• Title/Summary/Keyword: Polymer behavior model

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Biaxial Deformation Behavior of Polymer Networks

  • Takigawa, Toshikazu
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.130-131
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    • 2006
  • Real elastomers show the anomalous behavior in the Ii dependence curves of the derivatives of W with respect to Ii at small strains. The limiting values of the derivatives were evaluated by a simple model based on the assumption that W in the large deformations should coincide with that in the linear elasticity theory. The calculated values were in good agreement with the experimental ones for real elastomers.

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A Model for Diffusion and Dissolution Controlled Drug Release from Dispersed Polymeric Matrix (고분자 분산 매트릭스로부터의 약물방출에 관한 확산 및 용출 제어 모델)

  • Byun, Young-Rho;Choi, Young-Kweon;Jeong, Seo-Young;Kim, Young-Ha
    • Journal of Pharmaceutical Investigation
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    • v.20 no.2
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    • pp.79-88
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    • 1990
  • A numerical model for diffusion and dissolution controlled transport from dispersed matrix is presented. The rate controlling process for transport is considered to be diffusion of drug through a concentration gradient coupled with time-dependent surface change and/or disappearance of the dispersed drug in response to the dissolution. The transport behavior of drug was explained in terms of ${\nu}$ parameter: ${\nu}$ value means a ratio of diffusion time constant and dissolution time constant. This general model has wide range of application from where release is controlled by the diffusion rate to where release is governed by the dissolution rate. Based on this model, theoretical drug concentration, particle size distributions in the polymer matrix system and the resulting release rate were also investigated.

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Instability of Electrically Driven Polymer Liquid Jets

  • Lee Min-Hyung;Kang Seung-Baik;Park Joo-Hyuk
    • Journal of Mechanical Science and Technology
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    • v.20 no.3
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    • pp.409-417
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    • 2006
  • Polymer nanofibers can be generated by a electrospinning process. The process involves electrically charged jet of polymer solutions evolving from a droplet. The jet stretches in vertical direction due to the difference between charged particle and constant current located at the collector, while the Coulomb and viscoelastic forces start to contribute to radial and azimuthal (torsional) stretching. In this paper, the unstable dynamics of the liquid polymer jet is examined experimentally and theoretically. A complex viscoelastic rheological model has been adopted to analyze the behavior of a charged liquid jet. The model includes complex phenomena of stress relaxation of the liquid jet resulting from the competing force components. The experimental data of the jet paths captured by high-speed videocamera also confirm the similar behavior with the predictions.

Nonlinear large deformation dynamic analysis of electroactive polymer actuators

  • Moghadam, Amir Ali Amiri;Kouzani, Abbas;Zamani, Reza;Magniez, Kevin;Kaynak, Akif
    • Smart Structures and Systems
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    • v.15 no.6
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    • pp.1601-1623
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    • 2015
  • Electroactive polymers have attracted considerable attention in recent years due to their sensing and actuating properties which make them a material of choice for a wide range of applications including sensors, biomimetic robots, and biomedical micro devices. This paper presents an effective modeling strategy for nonlinear large deformation (small strains and moderate rotations) dynamic analysis of polymer actuators. Considering that the complicated electro-chemo-mechanical dynamics of these actuators is a drawback for their application in functional devices, establishing a mathematical model which can effectively predict the actuator's dynamic behavior can be of paramount importance. To effectively predict the actuator's dynamic behavior, a comprehensive mathematical model is proposed correlating the input voltage and the output bending displacement of polymer actuators. The proposed model, which is based on the rigid finite element (RFE) method, consists of two parts, namely electrical and mechanical models. The former is comprised of a ladder network of discrete resistive-capacitive components similar to the network used to model transmission lines, while the latter describes the actuator as a system of rigid links connected by spring-damping elements (sdes). Both electrical and mechanical components are validated through experimental results.

