• Title/Summary/Keyword: Polyethylene terephthalate(PET)

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전해수 특성 및 전해수와 초음파를 이용한 PET의 가수분해

  • 최용철;홍영기;채경수;배기서
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2003.04a
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    • pp.144-148
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    • 2003
  • 현재 섬유 분야에서 많은 부분을 차지하고 있는 폴리에틸렌테레프탈레이트(Polyethylene terephthalate, PET) 섬유는 강도, 혼방성, 내열성 등이 우수한 반면, 염색성, 필링성, 흡습성, 대전성 등의 결점들을 가지고 있어 이러한 단점들을 개선하려는 연구가 현재까지 지속적으로 진행되어 오고 있다 PET의 개질 방법 가운데 촉감개선을 위한 알칼리 감량 가공은 영국에서 처음으로 시도되었고, 1970년대 중반 이후 일본에서 공업화시켰으며 현재에도 가장 널리 사용되고 있는 방법 중의 하나이다. (중략)

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Molecular Composite of Cellulose Triacetate and Polyester (I) - Solution Property- (셀루로오즈 트리아세테이트와 폴리에스테르의 분자복합체(I) -용액 성질-)

  • Hong, Young-Keun
    • Textile Coloration and Finishing
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    • v.3 no.4
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    • pp.17-21
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    • 1991
  • A rigid polymer, cellulose triacetate (CTA) dissolved in a combination of trifluoroacetic acid (TFA) and methylene chloride (MC) solution are liguid crystalline above a certain concentration. A flexible polymer, polyethylene terephthalate (PET) also dissolves in TFA/MC, but does not form liguid crystal phase. Ternary solutions, CTA/PET/TFA-MC which CTA and PET were mixed in a same solvent TFA/MC (6/4 : v/v) showed phase separation and mesophase formation.

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The Effects of Polar Compounds on the Rate of Dye Exhaustion in Solvent Dyeing (용제염색에서 극상 화합물이 염착속도에 미치는 영향)

  • 이대수;안태환
    • Textile Coloration and Finishing
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    • v.2 no.1
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    • pp.21-30
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    • 1990
  • In order to obtain high dye uptake initially, polyethylene terephthalate (PET) filaments were dyed with C.I.Disperse Orange 3 and Red 1 in mixed solvents of tetrachloroethylene acidic solvent, ethyl alcohol and tetrachloroethylene basic solvent, DMF. The dyeing behavior in the mixed solvent of tetrachloroethylene and basic solvent, DMF, the initial uptake of disperse dyes increased rapidly. The shrinkage of PET increased when the solubility parameter values of PET fiber and mixed solvent approached graduately.

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Chemical Recycling Technology from Polyester Wastes (폴리에스터 폐자원의 화학적 재활용기술)

  • Han, Myung-Wan;Kang, Kyung-Suk;Song, Jae-Kyung
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.96-103
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    • 2012
  • This paper reviews recent technologies for recycling poly (ethylene terephthalate) wastes. Wide application and non-biodegradability of the PET creates huge amounts of waste and disposal, leading to an environmental problem and economic loss. Chemical recycling can be a promising technology to deal with these problems by converting the waste into useful feedstock material for polyester production. Chemical recycling of polyethylene terephthalate are processes where the PET polymer chain is destructed by the impact of glycol (MEG) causing glycolysis, methanol causing methanolysis or water causing hydrolysis. After intensive purification polyester oligomers or the monomers MEG, dimethyl telephthalate (DMT) or purified terephthalic acid (PTA) are received which are re-used to produce polyester products.

Physical and mechanical properties of cement mortar with LLDPE powder and PET fiber wastes

  • Benimam, Samir;Bentchikou, Mohamed;Debieb, Farid;Kenai, Said;Guendouz, Mohamed
    • Advances in concrete construction
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    • v.12 no.6
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    • pp.461-467
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    • 2021
  • Polyethylene-terephthalate (PET) from bottle waste and linear low-density polyethylene (LLDPE) from barrels and tanks waste are widely available and need to be recycled. Recycling them in concrete and mortar is an alternative solution for their disposal. In this study various quantities of sand (5%, 10%, 15% and 20%) were substituted by powder from LLDPE waste. In addition, PET waste fibers (corrugated, straight) were added to the mortar with different percentages (0.5%, 1%, 1.5% and 2%) of cement mass. This paper evaluate the mechanical and physical properties of the composites in fresh (workability, air content and density) and hardened state (compressive and flexural strength, water absorption and total shrinkage). From the experimental results, it can be concluded that the strengthening in tensile of the mortar with plastic waste corrugated fibers is improved. Other important results are that the water absorption and the density rate are less than that of the ordinary mortar.

