• Title/Summary/Keyword: Polymer curing

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Experiment and Numerical Study on Thermal Characteristics of UV-NIL Process Considering the Cure Kinetics of Photo-polymer (레진의 경화 반응을 고려한 UV-NIL공정의 열특성에 관한 실험 및 수치해석 연구)

  • Kim, Woo-Song;Park, Gyeong-Seo;Nam, Jin-Hyun;Yim, Hong-Jae;Jang, Si-Yeol;Lee, Kee-Sung;Jeong, Jay;Lim, Si-Hyeong;Shin, Dong-Hoon
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1847-1850
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    • 2008
  • The process conditions during ultraviolet nanoimprint lithography (UV-NIL) process such as temperature, stamping pressure, UV irradiation, etc. are effective factors for successful imprinting of complex and fine patterns. In this study, the effects of aluminum mold on the thermal characteristics of UV-NIL process were investigated through imprinting experiments and numerical simulations. The temperature of polymer resin on mold was measured to study thermal characteristics during UV curing. From the experimental and numerical results, the importance of curing reaction control for UV-NIL process was discussed for deformation characteristics.

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Interfacial Properties and Curing Behavior of Carbon Fiber/Epoxy Composites using Micromechanical Techniques and Electrical Resistivity Measurement (Micromechanical 시험법과 전기적 고유저항 측정을 이용한 탄소섬유강화복합재료의 계면 물성과 경화거동에 관한 연구)

  • 이상일;박종만
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.11a
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    • pp.17-21
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    • 2000
  • Logarithmic electrical resistivity of the untreated or thin diameter carbon fiber composite increased suddenly to the infinity when the fiber fracture occurred by tensile electro-micromechanical test, whereas that of the ED or thick fiber composite increased relatively broadly up to the infinity. Electrical resistance of single-carbon fiber composite increased suddenly due to electrical disconnection by the fiber fracture in tensile electro-micromechanical test, whereas that of SFC increased stepwise due to the occurrence of the partial electrical contact with increasing the buckling or overlapping in compressive test. Electrical resistivity measurement can be very useful technique to evaluate interfacial properties and to monitor curing behavior of single-carbon fiber/epoxy composite under tensile/compressive loading.

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The experimental investigation for the curing condition deduce of the Polymer concrete manhole (폴리머 콘크리트 맨홀의 양생 조건 도출을 위한 실험적 고찰)

  • Kim, Dong-Hun;Han, Jin-Woo
    • 한국정보통신설비학회:학술대회논문집
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    • 2008.08a
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    • pp.545-548
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    • 2008
  • 불포화 폴리에스테르 수지를 결합재로 사용하여 제작되는 폴리머 콘크리트 맨홀은 조기 고강도 발현, 접착성. 수밀성, 내동결융해성, 내약품성, 내마모성, 전기절연성이 우수하여 프리캐스트로 제작되는 많은 통신용 맨홀에 적용되고 있다. 폴리머 콘크리트의 결합재로 사용되는 불포화 폴리에스테르 수지는 열경화성수지로써, 자체 발열에 의해 거푸집을 탈형할 정도의 초기 경화 반응이 나타나지만, 구조물로서 요구되는 소요 강도를 발휘하기 위해서는 적정 온도에 의한 추가 양생이 반드시 필요하다. 이에 본 논문에서는 폴리머 콘크리트의 휨 강도 시험용 공시체를 사용하여, 다양한 양생 온도 조건 및 양생기간에 따른 휨 강도를 측정하였으며, 이를 가열 촉진 양생에 의한 휨 강도와 비교하여 콘크리트가 소요 강도를 발휘하는데 요구되는 적정 온도와 기간을 도출하였다. 이를 통해 폴리머 큰크리트 맨홀의 품질 확보를 위한 생산 관리와 제품 검사를 체계적이고 효율적으로 수행할 수 있도록 하였다.