The characteristic analysis for polymer of household macromolecule fuel cell (가정용 고분자 연료전지의 중합체에 대한 특성해석)

  • Cho, Y.R.;Kim, N.H.;Han, K.H.;Yun, S.Y.;Baek, S.H.;Kim, I.N.
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1722-1724
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    • 2005
  • The focus of this paper is to develop a mathematical model for investigating the dynamic performance of a polymer electrolyte membrane fuel cell. The model in this work is based on physical laws having clear significance in replicating the fuel cell system and can easily be used to set up different operational strategies. Simulation results display the transient behavior of the voltage within each single cell, and also within a number of such single cells combined into a fuel cell stack system. A linear as well as a nonlinear analysis of the polymer electrolyte membrane fuel cell system(PEMFC) has been discussed in order to present a complete and comprehensive view of this kind of modeling. Also, a comparison of the two kinds of analysis has been performed. Finally, the various characteristics of the fuel cell system are plotted in order to help us understand its dynamic behavior. Results indicate that there is a considerable amount of error in the modeling process if we use a linear model of the fuel cell. Thus, the nonlinearities present in the fuel cell system should be taken into account in order to obtain a better understanding of the dynamic behavior of the fuel cell system.

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Brownian Dynamics Simulation Study on the Anisotropic FENE Dumbbell Model for Concentrated Polymer Solution and the Melt

  • Sim, Hun Gu;Lee, Chang Jun;Kim, Un Jeon;Bae, Hyeong Seok
    • Bulletin of the Korean Chemical Society
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    • v.21 no.9
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    • pp.875-881
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    • 2000
  • We study the rheological properties of concentrated polymer solution and the melt under simple shear and elon-gational flow using Brownian dynamicssimulation. In order to describe the anisotropic molecular motion, we modifiedthe Giesekus' mobility tensor by incorporating the finitely extensible non-linear elastic (FENE) spring force into dumbbell model. To elucidate the nature of this model, our simulation results are compared with the data of FENE-P ("P"standsfor the Perterin) dumbbell model and experiments. While in steady state both original FENE and FENE-P models exhibit a similar viscosity response,the growthof viscosity becomes dissimilar as the anisotropy decreases and the flowrate increases. The steady state viscosity obtained from the simulation well describes the experiments including the shear-thinning behavior in shear flow and viscosity-thinning behavior in elongational flow. But the growth of viscosity oforiginal FENE dumbbell model cannot describe the experimental results in both flow fields.

Flexural Creep Model of Recycled-PET Polymer Concrete (재활용 PET 폴리머 콘크리트의 휨 크리프모델)

  • Tae, Ghi-Ho;Jo, Byung-Wan;Park, Jong-Wha
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.661-664
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    • 2006
  • As polymer concrete become more widely used by design engineers, it is important that the viscoelastic mechanical behavior of these materials is properly taken into account. Also, an important consideration in the design of polymer concrete is the behavior of creep according to ages of polymer concrete. In this study, flexural creep test was performed on recycled-PET polymer concrete. An method of accelerating the flexural creep tests, called the two-point method, was developed. The two-point method uses the results of three 24-hours creep tests performed at elevated temperatures to develop a Prony series equation that predicts the long-term creep strains at room temperature. The test results demonstrated that two-point method can predict long-term creep strain with sufficient accuracy. The difference between the predicted creep compliance values from those obtained experimentally was less than 5 percent.

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Numerical Analysis of Drag-Reducing Turbulent Flow by Polymer Injection with Reynolds Stress Model (레이놀즈응력모델을 이용한 난류의 고분자물질 첨가 저항감소현상에 대한 수치해석)

  • Ko, Kang-Hoon;Kim, Kwang-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.1
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    • pp.1-8
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    • 2000
  • A modified low-Reynolds-number Reynolds stress model is developed for the calculation of drag-reducing turbulent flows induced by polymer injection. The results without polymer injection are compared with the results of direct numerical simulation to ensure the validity of the basic model. In case of drag reduction, profiles of mean velocity and Reynolds stress components, in two-dimensional channel flow, obtained with a proper value of viscosity ratio are presented and discussed. Computed mean velocity profile is in very good agreement with experimental data. And, the qualitative behavior of Reynolds stress components with the viscosity ratio is also reasonable.