• Title/Summary/Keyword: Polyethylene terephthalate(PET)

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Crystallization Behavior of PET Modified by Pentanediol units (Pentanediol unit로 개질된 PET의 결정화 거동)

  • Lee, Sun-Hui;Sim, Mi-Ja;Kim, Sang-Wook
    • Korean Journal of Materials Research
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    • v.2 no.2
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    • pp.101-109
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    • 1992
  • Polyethylene terephthalate(PET) is a well known commercial polymer widely available as fibre and as a major polymer with diverse applications. In this experiment, for the modification of PET, the pentanediol isomers, 1,5-pentanediol(1,5-PD) and neopentyl glycol(NPG), were introduced as third monomers. Crystallization rate decreased by the added NPG of PET modified by NPG units. In the case of PET modified by 1,5-PD, crystallization rate had been slightly increased at all temperatures until the 1,5-PD was added about 10 mol%. The decreased crystallization rate is thought to be due to branched from methyl group of neopentyl, which greatly retards the crystallization by growing onto the crystal surface of the diffused polymer chain.

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Transient Behaviors of ZnO Thin Films on a Transparent, Flexible Polyethylene Terephthalate Substrate

  • Kim, Yongjun;Lee, Hoseok;Yi, Junsin;Noh, Jinseo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.179.1-179.1
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    • 2015
  • Thickness-dependent electrical, structural, and optical properties of zinc oxide (ZnO) thin films on polyethylene terephthalate (PET) substrates were investigated in the very thin thickness range of 20 to 120 nm. A very unusual transition phenomenon, in which electrical resistance increases with an increase in film thickness, was observed. From structural and compositional analyses, this transition behavior was explained to arise from metallic Zn agglomerates dispersed in non-crystalline Zn-O matrix. It was unveiled that film thickness more than 80 nm is required for the development of hexagonal crystal structure of ZnO. ZnO films on PET substrates exhibited high optical transmittance and good mechanical flexibility in the thickness range. The results of this study would provide a valuable guideline for the design of ZnO thin films on organic substrates for practical applications.

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Thickness Effect of Double Layered Sheet on Burr Formation during Micro-Via Hole Punching Process (미세 비아홀 펀칭 공정 중 이종 재료 두께에 따른 버 생성)

  • 신승용;임성한;주병윤;오수익
    • Transactions of Materials Processing
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    • v.13 no.1
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    • pp.65-71
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    • 2004
  • Recent electronic equipment becomes smaller, more functional, and more complex. According to these trends, LTCC(low temperature co-fired ceramic) has been emerged as a promising technology in packaging industry. It consists of multi-layer ceramic sheet, and the circuit has 3D structure. In this technology via hole formation plays an important role because it provides an electric path for the packaging interconnection network. Therefore via hole qualify is very important for ensuring performance of LTCC product. Via holes are formed on the green sheet that consists of ceramic(before sintering) layer and PET(polyethylene terephthalate) one. In this paper we found the correlation between hole quality and process condition such as PET thickness and ceramic thickness. The shear behavior of double layer sheet by micro hole punching which is different from that of single layer one was also discussed.

Treatment and Characterization of Polyethylene Terephthalate Fibers with Silicone Rubber Adhesive for Heat-Resistant Adhesion (실리콘 고무와 내열접착 향상을 위한 Polyethylene Terephthalate 섬유 접착층의 제조 및 특성)

  • Kim, Jihyo;Lee, Sangoh;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.31 no.2
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    • pp.107-117
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    • 2019
  • In case of pure rubber materials, the initial quality of the rubber materials would be excellent, however, the durability against external impact might be poor. In order to overcome the relatively low durability, textile cord could be employed with silicone rubber. We have studied the improvement of heat-resistant adhesion properties of silicone adhesives between silicone rubber and PET fibers by applying various conditions including dip solution recipe. The silicone rubber used was a platinum catalyst curing type and platinum catalyst type silicone adhesive was used as an adhesive to obtain an optimum adhesive force. Furthermore, the bonding mechanism between silicone and PET fiber was established.