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Thermal, Curing, Elastic, and Mechanical Properties of Ethylene Propylene Diene Monomer/Polybutadiene/Carbon Black Composites

  • Tae-Hee Lee;Keon-Soo Jang
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.142-151
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    • 2023
  • In this study, we investigate the thermal and mechanical properties of composites comprising ethylene propylene diene monomer (EPDM) and polybutadiene (PB) obtained using carbon black (CB) as a reinforcing and compatibilizing filler. Owing to the significance of elastomeric materials in various industrial applications, blending of EPDM and PB has emerged as a strategic method to optimize the material properties for specific applications. This study offers insights into the blend composition, its microstructure, and the resulting macroscopic behaviors, focusing on the synergetic effects of composite materials. Furthermore, this study delves into curing and rheological behaviors, crosslink densities, and mechanical, thermal, and elastic properties of the elastomeric composites. Through systematic exploration, we believe that this study will be beneficial to material scientists and engineers working on developing advanced elastomeric composites.

Design of Hard Coating Resin for In-mold Decoration (IMD) Foil and Effects of EB Irradiation on IMD Foil Layers (In-mold Decoration(IMD) 포일용 경질 코팅 수지 설계 및 전자빔 조사가 IMD 포일 구성층에 미치는 영향)

  • Sim, Hyun-Seog;Kim, Geon-Seok;Shin, Ji-Hee;Lee, Kwang-Hee
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.268-274
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    • 2012
  • The silane coupling agent, 3-(trimethoxysilyl)propyl methacrylate (${\gamma}$-MPTS), was grafted on the surface of alumina nanoparticles. We used the surface modified nanoparticles in the hard coating layer for in-mold decoration (IMD) foils and evaluated the coating properties such as hardness and anti-abrasion property. The effects of electron beam (EB) irradiation on color layer and anchor layer of IMD foils were observed through the difference in color and the cross-cut tape test, respectively. Also, cure kinetics as studied quantitatively under various reaction temperatures by analysis of surface properties and Fourier transform infrared (FTIR) spectroscopy. From these results, we constructed database for the commercial exploitation of EB curing system.

Structural Behavior of Retrofitted RC beams with Fire Damages (화재 피해를 입은 일반강도 RC 보의 보수성능)

  • 안주희;신영수;이차돈;홍성걸
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.1013-1016
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    • 2003
  • This paper is to evaluate practically the techniques and materials of repair for RC elements with fire damages as well as to investigate the structural behavior of RC beams according to pre- or post-repair after fire-damages. For this purpose, normal concrete flexural specimens were exposed to high temperatures by the ISO 834 specification. After natural cooling and post-fire-curing in a natural environment for 2 months, the specimens were repaired with polymer cement mortar for 1 month curing.

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Investigated properties of Low temperature curing Ag Paste for Silicon Hetero-junction Solar Cell

  • Oh, Donghyun;Jeon, Minhan;Kang, Jiwoon;Shim, Gyeongbae;Park, Cheolmin;Lee, Youngseok;Kim, Hyunhoo;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.160-160
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    • 2016
  • In this study, we applied the low temperature curing Ag paste to replace PVD System. The electrode formation of low temperature curing Ag paste for silicon Hetero-junction solar cells is important for improving device characteristics such as adhesion, contact resistance, fill factor and conversion efficiency. The low temperature curing Ag paste is composed various additives such as solvent, various organic materials, polymer, and binder. it depends on the curing temperature conditions. The adhesion of the low temperature curing Ag paste was decided by scratch test. The specific contact resistance was measured using the transmission line method. All of the Ag electrodes were experimented at various curing temperatures within the temperature range of $160^{\circ}C-240^{\circ}C$, at $20^{\circ}C$ intervals. The curing time was also changed by varying the conditions of 10-50min. In the optimum curing temperature $200^{\circ}C$ and for 20 min, the measured contact resistance is $19.61m{\Omega}cm^2$. Over temperature $240^{\circ}C$, confirmed bad contact characteristic. We obtained photovoltaic parameter of the industrial size such as Fill Factor (FF), current density (Jsc), open-circuit voltage (Voc) and convert efficiency of up to 76.2%, 38.1 mA/cm2, 646 mV and 18.3%, respectively.

