• 제목/요약/키워드: Polymer Composites

검색결과 1,723건 처리시간 0.028초

Effects of E-beam treatment on the interfacial and mechanical properties of henequen/polypropylene composites

  • Cho, Dong-Hwan;Lee, Hyun-Seok;Han, Seong-Ok;Drzal, Lawrence T.
    • Advanced Composite Materials
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    • 제16권4호
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    • pp.315-334
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    • 2007
  • In the present study, chopped henequen natural fibers without and with surface modification by electron beam (E-beam) treatment were incorporated into a polypropylene matrix. Prior to composite fabrication, a bundle of raw henequen fibers were treated at various E-beam intensities from 10 kGy to 500 kGy. The effect of E-beam intensity on the interfacial, mechanical and thermal properties of randomly oriented henequen/polypropylene composites with the fiber contents of 40 vol% was investigated focusing on the interfacial shear strength, flexural and tensile properties, dynamic mechanical properties, thermal stability, and fracture behavior. Each characteristic of the material strongly depended on the E-beam intensity irradiated, showing an increasing or decreasing effect. The present study demonstrates that henequen fiber surfaces can be modified successfully with an appropriate dosage of electron beam and use of a low E-beam intensity of 10 kGy results in the improvement of the interfacial properties, flexural properties, tensile properties, dynamic mechanical properties and thermal stability of henequen/polypropylene composites.

Low Cycle Fatigue of PPS Polymer Injection Welds ( II ) - Fiber Orientation and Fracture Mechanism -

  • Lim, Jae-Kyoo;Song, Jun-Hee
    • Journal of Mechanical Science and Technology
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    • 제17권6호
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    • pp.836-843
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    • 2003
  • The polymer composites contain numerous internal boundaries and its structural elements have different responses and different resistances under the same service environment. Fatigue phenomenon is much more complex in composites than homogeneous materials. An understanding of the fracture behavior of polymer composite materials subjected to constant and cyclic loading is necessary for predicting the life time of structures fabricated with polymers. There is a need to acquire a better understanding of the fatigue performance and failure mechanisms of composites under such conditions. Therefore, in this study the analyses of fiber orientation and fracture mechanism for low cycle fatigue crack have been studied by SEM and LM for observing the ultrathin sections.

탄소나노튜브 복합재를 이용한 고분자 액추에이터의 냉각 개선 (Enhanced Cooling Performance of Polymer Actuators Using Carbon Nanotube Composites)

  • 박성욱;석지원
    • Composites Research
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    • 제30권2호
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    • pp.165-168
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    • 2017
  • 낚싯줄이나 재봉실을 꼬아서 만드는 코일형 고분자 액추에이터는 열을 가하거나 냉각하면 수축하거나 늘어나면서 작동을 하게 된다. 따라서, 코일형 고분자 액추에이터의 동작 속도는 가열 및 냉각 속도에 매우 민감하게 되는 문제가 있다. 코일형 고분자 액추에이터의 동작 속도를 개선하기 위해서, 폴리디메틸실록산 복합재를 액추에이터에코팅하였다. 폴리디메틸실록산에다중벽탄소나노튜브를혼합함으로써, 액추에이터의동작속도를약 13% 개선하였다.

직조된 대나무 자연섬유 복합재료의 제조인자에 따른 굽힘강도 (Bending Strength of Natural Woven Bamboo Fiber-reinforced Polymer Composites with Manufacturing Factors)

  • 송준희;임재규
    • 대한기계학회논문집A
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    • 제30권8호
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    • pp.916-922
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    • 2006
  • In recent years there has been a growing interest for the use of natural fibers in composite applications due to their low cost, environmental friendliness, and good mechanical properties. The purpose of this study is to determine the characteristic of bending strength on bamboo fiber reinforced polymer composites. The parameters of RTM process depend on the weight ratio of bamboo fiber and resin, the number of bamboo ply and amount of hardening agent. Mechanical properties was investigated for each process factor of polymer composites. Test result shows that bending strength was a maximum(approximately 85MPa) value when composite thickness was 6mm and weight ratio of resin was 13%.

고분자 열분해에 의한 $MoSi_2$/SiC 세라믹 복합체 ($MoSi_2$/SiC Ceramic Composites Prepared by Polymer Pyrolysis)

  • 김범섭;김득중;김동표
    • 한국세라믹학회지
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    • 제37권8호
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    • pp.805-810
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    • 2000
  • The formation, microstructure and properties of MoSi2/SiC ceramic composites by polymer pyrolysis were investigated for the application of heating element material. Polymethylsiloxanes were mixed with Si, SiC, MoSi2 as filler and ceramic composites prepared by pyrolysis in N2 atmosphere at 1320~145$0^{\circ}C$ were studied. Dimensional change, density variation and phases were analyzed and correlated to the resulting material properties. Microstructures of ceramic composite prepared by polymer pyrolysis were composed of MoSi2, SiC and silicon oxycarbide glass matrix. Depending on the pyrolysis conditions, ceramic composites with a density of 86~90 TD%, a fracture strength of 213~284 MPa, a thermal expansion coefficient of 4~7$\times$10-6 were obtained. The electrical resistivity of the specimen decreased with increasing of temperature up to 50$0^{\circ}C$.

