• Macromolecular Research
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• v.16 no.2
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• pp.139-148
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• 2008

Biodegradable and elastic poly(L-lactide-co-$\varepsilon$-caprolactone) (PLCL) was electrospun to prepare nanofibers, and N-isopropylacrylamide (NIPAAm) was then grafted onto their surfaces under aqueous conditions using $^{60}Co-{\gamma}$ irradiation. The graft yield increased with increasing irradiation dose from 5 to 10 kGy and the nanofibers showed a greater graft yield compared with the firms. SEM confirmed that the PLCL nanofibers maintained an interconnected pore structure after grafting with NIPAAm. However, overdoses of irradiation led to the excessive formation of homopolymer gels on the surface of thc PLCL nanofibers. The equilibrium swelling and deswelling ratio of the PNIPAAm-g-PLCL nanofibers (prepared with 10 kGy) was the highest among the samples, which was consistent with the graft yield results. The phase-separation characteristics of PNIPAAm in aqueous conditions conferred a unique temperature-responsive swelling behavior of PNIPAAm-g-PLCL nanofibers, showing the ability to absorb a large amount of water at < $32^{\circ}C$, and abrupt collapse when the temperature was increased to $40^{\circ}C$. In accordance with the temperature-dependent changes in swelling behavior, the release rate of indomethacin and FITC-BSA loaded in PNIPAAm-g-PLCL nanofibers by a diffusion-mediated process was regulated by the change in temperature. Both model drugs demonstrated greater release rate at $40^{\circ}C$ relative to that at $25^{\circ}C$. This approach of the temperature-controlled release of drugs from PNIPAAm-g-PLCL nanofibers using gamma-ray irradiation may be used to design drugs and protein delivery carriers in various biomedical applications.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.5
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• pp.69-78
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• 2014

The paper recycling becomes more important technology in terms of the reduction of the municipal waste and of saving natural resource such as wood. However the more utilization of recycled fiber would result in the higher contaminants in the papermaking processes and in the deterioration of the paper quality. The oil marks in the paper products becomes one of the major defects of paper products originated from paper recycling. The coagulation of various stickies in recycled fiber stock led to the oil marks. In this work, we applied functional polymer additives such as the dispersing agents, the fixing agents and the hydrophobic talc powder for the control of those stickies in order to remove the oil marks. The addition of the talc powder showed the great reduction in the oil marks of the packaging paper products. The hydrophobic surface of the talc particles collected the individual sticky materials and prevented their aggregation in the recycled fiber stock, which resulted in the great reduction of the oil marks on the paper products.

• Computers and Concrete
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• v.31 no.6
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• pp.513-525
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• 2023

This research presents the experimental and theoretical evaluations on circular steel-fiber-reinforced-concrete (SFRC) columns reinforced by glass-fiber-reinforced-polymer (GFRP) rebar under the axial compressive loading. Test programs were designed to investigate and compare the effect of different parameters on the structural behavior of columns by performing tests. Theses variables included conventional concrete (CC), fiber concrete (FC), steel/GFRP longitudinal rebars, and transversal rebars configurations. A total of 16 specimens were constructed and categorized into four groups in terms of different rebar-concrete configurations, including GFRP-rebar-reinforced-CC columns (GRCC), GFRP-rebar-reinforced-FC columns (GRFC), steel-rebar-reinforced-CC columns (SRCC) and steel-rebar- reinforced-FC columns (SRFC). Experimental observations displayed that failure modes and cracking patterns of four groups of columns were similar, especially in pre-peak branches of load-deflection curves. Although the average ultimate axial load of columns with longitudinal GFRP rebars was obtained by 17.9% less than the average ultimate axial load of columns with longitudinal steel rebars, the average axial ductility index (DI) of them was gained by 10.2% higher than their counterpart columns. Adding steel fibers (SFs) into concrete led to the increases of 7.7% and 6.7% of the axial peak load and the DI of columns than their counterpart columns with CC. The volumetric ratio had greater efficiency on peak loads and DIs of columns than the type of transversal reinforcement. A simple analytical equation was proposed to predict the axial compressive capacity of columns by considering the axial involvement of longitudinal GFRP rebars, volumetric ratio, and steel spiral/hoop rebar. There was a good correlation between test results and predictions of the proposed equation.