Dielectric Properties and Breakdown Strength in Insulation/Semiconductive/Insulation (절연/반도전/절연층에 있어서 유전특성과 절연파괴 현상)

  • 강대용;오광영;김용주;박대회
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.163-166
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    • 1998
  • In this paper, breakdown strength and dielectric characteristics were experimented in the structures of insulation/insulation/insulation and insulation/semiconductor/insulation by using of insulation material of polyethylene terephthalate film. The breakdown strength and the permitivity of each specimen were measured as a function of temperature and frequency respectively. The breakdown strength of PET/PET/PET did not changed greatly but that of PET/SEMl/PEr increased as a function of temperature. As the frequency inclosed, the permitivity of PET/PET/PET and PET/SEMI/PET decreased. The tan $\delta$ of PET/PET/PET showed lower than that of PET/SEMl/PET in low frequency but higher in high frequency .

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Surface treatment of polyethylene terephthalate films by corona discharge (코로나방전에 의한 polyethylene terephthalate 필름의 표면처리)

  • 김명룡
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.316-323
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    • 1995
  • A vital step in magnetic tape manufacturing is the surface modification of polymer substrate prior to ink application. A critical element for good adhesion of magnetic ink on polymeric substrate is the ability to join ink in cost-effective manner. Corona discharging is one of the effective methods of modifying polymer surface to improve adhesion while maintaining the desirable properties of the film itself. Surface treatment by corona which is exposure of film surface to electron or ion bombardment, rather than mere exposure to active species, like atomic oxygen or ozone, can enhance adhesion by removing contaminant, electret, roughening surface, and/or introducing reactive chemical groups. Reactive neutrals, ions, electron and photons generated during the corona treatment interact simultaneously with polymers to alter surface chemical composition, wettability, and thus film adhesion. However, it is highly recommended that extensive chains scission be avoided because it can lead to side-effect by forming sticky matter, resulting in dropouts. This paper reviews principles of surface preparation of polymer substrate by corona discharging. In addition, the experimental section provides a description of parameter optimization on corona discharging treatment and its side-effect. Experimental results are discussed in terms of surface wetting as determined by contact angle measurements.

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Volume Resistivity Properties of Polyethylene Terephthalate Film due to Temperature Variation (온도변화에 따른 폴리에틸렌텔레프탈레이트 박막의 체적고유저항 특성)

  • Youn, J.I.;Ko, K.Y.;Shin, H.T.;Shin, J.Y.;Lee, C.H.;Hong, J.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.224-227
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    • 2002
  • In this paper, we have investigated the physical properties and electrical conduction properties of polyethylene terephthalate film due to temperature variation, and the measurement of volume resistivity used to highmegohm meter is measured from 1 to 10 minutes when the specimen applied the voltage accroding to the step voltage appling method. From FT-IR spectrum as an analysis of physical properties, the strong absorption in wavenumbers $1019[cm^{-1}]$, $1266[cm^{-1}]$ and $1752[cm^{-1}]$ observed by the C=O and benzene ring. From the analysis of DSC, the crystalline melting points of the specimen observed in the temperature $80[^{\circ}C]$ and $263[^{\circ}C]$, respectively.

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The excimer laser ablation of PET for micro-mold insert - The control of cross sectional shape using Fourier optics - (마이크로 금형 제작을 위한 PET의 엑시머 레이저 어블레이션 - 퓨리에 광학을 이용한 가공 단면 형상의 제어 -)

  • Shin, Dong-Sik;Lee, Je-Hoon;Seo, Jung;Kim, Do-Hoon
    • Laser Solutions
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    • v.6 no.3
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    • pp.19-28
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    • 2003
  • The manufacturing process for the microfluidic device can include sequential steps such as master fabrication, electroforming, and injection molding. The laser ablation, using masks, has been applied to the fabrication of channels in microfluidic devices. In this research, an excimer laser was used to engrave microscopic channels on the surface of PET (polyethylene terephthalate), which shows a high absorption ratio for an excimer laser beam with a wavelength of 248 m. When 50-${\mu}{\textrm}{m}$-wide rectangular microscopic channels are ablated with a 500 ${\times}$ 500 ${\mu}{\textrm}{m}$ square mask at a magnification ratio of 1/10, ditch-shaped defects were found in both corners. The measurement of laser beam intensity showed that a coherent image in the PET target caused such defects. Analysis based on the Fourier diffraction theory enabled the prediction of the coherent shape at the image surface as well as the diffraction beam shape between the mask and the image surface. It also showed that the diameter of the aperture had a dominant effect. The application of aperture with a diameter of less than 3 mm helped to eliminate such defects in the ablated rectangular microscopic channels on PET without such ditch-shaped defects.

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