• Title/Summary/Keyword: Polyimide (PI)

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A study on the synthesis and characterization of PI/$\textrm{TiO}_2$ nano-composite (폴리이미드/$\textrm{TiO}_2$ 나노 복합재의 합성 및 특성에 관한 연구)

  • 이중희;이봉신;허석봉
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.137-140
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    • 2001
  • Oragnic/inorganic hybrid materials prepared by sol-gel method have rapidly become a fasci nating research field in materials science. In this study, Polyimide/$\textrm{TiO}_2$ composites were synthesized from nano-sized anatase $\textrm{TiO}_2$ and two types of Polyimide (BTDA-PPD, PMDA-ODA) by Sol-gel method. Nano-sized $\textrm{TiO}_2$ particles were prepared from $\textrm{TiOEt}_4$ solution. The composites were charcaterized by using XRD, TGA, IR, TEM, and Atomic Force Microscope(AFM). $\textrm{TiO}_2$ nano particles were dispersed well in polyimide matrix and the thermal stability of polyimide was improved with $\textrm{TiO}_2$ nano-sized particles.

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Effect of the Molecular Structure of Rubbed Polyimide Films for Surface Liquid Crystal Alignment of Nematic Liquid Crystal (네마틱 백정의 표면 액정 배향에관한 폴리이미드막의 분자 구조의 효과)

  • 서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.232-234
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    • 1996
  • We have investigated the effect of molecular structure of polymer of rubbed polyimide (PI) films for surface liquid crystal alignment. To obtain surface alignment effect of Polymer molecular structure, we measured the polar (out of plane-tilt) anchoring strength and surface ordering of 5CB on rubbed PI surfaces. We have found that the polar anchoring strength of 5CB is depend on the polymer molecular structure of these unidirectionally rubbed PI surfaces.

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No-bias-bend pi cell using the rubbed polyimide mixture

  • Kim, Dae-Hyeon;Park, Hong-Gyu;Kim, Yeong-Hwan;Kim, Byeong-Yong;Ok, Cheol-Ho;Han, Jeong-Min;Seo, Dae-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.186-186
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    • 2009
  • Most liquid crystal display modes, including the twisted nematic (TN) $mode^1$, the in-plane switching (IPS) $mode^2$, the fringe field switching (FFS) $mode^3$, and the vertically aligned (VA) $mode^4$ are based on either a horizontal or a vertical alignment. However, for some applications, such as no-bias-bend (NBB) pi cell or bistable bend-splay display, an intermediate pretilt angle is essential$^5$. NBB pi cells have been a focus of interest because of their fast response time; however, the reliable control of the intermediate pretilt angle of liquid crystals that is required for the fabrication of NBB pi cells is challenging. The controllable pre-tilt angle of liquid crystals was investigated using a blend of horizontal and vertical polyimide prepared by a rubbing method. Various pretilt angles in the range from 0^{\circ}$ to 90^{\circ}$ were achieved as a function of the vertical polyimide content. We observed uniform liquid crystal alignment on the rubbing-treated blended polyimide layer. A NBB pi cell with an intermediate pretilt angle of 47.8^{\circ}$ was manufactured. This cell had no initial bias voltage and a low threshold voltage, which indicates that it has low power consumption. In addition, the response time of the NBB pi cell was rapid.

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Electro-optical Characteristics of Twisted Nematic(TN)-LCD using New Ion Beam Equipment (새로운 이온빔장치를 사용한 Twisted Nematic-LCD의 전기광학특성)

  • Kim Sang-Hoon;Hwang Jeoung-Yeon;Jang Mi-Hye;Kim Gwi-Yeol;Seo Dae-Shik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.547-551
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    • 2006
  • We studied liquid crystal (LC) alignment with ion beam (IB) on polyimide and electro-optical characteristics of twisted nematic (TN)-liquid crystal display (LCD) on the polyimide surface using obliquely ion beam (IB) exposure with new IB type equipment. A good uniform alignment of the nematic liquid crystal (NLC) alignment with the ion beam exposure on the polyimide surface was observed. In addition, it can be achieved the good EO properties of the ion-beam-aligned TN-LCD on polyimide surface. Also, the EO characteristics of the ion-beam-aligned TN-LCD on a polyimide (PI) surface with ion beam exposure using new type IB equipment is same or more superior than ion-beam-aligned TN-LCD on a polyimide (PI) surface with ion beam exposure using Kaufman-type Ar ion gun.

EO Characteristics in the Vertical Alignment (VA)-$\pi$ mode LCD Using the Tilt Angle Decrease Effect on the Blended Polymer (혼합된 polymer에서의 틸트 감소 효과를 이용한 VA-$\pi$ mode LCD의 전기광학 특성)

  • Lee, Kyung-Jun;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05d
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    • pp.53-56
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    • 2003
  • Blending effects for generating a pretilt angle in nematic liquid crystal (NLC) with negative dielectric anisotropy on the blended polyimide (PI) of homeotropic and homogeneous alignment surface were studied. Also, we investigated the EO performances for the advanced VA-$\pi$ cell using this homeotropic blended PI surface. A many decrease of tilt angle on the polymer surface to blend homeotropic PI and homogeneous PI with side chain type was measured, and the tilt angle decreased as blended ratio and rubbing strength increase. The blended effects for generating a pretilt angle were clearly observed, and the many decrease of tilt angle can be achieved by using the blended PI surface. The electro-optical (EO) characteristics using the advanced VA-$\pi$ cell using the homeotropic blended PI surface than that of conventional VA cell can be improved. We suggest that the developed advanced VA-$\pi$ cell on a homeotropic blended PI surface is a promising technique for the achievement of a fast response time, and a high contrast ratio.