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Mechanical Properties and Failure Mechanism of the Polymer Composite with 3-Dimensionally Stitched Woven Fabric

  • Lee, Geon-Woong;Park, Joong-Sik;Lee, Sang-Soo;Park, Min;Kim, Junkyung;Choe, Chul-Rim;Soonho Lim
    • Macromolecular Research
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    • 제11권2호
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    • pp.98-103
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    • 2003
  • The mechanical properties and failure mechanisms of through-the-thickness stitched plain weave glass fabric/polyurethane foam/epoxy composites were studied. Hybrid composites were fabricated using resin infusion process (RIP). Stitched sandwich composite increased drastically the flexural properties as compared with the unstitched fabrics. The breaking of stitching yarns was observed during the flexural test and this failure mode yielded relatively high flexural properties. Composites with stitched sandwich structure improved the mechanical properties with increasing the number of stitching yarns. From this study, it was concluded that proper combination of stitching density and types of stitching fiber is important factor for through-the-thickness stitched composite panels.

입자의 크기에 따른 흑연 보강 전도성 고분자 복합재료의 특성 연구 (Effect of particle size on graphite reinforced conductive polymer composites)

  • 허성일;윤진철;오경석;한경섭
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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    • pp.257-260
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    • 2005
  • Graphite reinforced conductive polymer composites were fabricated by the compression molding technique. Graphite powder was mixed with an phenol resin to impart electrical property in composites. The ratio and particle size of graphite powder were varied to investigate electrical conductivity of cured composites. In this study, graphite reinforced conductive polymer composites with high filler loadings(>66wt.%) were manufactured to accomplish high electrical conductivity. With increasing the loading ratio of graphite powder, the electrical conductivity and flexural strength increased. However. above 80wt.% filler loadings, flexural strength decreased due to lack of resin. Regardless of graphite particle size, electrical conductivity wasn’t varied. On the other hand, with decreasing particle size, flexural strength increased due to high specific surface area.

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Preparation and Physical Properties of Poly(lactic acid) Bio-Composites using Surface Modified Microfibriled Celluloses

  • Yeo, Jun-Seok;Seong, Dong-Wook;Hwang, Seok-Ho
    • Elastomers and Composites
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    • 제50권1호
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    • pp.62-67
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    • 2015
  • The surface modification of microfibriled cellulose (MFC) was carried out through the hydrolysis-condensation reaction using (3-aminopropyl)triethoxysilane (APS) and 3-glycidyloxypropyltriethoxysilane (GPS) and then the modified cellulose was compounded with bio-degradable poly(lactic acid) (PLA). Also, pristine MFC was compounded with PLA as a control groups. The confirmation of surface modification for the pristine MFC was characterized by FT-IR and SEM/EDX. The thermal and mechanical properties of the PLA/MFC composites depended on the content of MFC and the type of silane coupling agents. From the thermal, morphological and mechanical behaviors of the PLA/MFC composites, it was found that GPS-MFC was more successful to improve the interface adhesion between PLA matrix and the surface of MFC than that of APS-MFC.

Flexural Behaviors of 4D Carbon/carbon Composites with the Preform Architectures

  • Lee, Ki-Woong;Park, Jong-Min;Joo, Hyeok-Jong
    • Carbon letters
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    • 제9권1호
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    • pp.28-34
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    • 2008
  • Multidirectional reinforcement is aimed primarily at overcoming interlaminar weakness, hence a major interest lies in the mechanical properties of multidirectional carbon/carbon composites. Mechanical properties depend on the type of carbon fiber, the size of the fiber bundle, the spacing of the bundles, the angles of the bundles relative to the axes of the block, and matrix formation. In the present studies, PAN based carbon fiber preforms manufactured different size of unit cell have been prepared. Densification of these used high pressure infiltration and carbonization technique with coal tar pitch as matrix precursor was carried out. Scanning electron microscopy has been used to study the fracture behavior of composites. The size of unit cell of the preforms has considerably affected on the flexural properties as well as microstructure of the carbon/carbon composites.

Thermal Properties of Poly($\varepsilon$-Caprolactone)/Multiwalled Carbon Nanotubes Composites

  • Kim, Hun-Sik;Chae, Yun-Seok;Choi, Jae-Hoon;Yoon, Jin-San;Jin, Hyoung-Joon
    • Advanced Composite Materials
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    • 제17권2호
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    • pp.157-166
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    • 2008
  • In this study, multiwalled carbon nanotubes (MWCNTs) were compounded with the poly($\varepsilon$-caprolactone) (PCL) matrix at the solution state using chloroform. For homogeneous dispersion of MWCNTs in polymer matrix, oxygen-containing groups were introduced on the surface of MWCNTs. The mechanical properties of the PCL/MWCNTs composites were effectively increased due to the incorporation of MWCNTs. The composites were characterized using scanning electron microscopy in order to obtain information on the dispersion of MWCNT in the polymeric matrix. In case of 1.2 wt% of MWCNTs in the matrix, strength and modulus of the composite increased by 12.1% and 164.3%, respectively. In addition, the dispersion of MWCNTs in the PCL matrix resulted in substantial decrease of the electrical resistivity of the composites as the MWCNTs loading was increased from 0 to 2.0 wt%. Furthermore, thermal stability of the PCL and PCL/MWCNTs-COOH composites were investigated using the data acquired from the thermogravimetric analysis. The detailed kinetics of the thermal degradation of the composites was investigated by analyzing their thermal behavior at different heating rates in a nitrogen atmosphere. Activation energy of thermal degradation was determined by using the equations proposed by Kissinger and Flynn-Wall-Ozawa. The apparent activation energy of PCL/MWCNTs-COOH composite was considerably higher than that of neat PCL.