• Polymer(Korea)
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• v.30 no.6
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• pp.498-504
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• 2006

A suspension polymerization of styrene In aqueous phase was employed to study if polystyrene particles ranging from 1 to $20{\mu}m$ can be produced. Hydrophobic silica was selected as a stabilizer and azo-bisisobutyronitrile (AIBN) as an initiator. Polymerization reaction was carried out at a selected temperature in the range of $65{\sim}95^{\circ}C$. Stabilizer concentration was varied from 0.17 to 3.33 wt% compared to the water while the concentration of the initiator was raised from 0.13 to 6.0 wt% compared to the monomer. Dispersion of hydrophobic silica into the water phase was achieved by precise control of pH. Optimum dispersion of silica was obtained at pH 10. Average particle diameter decreased with increasing amounts of stabilizer concentration initially, exhibiting the minimum average diameter at 1.67 wt% of stabilizer concentration, after which it started to Increase. It is speculated that an excessive presence of stabilizer encouraged a secondary reaction in the reaction medium, which led to particle agglomeration, and as a result an increase in average particle diameter. Molecular weight was found to be independent of stabilizer concentration between 0.13 and 1.00 wt% whereas, it increased when stabilizer concentration exceeded 1.67 wt%. Variation of molecular weight was probably caused by the reduced activity and efficiency of initiator due to the high concentration of silica, and the secondary reaction in the reaction medium, as well. An increase in the Initiator concentration and/or reaction temperature resulted in an increase in both reaction rate and particle diameter. Consequently, we have confirmed that spherical polystyrene particles with $1{\sim}20{\mu}m$ in diameter can be prepared by careful selection of the concentration of stabilizer, initiator, pH and reaction temperature.

• Journal of the Korea Concrete Institute
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• v.19 no.6
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• pp.717-726
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• 2007

If conventional reinforcements are used for high-strength concrete (HSC) structures, a large amount of the reinforcement must be required to compensate for the brittleness of HSC and make the best use of HSC. This raises some structural problems such as steel congestion and an increase in self-weight. Therefore, alternative reinforcing materials and methods for HSC structures are needed. In this study, four full-scale beam specimens constructed with HSC (100 MPa) were tested to investigate the effect of the different shear reinforcements on the shear behavior. These four specimens were reinforced for shear stirrups with normal and high strength steels, headed bars, and carbon fiber-reinforced polymer (CFRP) bars, respectively. In addition, steel fibers were added to the HSC in the two of the specimens to observe their beneficial effects. The use of high strength steels resulted in the improvement of the shear capacity since the shear resistance provided by the shear reinforcements and the bond strength were increased. The specimen reinforced with headed bars also showed a superior performance to the conventional steel reinforced specimen due to the considerably high anchorage strength of headed bar. CFRP bars used in this research, however, seemed to be inadequate for shear reinforcement because of the inferior bond capacity. The presence of the steel fibers in concrete led to remarkable improvement in the ductility of the specimens as well as in the overall cracks control capability.

• Journal of the Korean Chemical Society
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• v.42 no.1
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• pp.92-98
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• 1998

Poly(DL-lactide-co-glycolide) (80:20) was synthesized from DL-lactide and glycolide, and the copolymers was made to micelles containing clonazepam for drug delivery system. The release experiments of the drug from micelles were operated at pH 7.4 phosphate buffer solution $37.0{\pm}0.05^{\circ}C$. The linearly-releasing time ranges of the drug from micelles prepared with the copolymer/drug weight ratio of 20:40, 20:20, and 40:20 (mg) were 50, 41, and 29 days, respectively. So the linearly-releasing time of drug showed the order of micelles 20/40 > micelles 20/20 > micelles 40/20. In short, the formulation allows polymeric micelles to suppress the burst effect of the drug release mechanism, which led to the controlled release pattern and the possibility of drug delivery system for veinous injection.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.3
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• pp.16-23
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• 2016

DFRCC (ductile fiber reinforced cementitious composites), which are a significantly improved ductile material compared to conventional concrete, were evaluated as a new construction material with a high potential applications to concrete structures for a range of purposes. In this study, experiments on the failure behavior of composite beams with a DFRCC and FRP (fiber reinforced polymer) plank with a rib used as permanent formwork and tensile reinforcement were carried out. A normal concrete and a fiber reinforced concrete with PVA series of RF4000 and the PP series of PP-macro were used for comparison, and each RF4000+RSC15 and PP-macro+RSC15 was tested by producing composite beams. The experimental results of the FRP plank without a sand coating showed that sliding failure mode between the FRP plank and concrete started from a flexural crack at the beam center; therefore it is necessary for the FRP plank to be coated with sand and the effect of the fiber to failure mode did not appear to be huge. The experiment of the FRP plank with a sand coating showed that both 1200mm and 2000mm allowed sufficient bonding between the concrete and FRP plank. The maximum load of the fiber reinforced concrete was higher than that of normal concrete and the case which a series of PP fiber was mixed showed the highest value. The crack latency caused by the fibers led to composite action with a FRP rib.