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EO Characteristics in the Advanced Vertical Alignment VA-$\pi$ Cell on a Homeotropic Blended Polymer (수직 복합 폴리머 표면을 이용한 Advanced VA-$\pi$ cell의 전기광학 특성)

  • Lee, Kyung-Jun;Hwang, Jeoung-Yeon;Hahn, Eun-Joo;Paek, Seung-Kwon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.530-533
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    • 2002
  • Blending effects for generating a pretilt angle in nematic liquid crystal (NLC) with negative dielectric anisotropy on the blended polyimide (PI) of homeotropic and homogeneous alignment surface were studied. Also, we investigated the EO performances for the advanced VA-$\pi$ cell using this homeotropic blended PI surface. A many decrease of tilt angle on the polymer surface to blend homeotropic PI and homogeneous PI with side chain type was measured, and the tilt angle decreased as blended ratio and rubbing strength increase. The blended effects for generating a pretilt angle were clearly observed, and the many decrease of tilt angle can be achieved by using the blended PI surface. The electro-optical (EO) characteristics using the advanced VA-$\pi$ cell using the homeotropic blended PI surface than that of conventional VA cell can be improved. We suggest that the developed advanced VA-$\pi$ cell on a homeotropic blended PI surface is a promising technique for the achievement of a fast response time, and a high contrast ratio.

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Control of Tilt Angle on Homeotropic Polyimide Surface by Ion Beam Alignment (이온빔 배향을 이용한 수직 폴리이미드 표면에서의 틸트 각 제어)

  • Kang, Dong-Hun;Kim, Byoung-Yong;Kim, Sang-Hoon;Hwang, Jeoung-Yeon;Han, Jin-Woo;Kim, Jong-Hwan;Kang, Hee-Jin;Ok, Chul-Ho;Oh, Yong-Cheul;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.288-289
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    • 2006
  • The tilt angle generation of nematic liquid crystal(NLC) on the homeotropic polyimide(PI) surface by the new Ion beam alignment method is studied. The tilt angle of NLC on the homeotropic PI surface for all incident angle is about 38and this has a stabilization trend. And the good LC alignment of the NLC on the PI surface by ion beam exposure of 45Incident angle was observed. Also the tilt angle of NLC on the homeotropic PI surface by ion beam exposure of 45Incident angle had a tendency to decrease as ion beam energy density increase. So we had known that pretilit angle could be controlled from verticality to horizontality.

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Synthesis and Properties of Polyimide Composites Containing Graphene Oxide Via In-Situ Polymerization

  • Zhu, Jiadeng;Lee, Cheol-Ho;Joh, Han-Ik;Kim, Hwan Chul;Lee, Sungho
    • Carbon letters
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    • v.13 no.4
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    • pp.230-235
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    • 2012
  • In this study, reduced graphene oxide/polyimide (r-GO/PI) composite films, which showed significant enhancement in their electrical conductivity, were successfully fabricated. GO was prepared from graphite using a modified Hummers method. The GO was used as a nanofiller material for the preparation of r-GO/PI composites by in-situ polymerization. An addition of 20 wt% of GO led to a significant decrease in the volume resistivity of composite films by less than nine orders of magnitude compared to that of pure PI films due to the electrical percolation networks of reduced GO created during imidization within the films. A tensile test indicated that the Young's modulus of the r-GO/PI composite film containing 20 wt% GO increased drastically from 2.3 GPa to 4.4 GPa, which was an improvement of approximately 84% compared to that of pure PI film. In addition, the corresponding tensile strength was found to have decreased only by 12%, from 113 MPa to 99 MPa.

Electro-optical Characteristics of the One-side Rubbing TN-LCD on Polyimide Surface with Ion-beam Irradiation

  • Kim, Young-Hwan;Lee, Kang-Min;Kim, Byoung-Yong;Oh, Byeong-Yun;Han, Jeong-Min;Lee, Sang-Keuk;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.5
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    • pp.198-201
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    • 2008
  • The electro-optical (EO) characteristics of the one-side rubbing twisted nematic (TN) - liquid crystal display (LCD) on the polyimide (PI) surface with one-side ion beam (IB) irradiation were successfully studied. The good LC alignment for the one-side rubbing TN-LCD on the PI surface with one-side IB irradiation was observed. The suitable transmittance-voltage curves for the one-side rubbing TN-LCD on the PI surface with one-side IB irradiation were measured. Also, the good response time characteristics of the one-side rubbing TN-LCD on the PI surface with one-side IB irradiation were measured. The fast response time can be achieved for the one-side rubbing TN-LCD on the PI surface with one-side IB irradiation.

Electro-Optical Characteristics of Plastic STN Cell using photoalignment method (광배향을 이용한 플렉시블 STN 셀의 전기 광학 특성)

  • Bae, Yu-Han;Hwang, Jeoung-Yeon;Kim, Jong-Hwan;Nam, Ki-Hyung;Lee, Whee-Won;Kim, Kang-Woo;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1007-1009
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    • 2004
  • We investigated the electro-optical(EO) performances of the super twisted nematic liquid crystal display(STN-LCD) on the polyimide(PI) surface with polymer film using rubbing and photoalignment method. Monodomain alignment of the plastic STN-LCD can be observed. A faster response time for the photoaligned plastic STN-LCD on the polyimide(PI) surfaces can be achieved than rubbingaligned plastic STN-LCD.

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