• Title/Summary/Keyword: Polymer Development

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Utility of Hydrophilic Polymer for Green Technology Development in Green Roofs Using Rainwater (빗물활용 옥상녹화 녹색기술 개발을 위한 친수성 중합체의 효용성)

  • Ju, Jin-Hee;Yang, Ji;Yoon, Yong-Han
    • Journal of Environmental Science International
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    • v.21 no.12
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    • pp.1469-1476
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    • 2012
  • Hydrophilic polymer is suitable as soil conditioners for green roofs that use rainwater, due to promotion of water retention capacity as well as enhancement of the water absorbing capacity. The objective of the present study was to investigate the effects of different levels of hydrophilic polymer concentrations (0, 0.1, 0.2, 0.4, 0.8% w/w) on the water holding capacity and growth response of 6 species in soils amended with hydrophilic polymer in 5 cm of soil thickness on green roofs. The results showed that the water holding capacity of the amended soil improved with increasing amount of applied polymer. The application of 0.8% w/w of the polymer increased the soil moisture by 87% compared to the control, and decreased slowly in green roofs during an arid period. The growth of Sedum spurium 'Dragon's blood' and Lampranthus spectabilis increased significantly and had greater than 60% relative coverage with higher hydrophilic polymer concentrations. However, Juniperus chinensis var. sargentii and Euonymus fortunei var. radicans had no significant differences upon change of hydrophilic polymer concentrations. In Carex kujuzana and Carex morrowii 'Aurea variegata', growth decreased with increase of hydrophilic polymer concentrations. 30 days after planting, Juniperus chinensis var. sargentii, Euonymus fortunei var. radicans, Carex kujuzana, and Carex morrowii 'Aurea variegata' died back due to lowest soil thickness (5 cm), but Sedum spurium 'Dragon's blood' and Lampranthus spectabilis had greater than 90% survival.

A Study on the Development of Polymer-Modified Mortars Using Styrene-Butyl Acrylate Latexes (St/BA의 모노머 비에 따른 폴리머 시멘트 모르타르 개발에 관한 연구)

  • Hyung, Won-Gil;Mun, Kyung-Ju;Song, Hun
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.785-791
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    • 2006
  • The purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars based on styrene and butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effects of monomer ratio on the typical properties of the polymer-modified mortars with styrene and butyl acrylate latexes. The polymer-modified mortars using the styrene and butyl acrylate latexes polymerized with various monomer ratios are prepared with different polymer-cement ratios, and tested for the particle size of polymer latexes, air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the polymer-modified mortars using styrene and butyl acrylate latexes with the mix proportions of synthesis having monomer ratios of 50:50 to 60:40 for the appropriate mix proportions can be recommended for practical applications. Their basic properties are greatly affected by the polymer-cement ratio rather than the monomer ratio, and are improved over un-modified mortar.

A Recent Trend of Research and Development of Polymer Insulator (고분자 애자의 연구 개발 동향)

  • Han, S.I.;Park, K.S.;Jeong, Y.H.;Park, Y.B.;Yun, I.S.;Kim, J.S.;Han, S.O.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1691-1693
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    • 1996
  • The construction or enlargement of the power facilities requires the compactness of them, and the development of power system amenities because of some reasons; the shortness of a site for power facilities, social request of the harmony of them with surroundings, and so on. For the insulator in this area, the research and development of polymer or composite insulator or its applications have been increased rapidly in some advanced countries, but the activities of our country are being in a weak step although our concern has been gradually enlarged about it in recent years. Thus, in this paper, we intend to introduce the trend of research and development of it in the inside and outside of the country.

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Optimization of the Water Absorption by Crosslinked Agar-g-Poly(acrylic acid) (Agar 그래프트 폴리아크릴산 겔의 흡수능 최적화)

  • Wuttisela, Karntarat;Panijpan, Bhinyo;Triampo, Wannapong;Triampo, Darapond
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.537-543
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    • 2008
  • Crosslinked agar-g-poly(acrylic acid) (x-agar-g-PAA) super absorbent with a water absorbency ($Q_{H2O}$) of approximately 660 g/g was synthesized by the copolymerization of agar with an acrylic acid monomer. KPS and MBA were used as the initiator and crosslinker, respectively. Grafting was performed in air. Infrared spectroscopy was used to identify the product of copolymerization. The optimum conditions to synthesize the x-agar-g-PAA superabsorbent were 0.1 g of agar, 0.1 g of the KPS initiator, for 15 min; 50% AA monomer, 0.005 g of the MBA crosslinker, for a propagation time of 5 min; and 1 M NaOH for 15 min to allow for saponification. The reaction temperature was $80{^\circ}C$.

Development of an Eco-friendly Plasticizer using Crude Glycol Derived from the Biodiesel Process (바이오디젤부산물인 폐글리세롤을 이용한 친환경 가소제의 개발)

  • Kang, Soo-Jung;Bae, Sung-Jae;Jin, Dae-Eon;Kim, Jinhwan
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.3
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    • pp.365-370
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    • 2014
  • Objectives: The major objective is development of an eco-friendly non-phthalate plasticizer using crude glycol derived from the biodiesel process. Methods: Glycerol monolaurate(GML) was synthesized from glycol and triglyrcerides. Glycerol diacetomonolaurate(GDAL) was synthesized from GML and acetic acid. Results: The synthesis of the GDAL plasticizer was measured with nuclear magnetic resonance spectroscopy(NMR). Mechanical properties were measured by universal testing machine(UTM) and the experimental values were compared with phthalate plasticizers such as dioctyl phthalate(DOP). In particular, the values for tensile strength and elongations with GDAL were higher than with DOP. Conclusions: We confirmed the development of an eco-friendly non-phthalate plasticizer by NMR. Based on our results, applicability for food and drug packaging materials was found.

