• Title/Summary/Keyword: Polymer curing

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Synthesis and Photopolymerization of Vinyl Ether and Epoxy-Functionalized Silicones

  • Pyun, Sang-Yong;Kim, Whan-Gi
    • Macromolecular Research
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    • v.11 no.3
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    • pp.202-205
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    • 2003
  • The reactive precursors, vinyl ethers, and epoxy-silicones, were synthesized. The vinyl ether monomers were prepared from primary alcohol and ethyl vinyl ether with mercury (II) acetate. The epoxy-functionalized silicones have been achieved by the controlled, rhodium-catalyzed, chemoselective hydrosilation of vinyl ether with siloxanes or silane. It was shown that the hydrosilation proceeds exclusively at the vinyl ether group of alkenyl vinyl ether without participation at the alkenyl group. The photoinduced cationic polymerization of these monomers was studied and found to be all highly reactive.

Rubber Toughened Epoxy

  • Ratna, D.;Banthia, Ajit K.
    • Macromolecular Research
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    • v.12 no.1
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    • pp.11-21
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    • 2004
  • Toughening of epoxy resins for improvement of crack resistance has been the subject of intense research interest during the last two decades. Epoxy resins are successfully toughened by blending with a suitable liquid rubber, which initially remains miscible with epoxy and undergoes a phase separation in the course of curing that leads to the formation of a two-phase microstructure, or by directly blending preformed rubbery particle. Unlike the situation for thermoplastics, physical blending is not successful for toughening epoxy resins. Recent advances in the development of various functionalized liquid rubber-based toughening agents and core-shell particles are discussed critically in this review.

Effect of the Binder Content on the Recycling of Scrap Waste Tires (폐타이어 재활용에 있어서 Binder양이 미치는 영향)

  • Kim, Jin-Kuk;Cho, Ha-Na;Lee, Soo-Koo
    • Elastomers and Composites
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    • v.29 no.5
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    • pp.431-435
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    • 1994
  • For recycling of the waste tires, polyurethane binder mixed with the scrapped rubber powders which obtained from tread part of waste tire. This study covered the effect of the binder contents on the mechanical properties of the blend. We also studied the change of the properties after aging on properties compared with those of before aging. The curing reaction of the binder was also investigated in this study. We obtained conclusions the suitable binder content was 15phr in this system.

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The effects of polymers and fly ash on unconfined compressive strength and freeze-thaw behavior of loose saturated sand

  • Arasan, Seracettin;Nasirpur, Omid
    • Geomechanics and Engineering
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    • v.8 no.3
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    • pp.361-375
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    • 2015
  • Constructions over soft and loose soils are one of the most frequent problems in many parts of the world. Cement and cement-lime mixture have been widely used for decades to improve the strength of these soils with the deep soil mixing method. In this study, to investigate the freeze-thaw effect of sand improved by polymers (i.e., styrene-acrylic-copolymer-SACP, polyvinyl acetate-PVAc and xanthan gum) and fly ash, unconfined compression tests were performed on specimens which were exposed to freeze-thaw cycles and on specimens which were not exposed to freeze-thaw cycles. The laboratory test results concluded that the unconfined compressive strength increased with the increase of polymer ratio and curing time, whereas, the changes on unconfined compressive strength with increase of freeze-thaw cycles were insignificant. The overall evaluation of results has revealed that polymers containing fly ash is a good promise and potential as a candidate for deep soil mixing application.

A Study on New Curing System Available for Solid Propellant (고체 추진제의 새로운 경화시스템에 관한 연구)

  • Min, Byoung-Sun;Park, Young-Chul;Yoo, Ji-Chang;Kim, Chang-Kee;Ryu, Baek-Neung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.420-421
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    • 2011
  • In this study, Instead of using urethane curative systems, which have long been used as solid propellants, a triazole curative system has been introduced into a new binder recipe in which azide groups in the polymer react with triple bonds of a dipolarophile curative.

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The study on ON-LINE and OFF-LINE systems of electronic image editing by time-code adressing method (전자 영상 편집에 있어서 time-code adressing 방식에 의한 ON-LINE, OFF-LINE system에 대한 연구)

  • BongJoKim
    • Journal of the Korean Graphic Arts Communication Society
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    • v.13 no.1
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    • pp.93-104
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    • 1995
  • Liquid crystal-polymer composite(LCPC) films promising new materials for both projection displays and vision product. LCPC films consist of a continous liquid crystal phase embedded in a three- dimensional network of polymer matrix. The liquid crystal in these LC phases can be elecrtrically switched giving rise to an opaque scattering off-stats and a transparent, non-scatting on- stats. In this work. a premixture is composed of LC, UV-curable monomer and photonitiator. LCPC films are formed by photopolymerization induced phase separation from this premixture. In conclusion, structure and electro-optical properties of LCPC films strongly depends on the selection of monomer, LC content and curing rate.

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Variable surface coatings composed of organic-inorganic hybrid polymers

  • Kessler, Daniel;Bahnmuller, Stefan;Theato, Patrick
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.315-315
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    • 2006
  • A variable surface coating with the potential to fulfill the requirements of industry will be presented. Via controlled radical polymerization methods from a functionalized Polymethylsilsesquioxane delivers an inorganic-organic block copolymer, which can be easily modified and tuned for different applications. Spin coated or dip coated on various substrates show promising results. By using different block copolymers the contact angle on a silicon wafer can be varied in a range of $90^{\circ}\;up\;to\;145^{\circ}$ After curing and complete condensation a perfect adhesion on glasses, plastics and metals is achieved.

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The Preparation and Adhesion Performances of Transparent Acrylic Pressure Sensitive Adhesives Containing Acrylamide Monomer for Optical Applications

  • Baek, Seung-Suk;Jang, Se-Jung;Hwang, Seok-Ho
    • Elastomers and Composites
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    • v.51 no.3
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    • pp.181-187
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    • 2016
  • Transparent acrylic pressure sensitive adhesives (PSAs) were successfully prepared by photopolymerization with 2-ethylhexyl acrylate (2-EHA) and 2-hydroxyethyl acrylate (2-HEA) as a default constituent and with isobornyl acrylate (IBOA) and N-(isobutoxymethyl)acrylamide (IBMA) as a variable constituent. The IBMA mole fraction effect in the acrylic PSAs was investigated on adhesion performances and the optical properties including 85/85 test as well as the characteristics (solid content, and molecular weight) of the PSA syrups were also investigated. Regardless increasing the IBMA mole fraction in the acrylic PSAs, the acrylic PSAs exhibited almost the same adhesion performance such as $180^{\circ}$ peel strength (~4.0 kg/25 mm) and probe tack (~0.27 kg). All the acrylic PSA samples also showed high transmittance (more than 91%), low haze (less than 1.0%) and low color-difference (less than 1.0) before and after 85/85 test.