Manufacture of Environmentally-friendly Flame-retardant Paper with Polyethylene Terephthalate (PET) Short Cut Fiber (PET 섬유를 사용한 친환경 난연지 제조방법에 대한 연구)

  • Kim, Ji-Seop;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.14-20
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    • 2012
  • In this paper, the flame-retardant wall paper was successfully prepared with recycled polyethylene terephthalate (PET) short cut fiber with flame-retardant property and wood pulp using polyvinyl alcohol (PVA) as binder followed by treatment of non-halogen flame retardant. Physical properties such as formation index, tensile strength, elongation, and burst strength increased as defibrillation increased except tear strength. Bulk increased but formation index, tensile strength, elongation and burst strength decreased along with addition of PET short cut fiber. It was also found that tear strength rose significantly up to 30% of PET short cut fiber and then declined (fell) rapidly. As addition level of PVA increased tensile strength, elongation and burst strength increased, but tear strength decreased slightly. Addition of 20% of PET short cut fiber and 13% of PVA provided the flame-retardant wall paper with both improved flameproofing and physical properties.

Characteristics of flexible indium tin oxide electrode grown by continuous roll-to-roll sputtering process for flexible displays

  • Choi, Kwang-Hyuk;Cho, Sung-Woo;Jeong, Jin-A;Kim, Han-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.605-608
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    • 2008
  • The preparation and characteristics of flexible indium tin oxide electrodes grown on polyethylene terephthalate (PET) substrates using a specially designed roll-to-roll sputtering system for use in flexible optoelectronics In spite of low a PET substrate temperature, we can obtain the flexible electrode with a sheet resistance of 47.4 ohm/square and an average optical transmittance of 83.46 % in the green region of 500~550 nm wavelength. Both x-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) analysis results showed that all flexible ITO electrodes grown on the PET substrate were an amorphous structure with a very smooth and featureless surface, regardless of the Ar/$O_2$ flow ratio due to the low substrate temperature, which is maintained by a cooling drum. In addition, the flexible ITO electrode grown on the Ar ion beam treated PET substrates showed more stable mechanical properties than the flexible ITO electrode grown on the wet cleaned PET substrate, due to an increased adhesion between the flexible ITO and the PET substrates.

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Behaviour of recycled aggregate concrete beam-column connections in presence of PET fibers at the joint region

  • Marthong, Comingstarful
    • Computers and Concrete
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    • v.21 no.6
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    • pp.669-679
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    • 2018
  • In this paper the behavior of reinforced concrete (RC) beam-column connections under cyclic loading was analyzed. The specimens, manufactured in a reduced-scale were made of (a) recycled aggregate concrete (RAC) by replacing 30% of natural coarse aggregate (NCA) with recycled coarse aggregate (RCA) and (b) RAC incorporating Polyethylene terephthalate (PET) fiber i.e., PET fiber-reinforced concrete (PFRC) at the joint region. PET fiber (aspect ratio=25) of 0.5% by weight of concrete used in the PFRC mix was obtained by hand cutting of post-consumer PET bottles. A reference specimen was also prepared using 100% of NCA and subjected to similar loading sequence. Comparing the results the structural behavior under cyclic loading of RAC specimens are quite similar to the reference specimens. Damage tolerance, load resisting capacity, stiffness degradation, ductility, and energy dissipation of the RAC specimens enhanced due to addition of PET fibers at the joint region. PFRC specimens also presented a lower damage indices and higher principal tensile stresses as compared to the RAC specimens. The results obtained gave experimental evidence on the feasibility of RAC for structural use. Using PET fibers as a discrete reinforcement is recommended for improving the seismic performance of RAC specimens.

