cellolose/hydrogels containing cellulase-treated cotton fibers showed the best effect on retaining moisture content increasing upto 380% in comparison with the one containing untreated cotton as well as excellent dispersibility.

Preparation of crosslinkable imide oligomers and Applications in Polyether Imides for Dual-ovenable Packaging (가교형 이미드 올리고머 제조 및 듀얼 오브너블 용기(Dual-Ovenable Packaging) 용 폴리에테르이미드에 대한 적용 연구)

  • Seo, Jongchul;Park, Su-Il;Choi, Seunghyuk;Jang, Wongbong;Han, Haksoo
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.45-52
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    • 2010
  • Two different imide oligomers(6FDA-ODA/APA and 6FDA-MDA/MA) having crosslinkable end groups were prepared by using a solution imidization method and their properties were investigated. Also, semi-interpenetrating polymer networks(semi-IPN) were prepared using the blends of imide oligomers with polyetherimide $Ultem^{(R)}$, which is used in dual-ovenable packaging materials. The characteristic properties of semi-IPN films were interpreted by using TGA, Thin Film Diffusion Analyzer, and WAXD. Molecular weights of imide oligomers were successfully controlled utilizing 2-aminophenylacetylene(APA) and maleic anhydride(MA) as an endcapping agent. Exotherm reactions by crosslinking appeared and the amount of exthotherm heat was linearly increased as the content of imide oligomers was increased. For semi-IPNs of $Ultem^{(R)}$ and imide oligomers, 5% and 10% weight loss temperatures increased as the contents of imide oligomers were increased. Diffusion coefficient and water uptake of semi-IPNs decreased as the content of imide oligomers was increased, which might be resulted from hydrophobic fluorine group and high packing density. It was concluded that relatively low thermal stability and hydrolytic stability of polyetherimide $Ultem^{(R)}$ were improved by incorporating new developed imide oligomers.