• 제목/요약/키워드: Polymer Material

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이온젤 전해질 절연체 기반 고분자 비휘발성 메모리 트랜지스터 (Ion Gel Gate Dielectrics for Polymer Non-volatile Transistor Memories)

  • 조보은;강문성
    • 한국전기전자재료학회논문지
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    • 제29권12호
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    • pp.759-763
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    • 2016
  • We demonstrate the utilization of ion gel gate dielectrics for operating non-volatile transistor memory devices based on polymer semiconductor thin films. The gating process in typical electrolyte-gated polymer transistors occurs upon the penetration and escape of ionic components into the active channel layer, which dopes and dedopes the polymer film, respectively. Therefore, by controlling doping and dedoping processes, electrical current signals through the polymer film can be memorized and erased over a period of time, which constitutes the transistor-type memory devices. It was found that increasing the thickness of polymer films can enhance the memory performance of device including (i) the current signal ratio between its memorized state and erased state and (ii) the retention time of the signal.

Ethylene Oxide기를 갖는 Acrylate계 Gel Polymer Electrolyte의 전기화학적 특성에 관한 연구 (A Study on Electrochemical Properties of Acrylate-based Gel Polymer Electrolyte with Ethylene Oxide Group)

  • 김현수;신정한;문성인;오대희
    • 한국전기전자재료학회논문지
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    • 제17권6호
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    • pp.608-614
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    • 2004
  • The gel polymer electrolyte was prepared by radical polymerization using tetra(ethylene glycol) diacrylate and tri(ethylene glycol) dimethacrylate to investigate affect of the number of ethylene oxide. The gel polymer electrolyte showed good electrochemical stability up to 4.5 V vs. Li/Li and high ionic conductivity at various temperatures. The lithium-ion polymer batteries with the gel polymer electrolyte, tetra(ethylene glycol) diacrylate- and tri(ethylene glycol) dimethacrylate-based, also represented good electrochemical performances such as rate capability, low-temperature performances and cycleability. However, the cell with tri(ethylene glycol) dimethacrylate, which has three ethylene oxide, showed better electrochemical performance.

A Case Study of Paraffin Double-walled Microencapsulation Preparation Using Acrylic Polymer and Melamine Polymer for Thermal Energy Storage

  • Nguyen, Hang Vo-Minh;Kim, Chae-Hyun;Kim, Jong-Kuk
    • 한국태양에너지학회 논문집
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    • 제39권5호
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    • pp.65-78
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    • 2019
  • In this study, we investigated the paraffin encapsulation using double-walled encapsulation technique. The first encapsulation used methyl methacrylic acid as the main component in acrylic polymer and the second encapsulation used melamine polymer. Particles size and distribution of the capsules were analyzed using scanning electron microscopy. In the first encapsulation, the stable capsules were obtained at 67% of phase change material ratio to methyl methacrylic acid monomer and the size of the capsule was from 0.2 to $0.3{\mu}m$. In the second encapsulation, the size of the capsules was almost the same with those capsules prepared in the first encapsulation. The particle size of single wall and double wall was about $0.3{\mu}m$. As a result of the encapsulation of paraffin using double-walled encapsulation technique, it was confirmed that the particle size was determined in the process of encapsulating using the acrylic polymer at the first wall material, and the physical and thermal stability of the capsules were imparted using melamine at the secondary wall material.

휨 하중을 받는 재생 PET 폴리머 콘크리트의 인장크리프 모델 (Tension Creep Model of Recycled PET Polymer Concrete with Flexural Loading)

  • 채영석;태기호
    • 한국안전학회지
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    • 제27권5호
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    • pp.117-125
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    • 2012
  • In recent years, polymer concrete based on polyester resin have been widely generalized and the research of polymer concrete have been actively pursued by the technical innovations. Polymer concrete is a composite consisting of aggregates and an organic resin binder that hardens by polymerization. Polymer concrete are stronger by a factor of three or more in compression, a factor of four to six in tension and flexural and a factor of two in impact when compared with portland cement concrete. In view of the growing use of polymer concrete, it is important to study the physical characteristics of the material, emphasizing the short term properties as well as long term mechanical behavior. If polymer concrete is to be used in flexural load-bearing application such as in beam, it is imperative to understand the deformation of the material under sustained loading conditions. This study is proposed to empirical and mechanical model of polymer concrete tension creep using long-term experimental results and mathematical development. The test results showed that proposed model has been used successfully to predict creep deformations at a stress level that was 20 percent of the ultimate strength and viscoelastic behavior of recycled-PET polymer concrete is linear of stress level up to 30 percent. It is expected that the present model allows more realistic evaluation of varying stresses in polymer concrete structures with a constant loading.

Relation between Huggins Constant and Compatibility of Binary Polymer Mixtures in the Aqueous Ternary Systems

  • Isamu Inamura;Makoto Kittaka;Tatsuya Aikou;Kazuhiko Akiyama;Tomoyuki Matsuyama;Masatsugu Hiroto;Hirade, Ken-ichi;Yuji Jinbo
    • Macromolecular Research
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    • 제12권2호
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    • pp.246-250
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    • 2004
  • We have classified a number of aqueous ternary systems containing two different polymers into three types by focusing on the deviation of the Huggins constant k'from the additivity line. Systems of type I have negative deviations of k'; the repulsive interaction between the two different polymers dominates. In systems of type II, k' almost follows the additivity relation; the repulsive and attractive interactions between the two different polymers are balancing. Type III systems have positive deviations of k'; the attractive interactions are relatively dominant. This classification of systems is supported by the fact that the positive and negative deviations of k' from the additivity line also correspond to the sign of interaction parameter between polymer 2 and 3, Δb$\_$23/. Furthermore, we have verified the relatively high compatibility between dextran and poly(vinyl alcohol) by determining the binodal concentration of a liquid-liquid phase separation for a water/dextran/poly(vinyl alcohol) system, which is classified as type III. Thus, we found that the compositional dependence of k' closely relates to the compatibility of binary polymer mixtures in aqueous ternary systems.

