• Title/Summary/Keyword: Polymer cement

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Application of In-Situ Mixing Hydration Accelerator on Polymer Modified Concrete for Bonded Concrete Overlay (접착식 콘크리트 덧씌우기를 위한 초속경화 첨가재 현장 혼합 폴리머 개질 콘크리트의 적용성 연구)

  • Kim, Young Kyu;Hong, Seong Jae;Lee, Seung Woo
    • International Journal of Highway Engineering
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    • v.17 no.3
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    • pp.85-95
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    • 2015
  • PURPOSES : Recently, bonded concrete overlay has been used as an alternative solution in concrete pavement rehabilitation since its material properties are similar to those of the existing concrete pavements. Deteriorated concrete pavements need rapid rehabilitation in order to prevent traffic jams on Korean expressways. Moreover, speedy and effective repair methods are required. Therefore, the use of bonded concrete overlay with ultra-rapid hardening cement has increased in an effort to reopen promptly the expressways in Korea. However, mobile mixer is required for ultra-rapid hardening cement concrete mixing in the construction site. The use of mobile mixer causes various disadvantages aforementioned such as limitation of the construction supply, open-air storage of mixing materials, increase in construction cost, and etc. In this study, therefore, hydration accelerator in-situ mixing on polymer modified concrete produced in concrete plant is attempted in order to avoid the disadvantages of existing bonded concrete overlay method using ultra-rapid hardening cement. METHODS : Bonded concrete overlay materials using ultra-rapid hardening cement should be meet all the requirements including structural characteristics, compatibility, durability for field application. Therefore, This study aimed to evaluate the application of hydration accelerator in-situ mixing on polymer modified concrete by evaluating structural characteristics, compatibility, durability and economic efficiency for bonded concrete overlay. RESULTS : Test results of structural characteristics showed that the compressive, flexural strength and bond strength were exceed 21MPa, 3.15MPa and 1.4MPa, respectively, which are the target strengths of four hours age for the purpose of prompt traffic reopening. In addition, tests of compatibility, such as drying shrinkage, coefficient of thermal expansion and modulus of elasticity, and durability (chloride ions penetration resistance, freezing-thawing resistance, scaling resistance, abrasion resistance and crack resistance), showed that the hydration accelerator in-situ mixing on polymer modified concrete were satisfied the required criteria. CONCLUSIONS : It was known that the hydration accelerator in-situ mixing on polymer modified concrete overlay method was applicable for bonded concrete overlay and was a good alternative method to substitute the existing bonded concrete overlay method since structural characteristics, compatibility, durability were satisfied the criteria and its economic efficiency was excellent compare to the existing bonded concrete overlay methods.

A Study on the Improvements of Strengths of Water-Permeable Concrete (투수성 콘크리트의 강도개선에 관한 연구)

  • 은재기;이철웅;김완기;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.307-312
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    • 1999
  • The purpose of this study is to ascertain the strength properties of water-permeable concrete with redispersible polymer powder, silica fume and polypropylene fibers. The water-permeable concrete using rediapersibel polymer powder with a water-cement ratio of 25%, polymer-cement ratios of 0 to 10%, silica fume contents of 0 to 10% and fiber contents of 0 to 1.5% are prepared, and tested for flexural strength, compressive strength and water permeability. From the test results, improvements in the strength properties of the water-permeable concrete due to the addition of the redispersible polymer powder, silica fume and fibers are discussed. It is concluded from the test results that the superior flexural and compressive strengths of water-permeable concretes are obtained at a propylene fiber content of 1.0% with a void filling ratio of 50%. And, the water-permeable concrete having a flexural strength of 15.6~28.4kgf/$\textrm{cm}^2$, a compressive strength of 63.5~120.6kgf/$\textrm{cm}^2$, and a coefficient of permeability of 1.14~1.70cm/s at a void filling ratio of 30% can be prepared. Also water-permeable concrete having a flexural strength of 35.6~57.9kgf/$\textrm{cm}^2$, a compressive strength of 164.0~290.0kgf/$\textrm{cm}^2$, and a coefficient of permeability of 0.19~1.04cm/s at a void filling ratio of 50% can be prepared in the consideration of the mix proprotioning factors.