Thermotropic Liquid Crystal Polymer Reinforced Poly(butylene terephthalate) Composites to Improve Heat Distortion Temperature and Mechanical Properties

  • Kim, Jun-Young;Kang, Seong-Wook;Kim, Seong-Hun
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.358-366
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    • 2006
  • Thermotropic liquid crystal polymer (TLCP)-reinforced poly(butylene terephthalate) (PBT) composites were prepared by melt processing. The improvement in the mechanical properties and the processability of the PBT/TLCP composites was attributed to the reinforcing effect by TLCP phase and its well distribution in the PBT matrix. X-ray diffraction results demonstrated that a slow cooling process leads to the thicker lamellar structures and the formation of more regular crystallites in the composites. The incorporation of TLCP improves not only the tensile strength and flexural modulus but also the heat distortion temperature (HDT) of the PBT/TLCP composites. The HDT values of the composites were dependent on TLCP content. The improvement in the HDT values of the PBT/TLCP composites may be explained in terms with the increased flexural modulus, the development of more regular crystalline structures, and the enhancement of the ability of the composites to sustain the storage modulus by TLCP phase. In addition, the simple additivity rule makes it possible to predict the HDT values of the PBT/TLCP composites.

Evaluation of BR Blending Methods for ESBR/silica Wet Masterbatch Compounds

  • Kim, Woong;Ahn, Byungkyu;Mun, Hyunsung;Yu, Eunho;Hwang, Kiwon;Kim, Wonho
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.242-248
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    • 2017
  • Wet masterbatch (WMB) technology is studied to develop high-content and highly disperse silica-filled compounds. This technology refers to the solidification of surface-modified silica with a rubber solution or latex. Until now, researchs based on styrene butadiene rubber (SBR)/silica WMB has been mainly performed. However, the blending of SBR/silica WMB and BR is not known and is currently under research and development. Therefore, in this study, the BR blending method suitable for emulsion (ESBR)/silica WMB is investigated by measuring their cure characteristics and the mechanical and dynamic viscoelastic properties. As a result, it was confirmed that the blending of ESBR/silica WMB and BR/silica dry masterbatch is most appropriate. However, it showed a disadvantage compared with the conventional mixing method, which was due to the surfactant remained and the sulfuric acid used as the coagulant.

Effect of polymer substrates on nano scale hot embossing (나노 사이즈 hot embossing 공정시 폴리머의 영향)

  • Lee, Jin-Hyung;Kim, Yang-sun;Park, Jin-goo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.71-71
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    • 2003
  • Hot embossing has been widely accepted as an alternative to photolithography in generating patterns on polymeric substrates. The optimization of embossing process should be accomplished based on polymer substrate materials. In this paper, the effect of polymer substrates on nano scale hot embossing process was studied. Silicon molds with nano size patterns were fabricated by e-beam direct writing. Molds were coated with self-assembled monolayer (SAM) of (1, 1, 2.2H -perfluorooctyl)-trichlorosilane to reduce the stiction between mold and substrates. For an embossing, pressure of 55, 75 bur, embossing time of 5 min and temperature of above transition temperature were peformed. Polymethylmethacrylates (PMMA) with different molecular weights of 450,000 and 950,000, MR-I 8010 polymer (Micro Resist Technology) and polyaliphatic imide copolymer were applied for hot embossing process development in nano size. These polymers were spun coated on the Si wafer with the thickness between 150 and 200 nm. The nano size patterns obtained after hot embossing were observed and compared based on the polymer properties by scanning electron microscopy (SEM). The imprinting uniformity dependent on the Pattern density and size was investigated. Four polymers have been evaluated for the nanoimprint By optimizing the process parameters, the four polymers lead to uniform imprint and good pattern profiles. A reduction in the friction for smooth surfaces during demoulding is possible by polymer selection.

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Development of Working Platform for the Polymer Insulator String (송전선로 폴리머애자 공사용 장비 개발)

  • Min, Byeong-Wook;Wi, Shwa-Bok;Bang, Hang-Kwon;Choi, Han-Yeol;Baek, Soo-Gon;Park, Jae-Ung
    • Proceedings of the KIEE Conference
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    • 2006.07a
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    • pp.438-439
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    • 2006
  • Porcelain insulators have generally been used in Korea to insulate a transmission line from the tower, and a highly polymerized compound polymer insulator which has superior stain proof characteristics, has also been used widely. Currently, a worker rides on the suspension insulator string for installation on towers and conductors but in case of polymer insulators, this will pollute and scratch the housing result in durability reduction by deterioration and corona. This study developed a high strength aluminum compound metal lauder designed to work on polymer insulators without riding, and a clamp type connecting device and safety gear for easy installation on the tower and conductor. These polymer insulator work device can be used for 154kV and 345kV polymer insulators through a strength and load test to secure safety. This paper presents field usage.

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