• YAKHAK HOEJI
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• v.41 no.3
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• pp.305-311
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• 1997

Sustained release-microspheres and immediate release-pellets were prepared to develop a controlled release multiparticulate system containing both water soluble and insoluble dr ug. Pseudoephedrin.HCl (EPD) and terfenadine (TRF) were used as model drugs, respectively. Sustained release-EPD microspheres were prepared by solvent evaporation method using Eudragit RL or RS as a matrix combined with pH-insensitive film coating. Smaller EPD microspheres were obtained when smaller amount of Eudragit as a matrix material or larger amount of magnesium stearate as a dispersing agent was used. However the obtained microspheres did not show syfficient sustained release characteristics. About 97% of EPD was released after 1 hr irrespective of matrix material used. Subsequent coating of the microspheres with pH-insensitive polymer such as Eudragit RS or ethylcelulose (EC) resulted good sustained in 37.5, 73.3 and 92.0% release of encapsulated EPD in distilled water after 1, 3 abd 7 hr, respectively. It corresponds to mean dissolution time (MDT) of 2.3 hr, which is much larger than that of un-coated EPD microspheres (0.0048 hr). Immediate release TRF pellets were prepared by spherically agglomerated crystallization using Eudragit E as an inert matrix and methylene chloride as a liquid binder. Using Eudragit E alone as a matrix resulted in satisfactory physical properties of the pellets such as sphericity, surface texture and flowability, but led to slower release of TRF from pellets than un-modified TRF powder (MDT of 1.70 vs 1.43 hr in pH 1.2 dissolution medium). Introducing propylene glycol or sodium lauryl sulfate as an emulsifier brought about faster release of TRF from pellets (MDT of 1.14 and 0.95 hr, respectively). In conclusion, microencapsulation by solvent evaporation combined with film coating and spherically agglomerated crystallization were successfully utilized to prepare controlled release multiparticulate system composed of sustained release EPD-microspheres and immediate release TRF pellets.

• Applied Chemistry for Engineering
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• v.18 no.1
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• pp.77-83
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• 2007

It is essential that second order nonlinear optical materials have low optical propagation losses in the wavelengths of second harmonic generation for practical applications in waveguides. Three dipolar chromophores substituted with nitro, cyano, and alkyl sulfone as an electron withdrawing group were prepared. The UV-Vis absorption spectra of the cyano and alkylsulfone chromophores showed a blue-shift compared to the nitro chromophore. The introduction of oxadiazole segment in the chromophore structure led to similar spectral shift. The blue-shift can produce low optical loses at second harmonics. The chromophores were successfully attached to a polyimide, yielding side chain polymers. The nonlinear optical property of the prepared optical polymers was determined by measuring electro-optic coefficient at 1.55 mm. The polymers exhibited high glass transition temperature of over $185^{\circ}C$ and thermal stability to $300^{\circ}C$ through differential scanning calorimeter analysis and thermal gravimetric analysis.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.958-964
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• 2008

In this work, micro-sized dextran particles, which have recently been focused as one of the candidate materials for the Drug Delivery System(DDS), were prepared by means of the Supercritical Antisolvent (SAS) process with $CO_2$. With dimethyl sulfoxide(DMSO) as the solvent, effects of the operating variables such as temperature (308.15~323.15 K), pressure(90~130 bar), solute concentration(10~20 mg/ml), and the molecular weight of the solute(Mw=37,500, 450,000) on the size and morphology of the resulting particles were thoroughly observed. The higher solute concentration led to the larger particles, however, the injection velocity of the solution and pressure did not show significant effects on the resulting particle size. With dextran of the lower molecular weight, the smallest particles were obtained at 313.15 K. On the other hand, the size of the particles from the high molecular weight dextran ranged between $0.1{\sim}0.5{\mu}m$ with an incremental effect of the temperature and pressure. For the solute concentration of 5 mg/ml, the lower molecular weight dextran did not form discrete particles while aggregation of the particles appeared when the solute concentration exceeded 15 mg/ml for the higher molecular weight dextran. It is believed that if the solute concentration is too low, the degree of the supersaturation in the recrystallization chamber would not be sufficient for initiation of the nucleation and growth mechanism. Instead, the spinodal decomposition mechanism leads to formation of the island-like phase separation which appears similar to aggregation of the discrete particles. This effect would be more pronounced for the smaller molecular weight polymer system due to the narrower phase-splitting region.