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Examination of Tensile and Adhesion Performance According to Components and Application Environment of Cement-mixed Polymer-based Waterproofing (시멘트 혼입 폴리머계 방수재의 구성요소 및 적용환경에 따른 인장·부착성능 평가)

  • Lee, Jin-Yong;Choi, Jeong-Kyun;Kim, Seong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.41-49
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    • 2021
  • Cement-mixed polymer-based waterproofing materials are generally used in the form of application by mixing in the field, and it is necessary to supplement the construction ability for air bubbles and uneven coating thickness due to irregularities during construction. The final purpose of this study is to improve the waterproofing performance by adding a sheet attaching process to the composite construction rather than the single process of painting and applying the construction method when applying the polymer waterproofing material to the field. In this regard, the applicability was evaluated by examining the material, environment, and manufacturing method.

Inverse Emulsion Polymerization of Water Absorbent Polymer for Strength Enhancement of Mortars (모르타르 강도 증진을 위한 고분자 흡수제의 역유화 중합)

  • Hwang, Ki-Seob;Jung, Myoung-Geun;Jang, Seok-Soo;Jung, Yong-Wook;Lee, Seung-Han;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.434-441
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    • 2010
  • Sodium polyacrylate (PAANa) was synthesized by inverse emulsion polymerization method to absorb excess water in concrete. Liquid paraffin was used as a continuous phase. Acrylic acid (AA) was neutralized by aqueous sodium hydroxide solution (8 M). Different amount of N,N'-methylene bisacrylamide (MBA) was used as a crosslinking agent to change crosslinking density of the synthesized PAANa. The size distribution of synthesized particles was measured by particle size analyzer. Swelling ratio of crosslinked PAANa was evaluated from the equation in D. I. water, cement aqueous solution, and $Ca(OH)_2$ aqueous solution. The FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with PAANa. Incorporation of 1.0 wt% PAANa into cement increased compressive and flexural strength approximately 30% and 10%, respectively, compared with those of ordinary portland cement.

The Study on Synthesis and Application of Polymer Dispersion for Cement Modifier -The Waterproffing Effeet of Cement Mortar by Poly[DMA-co-DAMA] Emulsion- (시멘트 혼화용 폴리머 합성과 그 응용에 관한 연구 -Poly[DMA-co-DAMA] 에멀젼을 이용한 시멘트 모르타르의 방수성-)

  • Kim, Young-Geun;Herh, Dong-Seop;Park, Hong-Soo
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.669-680
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    • 1994
  • DMA-co-DAMA were synthesized from 2-diethylaminoethyl metacrylate and dodecyl-metacrylate containing long chain hydrocarbon group with hydrophilic and hydrophobic radicals. To facilitate water emulsification,acrylic copolymer was cationized by acetic acid to produce acetated acrylic copolymer. The structures of the synthesized copolymer and acetated copolymers were confirmed by IR, NMR, and molecular weight was measured by GPC, and C. H. N elemental analysis. Acetated acrylic copolymers were perfectly emulsified in water and showed increased emulsion stability. Polymer dispersion for cement modifier(PDCM-PDD) was prepared by blending of the guaternized acrylic copolymer synthesized above sodium silicate sodium gluconate oleic acid and triethanol amine. The result with prepared polymer dispersion of cement modfier was examined, and it was found that excellent waterproffing effect; Water permeability ratio is 0.44 under the water pressure of $100g/cm^2$ and 0.55 under $3kg/cm^2$, and water absorption ratio is 0.36~0.47 and 1.02 compressive strength ratio at mixed ratio of water/PDCM-PDD is 45 times.

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Physical and Mechanical Properties of Surlightweight Polymer Concrete (초경량(超輕量) 폴리머 콘크리트의 물리(物理)·역학적(力學的) 특성(特性))

  • Kim, Kyung Tae;Kim, Seong Wan;Sung, Chan Yong;Youn, Joon Ro;Han, Young Kou
    • Korean Journal of Agricultural Science
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    • v.24 no.2
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    • pp.218-225
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    • 1997
  • This study was performed to evaluate the physical and mechanical properties of surlightweight polymer concrete using synthetic lightweight aggregate. The following conclusions were drawn; 1. Unit weight was in the range of $810~970kgf/m^3$, the unit weights of those concrete were decreased 58~65% than that of the normal cement concrete. 2. The highest strength was achieved by $P_1$, it was increased 112% by compressive strength, 378% by bending strength and 290% by tensile strength than that of the normal cement concrete, respectively. 3. Ultrasonic pulse velocity was in the range of 2,206~2,595m/s, which was low showed compared to that of the normal cement concrete. 4. Durability of surlightweight polymer concrete was superior to that of the normal cement concrete. 5. Compressive, tensile and bending strength were largely showed with the increase of unit weight. But, ultrasonic pulse velocity was low showed with the increase of unit weight.