Recent Advances in the Chemobiological Upcycling of Polyethylene Terephthalate (PET) into Value-Added Chemicals

  • Joyce Mudondo;Hoe-Suk Lee;Yunhee Jeong;Tae Hee Kim;Seungmi Kim;Bong Hyun Sung;See-Hyoung Park;Kyungmoon Park;Hyun Gil Cha;Young Joo Yeon;Hee Taek Kim
    • Journal of Microbiology and Biotechnology
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    • v.33 no.1
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    • pp.1-14
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    • 2023
  • Polyethylene terephthalate (PET) is a plastic material commonly applied to beverage packaging used in everyday life. Owing to PET's versatility and ease of use, its consumption has continuously increased, resulting in considerable waste generation. Several physical and chemical recycling processes have been developed to address this problem. Recently, biological upcycling is being actively studied and has come to be regarded as a powerful technology for overcoming the economic issues associated with conventional recycling methods. For upcycling, PET should be degraded into small molecules, such as terephthalic acid and ethylene glycol, which are utilized as substrates for bioconversion, through various degradation processes, including gasification, pyrolysis, and chemical/biological depolymerization. Furthermore, biological upcycling methods have been applied to biosynthesize value-added chemicals, such as adipic acid, muconic acid, catechol, vanillin, and glycolic acid. In this review, we introduce and discuss various degradation methods that yield substrates for bioconversion and biological upcycling processes to produce value-added biochemicals. These technologies encourage a circular economy, which reduces the amount of waste released into the environment.

COMBUSTION KINETICS OF POLYETHYLENE TEREPHTHALATE

  • Oh, Sea-Cheon;Lee, Dong-Gyu;Kwak, Hyun;Bae, Seong-Youl
    • Environmental Engineering Research
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    • v.11 no.5
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    • pp.250-256
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    • 2006
  • The combustion kinetics of poly(ethylene terephthalate) (PET) was studied by the dynamic model which accounts for the thermal decomposition of polymer at any time. The kinetic analysis was performed by a conventional nonisothermal thermogravimetric (TG) technique at several heating rates between 10 and 40 K/min in air atmosphere. The thermal decomposition of PET in air atmosphere was found to be a complex process composed of at least two stages for which kinetic values can be calculated. The combustion kinetic analysis of PET gave apparent activation energy for the first stage of $257.3{\sim}269.9\;kJ/mol$, with a value of $140.5{\sim}213.8\;kJ/mol$ for the second stage. To verify the effectiveness of the kinetic analysis method used in this work, the kinetic analysis results were compared with those of various analytical methods. The kinetic parameters were also compared with values of the pyrolysis of PET in nitrogen atmosphere.

Experimental Study on Reinforcement Effects of PET Sheet (PET 섬유의 보강효과에 관한 실험적 연구)

  • Ha, Sang-Su
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.5
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    • pp.163-169
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    • 2017
  • Although the strength of polyethylene terephthalate (PET) fibers which are generally used to make plastic bottles is low, the deformability of PET fibers is substantially high. Due to these material characteristics, a PET fiber can be used as a reliable strengthening material to resist a large deformation caused by earthquake and research pertinent to application of PET fibers is actively conducted in Japan. Therefore, in this study, experiments have been carried out to investigate the lateral confinement effect of PET fibers and to assess the applicability of PET fibers to construction fields by comparing the strengthening effect of PET fibers to that of carbon and glass fiber sheets. For this purpose, concrete cylinder specimens with parameters of different concrete strength and strengthening layers of carbon fiber sheets, glass fiber sheets, and PET fibers were respectively tested using two sets of cylinders for each parameter. As a result, specimens strengthened with carbon fiber sheets and glass fiber sheets failed due to sudden decrease of strength as with existing studies. However, specimens with PET fibers reached their maximum strength and then failed after gradual decrease strength without failure of PET fibers. In addition, although the strength of specimens with PET fibers did not significantly increase in comparison with that of specimens with carbon fiber sheets and glass fiber sheets, specimens with PET fibers indicated considerable deformability. Thus, a PET fiber can be considered as an effective strengthening material.