• Title/Summary/Keyword: Polyethylene terephthalate

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A Study on Dyeability of Polyester Fabrics Grafted with Methacrylic Acid (MA 그라프트 폴리에스테르직물의 염색성에 관한 연구)

  • Baik, Chun-Eui;Cho, Seung-Sik;Song, Hwa-Sun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.6
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    • pp.946-954
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    • 1995
  • The purpose of this study is to modify the hydrophobic property and dyeability of polyethylene terephthalate fiber. Methacrylic acid (2nA) was graftpolymerized with benzoyl peroxide (BPO) as initiator onto polyethylene terephthalate fabrics. The results were as follow; 1. Graft-polymerization exhibited maximum graft ratio at a temperature of 100"C. 2. The polymer was gradually grafted in great amount to the surface of MA-g-PET as graft ration increase; with the cross-section examination of MA-g-PET, it was discovered that graft-polymeriation had also taken place inside the textile core. 3. Dyes absorption of basic dyes and disperse dyes was improved as craft ratio increase; with resistance to laundering, the former showed grade 3-4 and the latter showed grade 5.de 5.

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A Study on Electricity Properties of Polyethylene Terephthalate Film due to Thermally Degradation (열 열화에 의한 폴리에틸렌 테레프탈레이트 필름의 전기 특성에 관한 연구)

  • Lee, Sung Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.11
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    • pp.693-698
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    • 2017
  • In this study, the thermal degradation properties of polyethylene terephthalate film has been examined by the capacitance, Tan ${\delta}$, thermography, FTIR, and SEM results at temperatures of $90{\sim}170^{\circ}C$ and frequencies of 0.3~3,000 kHz. It was found that the capacitance decreased with increasing thermal imaging temperature, probably caused by weakening of chemical bond with increasing temperature. Tan ${\delta}$ decreased upon increasing temperature from $90^{\circ}C$ to $170^{\circ}C$, probably due to the molecular motion of COOH radical or OH radical. The FT-IR measurement reveals that no structural change of the material occurs upon thermal radiation. The SEM measurement shows that the material is stabilized by thermal decomposition with increasing temperature; however, excessive thermal degradation obstructs the stabilization of the material.

RF Bias Effect of ITO Thin Films Reactively Sputtered on PET Substrates at Room Temperature

  • Kim, Hyun-Hoo;Shin, Sung-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.3
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    • pp.122-125
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    • 2004
  • ITO films were deposited on polyethylene terephthalate substrate by a dc reactive magnetron sputtering using rf bias without substrate heater and post-deposition thermal treatment. The dependency of rf substrate bias on plasma sputter processing was investigated to control energetic particles and improve ITO film properties. The substrate was applied negative rf bias voltage from 0 to -80 V. The composition of indium, tin, and oxygen atoms is strongly depended on the rf substrate bias. Oxygen deficiency is the highest at rf bias of -20 V. The electrical and optical properties of ITO films also are dominated obviously by negative rf bias.

Crack Resistance Properties of Fiber Reinforced Concrete with Recycled PET Fiber (재생 PET 섬유가 혼입된 섬유 보강 콘크리트의 균열저항특성)

  • Kim, Sung-Bae;Kim, Hyun-Young;Yi, Na-Hyun;Kim, Jang-Jay-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.545-546
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    • 2009
  • This study was performed to prove the possibility of utilizing short plastic fibers made for recycled polyethylene terephthalate (RPET) as a structural material. To measure of crack control capacity, restrained drying shrinkage cracking test was performed. In order to verify the capacity of RPET fiber, it was compared with poly propylene (PP) fiber, most widely used short synthetic fiber, for fiber volume fraction of 0%, 0.5%, 0.75%, and 1.0%.

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Fiber surface and electrical conductivity of electroless Ni-plated PET ultra-fine fibers

  • Choi, Woong-Ki;Kim, Byung-Joo;Park, Soo-Jin
    • Carbon letters
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    • v.14 no.4
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    • pp.243-246
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    • 2013
  • In this work, electroless Ni-plating on polyethylene terephthalate (PET) ultra-fine fibers surfaces was carried out to improve the electric conductivity of the fiber. The surface properties of PET ultra-fine fibers were characterized using scanning electron microscopy, X-ray diffraction, and contact angle analyses. The electric conductivity of the fibers was measured using a 4-point testing method. The experimental results revealed the presence of island-like nickel clusters on the PET ultra-fine fibers surfaces in the initial plating state, and the electric conductivity of the Ni-plated fibers was enhanced with increasing plating time and thickness of the Ni-layers on the PET ultra-fine fibers.