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Polymer Dispersed Liquid Crystal for Enhanced Light Out-Coupling Efficiency of Organic Light Emitting Diodes

  • Gasonoo, Akpeko;Ahn, Hyeon-Sik;Lee, Jonghee;Kim, Min-Hoi;Lee, Jae-Hyun;Choi, Yoonseuk
    • Journal of IKEEE
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    • v.24 no.1
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    • pp.140-146
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    • 2020
  • We investigated light extraction film based on polymer dispersed liquid crystal (PDLC) for application in organic light emitting diodes (OLEDs). At least 30 seconds of direct UV irradiation process for curing PDLC film on a bottom-emitting OLEDs was successfully achieved without damage on the intrinsic properties of the OLED. We demonstrated that high haze and transmittance can be tuned simultaneously by controlling the UV curing time. By adding PDLC as an external layer without any additional treatment, the light scattering and extraction is increased. Consequently, a PDLC scattering film with 89.8% and 59.9 of total transmittance and haze respectively, achieved about 16% of light intensity enhancement from integrating sphere measurement.

On Some Changes in Polymer Blend Topological and Molecular Structures Resulted from Processing

  • Jurkowski, B.;Jurkowska, B.;Nah, C.
    • Elastomers and Composites
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    • v.37 no.4
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    • pp.234-243
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    • 2002
  • A general scheme of a rubber structure is proposed. Using the thermomechanical method(TMA), some changes in the molecular and topological structures for uncured and cured, and unfilled and filled rubbers during processing are shown. In our investigations as region it is understood a complex structure, which is expressed at the thermomechanical curve(TMC) as a zone differed from others in thermal expansion properties. This zone is between the noticed temperatures of relaxation transitions, usually on the level like those determined by DMTA at 1Hz. These regions, which shares, are not stable, and differ in molecular-weight distribution(MWD) of chain fragments between the junctions. Differences in dynamics of the formation of the molecular and topological structures of a vulcanizate are dependent on the rubber formulation, mixing technology and curing time. Some of characteristics of these regions correlate with mechanical properties of vulcanizates what is shown for NR rubbers containing ENR or CPE as a polymeric additive. It is well known that the state of order influences diffusivity of low-molecular substances into the polymer matrix. Because of this, the two topological amorphous regions should influence the distribution of the ingredients and resulting in rubber compounds' heterogeneity, and related properties of cured rubber. Investigation of this problem is expected to be, in the future, one of the essential factors in determining further improvement of polymeric materials properties by compounding with additives and in reprocessing of rubber scrap.

Physical and Mechanical Properties of Permeable Polymer Concrete Utilizing industrial By-Products

  • Sung, ChanYong;Kim, In Su
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.42
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    • pp.78-84
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    • 2000
  • Permeable polymer concrete can be applied to roads, sidewalks, river embankment, drain pipes, conduits, retaining walls, yards, parking lots, plazas, interlocking blocks, etc. This study is to explore a possibility of utilizing industrial by-products, a blast furnace slag and a fly ash, as fillers for permeable polymer concrete. Different mixing proportions are tried to find an optimum mixing proportion of permeable polymer concrete. The tests are carried out at 20$\pm$1$^{\circ}C$ and 60$\pm$2$^{\circ}C$ relative humidity. At 7 days of curing, compressive, flexural and splitting tensile strengths and water permeability ranged between 239~285kgf/$\textrm{cm}^2$, 107~133kgf/$\textrm{cm}^2$, 37~46kgf/$\textrm{cm}^2$ and 4.612~5.913$\ell$/$\textrm{cm}^2$/h, respectively. It is concluded that the blast furnace slag and fly ash can be used in permeable polymer concrete.

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