Impedance를 이용한 전도성고분자 센서의 에탄올 가스 감응특성 (Ethanol Gas Sensing Characteristics of Conducting Polymer Sensor Using Impedance)

  • 이경문;유준부;전희권;이병수;이덕동;허증수
    • 한국재료학회지
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    • 제13권3호
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    • pp.155-159
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    • 2003
  • The polypyrrole and polyaniline thin film sensors which were made by chemical polymerization were employed to detect ethanol gas. With a single sensor element we can obtain characteristic patterns of behaviour across a very wide frequency range when measuring either resistance or capacitance. Impedance spectroscopy was employed to study the gas sensing behavior of both capacitance and resistance based sensors with conducting polymer as the active sensing element.

전도성 고분자 복합체 제조를 위한 신합성 연구 (I) : 다공성정도가 전도성 고분자 복합체의 전도도에 미치는 영향 (Process for the Preparation of Conducting Polymer Composites (I) : Effect of the Porosity on the Conductivity)

  • 손석희;박영준;김중현
    • 공업화학
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    • 제7권2호
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    • pp.393-400
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    • 1996
  • Seed 유화 중합법과 용매 추출법을 이용하여 전도성 고분자 복합체를 위한 다공성 입자를 제조하였다. 건조된 다공성 입자를 모체 고분자로 사용하여 dopant로 사용하는 $FeCl_3$를 methanol에 녹여 흡수시킨 뒤에 건조시키고, 이를 다시 pyrrole를 녹인 ethyl ether 용액으로 중합하여 용액을 증발시킴으로서 전도성 고분자 복합체를 합성하였다. 이때, 모체 고분자로 사용된 비다공성 입자와 다공성 입자의 전도도를 비교하였다. 실험결과, 전도성 복합체의 전도도는 비다공성 입자보다는 다공성 입자를 사용하여 제조한 복합체가 전도성 중합체가 입자의 표면뿐만 아니라 pore안에서도 용이하게 형성되어 더 우수한 전도도를 나타내었다.

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Adaptive Fuzzy 제어기를 이용한 Embedded 시스템 기반의 기능성 고분자 구동체의 이중제어에 관한 연구 (A Study on Multi-Vehicle Control of Electro Active Polymer Actuator based on Embedded System using Adaptive Fuzzy Controller)

  • 김태형;김훈모
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1997년도 추계학술대회 논문집
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    • pp.307-310
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    • 1997
  • In case of environment requiring safety such as human body and requiring flexible shape, a conventional mechanical actuator system does not satisfy requirement. Therefore, in order to solve this problem, a research of various smart material such as EAP (Electro Active Polymer), EAC (Electro Active Ceramic) and SMA (Shape Memory Alloy) is in progress. Recently, the highest preferring material among various smart material is EP (Electrostictive Polymer), because it has very fast response time, poerful force and large displacement. The previous researches have been studied properties of polymer and simple control, but present researches are studied a polymer actuator. An EP (Electostrictive Polymer) actuator has properties which change variably as shape and environmental condition. Therefore, in order to coincide with a user's purpose, it is important not only to decide a shape of actuator and mechanical design but also to investigate a efficient controller. In this paper, we constructed the control logic with an adaptive fuvy algorithm which depends on the physical properties of EP that has a dielectric constant depending on time.

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리튬 폴리머 전지용 $LiMnO_2$정극의 도전재에 따른 전기 화학적 특성 (Electrochemical Properties of $LiMnO_2$ Cathode as a Function of Addition of Electric Active Materials for Lithium Polymer Batteries)

  • 조영재;김종욱;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.474-477
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    • 2001
  • The properties of LiMnO$_2$ was studied as a cathode active material for lithium polymer batteries. LiMnO$_2$ cathode active materials were synthesized by the reaction of LiOH . $H_2O$ and Mn$_2$O$_3$at various temperature under argon atmosphere. For lithium polymer battery applications, the LiMnO$_2$cell was characterized electrochemically by charge-discharge experiments and a.c. impedance spectroscopy. And the relationship between the characteristics of powders and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170 mAh/g for ο-LiMnO$_2$ cell was achieved. Used that SP270 as electric active material in LiMnO$_2$, it is excellent than property of electric active material used Acetylene black or KS6 at charge/discharge capacity.

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슬리브드 폴리머 발사체의 충격시 벌징 거동 패턴에 미치는 코어 재료의 영향 (Influences of Core Materials during Impact The Bulging Behavior of Sleeved Polymer Projectiles)

  • 신형섭;박성택;정윤철
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.198-203
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    • 2008
  • In the present study, the deformation behavior of both of metal and polymer combination on impact was investigated. They have showed a different deformation behavior when the co-axially combined projectile was impacted on rigid target. The theory according to Taylor's simplified approach assumes an ideally rigid-plastic material model exhibiting rate-independent behavior and simple one-dimensional wave propagation concepts that neglect radial inertia. In the case of impact with polymeric materials, elastic strain in general are not negligible compared with plastic strain; and the rigid-plastic material behavior assumed by Taylor for metallic materials cannot be applied any more. Since, the sleeve and the core materials have widely different mechanical properties, they will produce a significant difference of mechanical impedance with each other. Therefore these impedance mismatch influences on the deformation behavior sleeved polymer projectile on impact. As a result, sleeved projectiles will generate a very interesting impact behavior. Therefore, the according to sleeved metal material and core polymer material can see expected. The objective of this study was to investigate the factors which influences on deformation behavior pattern of sleeve materials surface.

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