Thickness Effect of Double Layered Sheet on Burr Formation during Micro-Via Hole Punching Process (미세 비아홀 펀칭 공정 중 이종 재료 두께에 따른 버 생성)

  • 신승용;임성한;주병윤;오수익
    • Transactions of Materials Processing
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    • v.13 no.1
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    • pp.65-71
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    • 2004
  • Recent electronic equipment becomes smaller, more functional, and more complex. According to these trends, LTCC(low temperature co-fired ceramic) has been emerged as a promising technology in packaging industry. It consists of multi-layer ceramic sheet, and the circuit has 3D structure. In this technology via hole formation plays an important role because it provides an electric path for the packaging interconnection network. Therefore via hole qualify is very important for ensuring performance of LTCC product. Via holes are formed on the green sheet that consists of ceramic(before sintering) layer and PET(polyethylene terephthalate) one. In this paper we found the correlation between hole quality and process condition such as PET thickness and ceramic thickness. The shear behavior of double layer sheet by micro hole punching which is different from that of single layer one was also discussed.

Temperature Dependence of Optical Properties on Polymer Materials (폴리머 재료에서의 광학적 물성의 온도의존성)

  • 정승묵;신영곤;이상훈;송국현;김영진;이낙규;나경환
    • Journal of the Semiconductor & Display Technology
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    • v.3 no.4
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    • pp.5-11
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    • 2004
  • Optical properties of PET(Polyethylene terephthalate), PC(Polycarbonate), Acrylic resin and PE(Polyethylene) sheets were studied as a function of heat treating temperature of $60^{\circ}C$ to $150^{\circ}C$. By the heat treatment, optical properties of transmittance, absorbance, and reflectance showed a considerable change with different ways according to the materials. To understand the reason of optical property change, X-ray diffraction and surface morphology were also investigated. It was observed that small crystallite and pore that can cause scattering largely affect the transmittance. It was suggested that change of surface chemical bond induce the reflectance variation.

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Treatment and Characterization of Polyethylene Terephthalate Fibers with Silicone Rubber Adhesive for Heat-Resistant Adhesion (실리콘 고무와 내열접착 향상을 위한 Polyethylene Terephthalate 섬유 접착층의 제조 및 특성)

  • Kim, Jihyo;Lee, Sangoh;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.31 no.2
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    • pp.107-117
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    • 2019
  • In case of pure rubber materials, the initial quality of the rubber materials would be excellent, however, the durability against external impact might be poor. In order to overcome the relatively low durability, textile cord could be employed with silicone rubber. We have studied the improvement of heat-resistant adhesion properties of silicone adhesives between silicone rubber and PET fibers by applying various conditions including dip solution recipe. The silicone rubber used was a platinum catalyst curing type and platinum catalyst type silicone adhesive was used as an adhesive to obtain an optimum adhesive force. Furthermore, the bonding mechanism between silicone and PET fiber was established.

Production of PBT(polybutylene terephthalate) Oligomer from Recycled PET(polyethylene terephthalate) (재활용 PET(polyethylene terephthalate)를 이용한 PBT(polybutylene terephthalate) 올리고머 제조)

  • Cho, Minjeong;Yang, Jeongin;Noh, Seunghyun;Joe, Hongjae;Han, Myungwan
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.437-442
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    • 2016
  • A new route for PBT (Poly butylene terephthalate) production from recycled PET (Poly ethylene terephthalate) has been explored. The route consists of glycolysis of PET (Poly ethylene terephthalate) wastes using 1,4-butandiol into BHBT oligomers and polycondensation of the oligomers into PBT oligomer. This process uses post-consumer or post-industrial recycled PET and converts it into high-end PBT type engineering thermoplastic via a chemical recycling process. Zink acetate was used as a catalyst for both glycolysis and polycondensation. Two types of reactor for the glycolysis, batch and semi-batch reactor, were investigated and their performances were compared. Semi-batch reactor removes ethylene glycol (EG) and THF (tetrahydrofuran) during the reaction. Amounts of EG and THF generated during the glycolysis reaction were measured and used as criteria for the reactor performance. Performance of semi-batch reactor was shown to be better than that of batch reactor. Optimum reaction condition for the semi-batch reactor was BD/PET ratio of 4, and reaction temperature of $220^{\circ}C$, giving high EG yield (max 91%) and low production of THF. In addition, it was confirmed that the molecular weight of PBT oligomer increases in accordance with the progress of the polycondensation reaction.