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A Study on Application of High Molecular Compound for Development of Eco-friendly Concrete (친환경 콘크리트 개발을 위한 고분자 화합물의 적용에 관한 연구)

  • Ryou, Jae Suk;Lee, Yong Soo;Song, Il Hyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.5A
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    • pp.299-305
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    • 2012
  • The objective of this paper is to obtain the basic data in order to develop an eco-friendly concrete through evaluation on the properties of polymer cement mortar and concrete using PVAc (Polyvinyl Acetate), as a kind of water-soluble polymer. For this purpose, the physical properties of cement mortar and concrete which does not contain the PVAc as the control batch were compared and analyzed with those using the PVAc. And then, the replacement amount of the PVAc was 3%, 6%, 9% and 12% by binder, respectively. And also, the properties of concrete using the PVAc were evaluated, by adding an antifoaming agent in order to control the air contents increasing with an increase of amount of polymer usage. As a result, in the case of polymer cement mortar using the PVAc, it presented that the compressive strength reduced, while the performance of flexural strength and drying shrinkage increased. When the replacement of the PVAc was 6% within concrete, the compressive, tensile, flexural strength and elastic modulus were increased.

Properties and Environmental Effects Estimation of Grout Using Set Accelerating Agent Made From Calcium Aluminate and Viscosity Agent (칼슘알루미네이트계 급결재와 증점제를 사용한 그라우트의 특성 및 환경영향 평가)

  • Heo, Hyung Seok;Yi, Seong Tae;Noh, Jae Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.4
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    • pp.122-129
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    • 2012
  • In this study, environmental problems(i.e., pH elevation and $Cr^{6+}$ detection) occurred by using the cement grout made from CA(calcium aluminate) were evaluated using viscosity agents(MC, chelate polymer). Ordinary portland cement and blaste-furnace slag cement were used by main materials and ACC(blended mixture of calcium aluminate) were used by accelerator for hardening of grout. In addition, viscosity agents were used for preventing pH elevation and heavy metal detection from grouting materials. From the results, it was noted that when chelate polymer was used, pH elevation and $Cr^{6+}$ detection were minimized. However, other cases showed higher pH elevation and $Cr^{6+}$ detection. At test 1 day, $Cr^{6+}$ detection with age presented over 97% of total value and, after that, additional increase was not distinct. As a result of this study, it was acknowledged that, to control pH elevation and heavy-metal (like $Cr^{6+}$) detection, the usage of BSC and chelate polymer is a very useful fact.

Influence of the Gradation of Aggregates on Permeability of Polymer Concrete (폴리머콘크리트의 투수성에 미치는 골재 입도 분포의 영향)

  • 윤길봉;이병렬;전찬기;양성환;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.141-146
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    • 2001
  • Permeable polymer concrete has a lot of internal voids, which has more excellent performance in permeability and durability than asphalt and cement concrete. Therefore, in this paper, influences of grading distribution of aggregates on the permeable polymer concrete are presented using polyester resin as binders. According to test results, it shows that compressive strength and unit weight increase with continuous grading distribution and increase of binder content, while void and permeability coefficient shows decline tendency

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Influence on the Grading of Aggregates on Properties of Permeable Polymer Concrete (투수성 폴리머 콘크리트의 특성에 미치는 골재 입도 분포의 영향)

  • 윤길봉;황인성;이병렬;전찬기;양성환;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.111-116
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    • 2002
  • Permeable polymer concrete has a lot of internal voids, which has more excellent performance in permeability and durability than asphalt and cement concrete. Therefore, in this paper, influences of grading distribution of aggregates on the permeable polymer concrete are presented using polyester resin as binders. According to test results, it shows that compressive strength and unit weight increase with continuous grading distribution and increase of binder content, while void and permeability coefficient shows decline tendency.

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