• 제목/요약/키워드: Polyether

검색결과 189건 처리시간 0.029초

Miscibility of TPU(PCL diol)/PCL Blend and its Effect on PCL Crystallinity

  • Ajili Shadi Hassan;Ebrahimi Nadereh Golshan
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.371-372
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    • 2006
  • Poly(${\varepsilon}-caprolactone$) (PCL) is a highly crystalline polymer that is miscible with several amorphous polymers including chlorinated polyether, poly(vinylchloride), poly(hydroxyether) and Bisphenol A polycarbonate. The crystallization behavior of miscible blend of amorphous/crystalline polymers has widely been studied. Generally a depression of the crystallization ability has been found with addition of amorphous component because of the reduction of chain mobility, the change of free energy of nucleation as a result of a specific interaction, and so on [1]. In this work, for the first time, the blend of PCL and copolymer of polyurethane containing polycaprolactone as a soft segment is considered. The structural similarity of TPU soft segment with PCL affects on formation of the miscible component and crystallization behavior of PCL in the blend. This has been studied using differential scanning calorimetry (DSC) and Wide-angle X-ray Scattering (WAXS).

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HTPE 둔감 추진기관의 급속가열 시험 및 평가 (Fast Cook-Off Test and Evaluation for HTPE IM Rocket Motor)

  • 이도형;김창기;연정모;정정용;유지창
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
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    • pp.167-170
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    • 2009
  • 본 연구에서는 추진기관 급속가열시험을 실시하여 그 특성을 분석 평가 하였다. 연소관은 카본 에폭시 복합재를 사용하였고 추진제는 둔감 특성을 향상 시켜주기 위해 HTPE 추진제를 사용하였다. 반응 형태를 정량적으로 판단하기 위해 음압 및 열유속 센서를 사용하였다. 급속가열 시험한 HTPE 모타들의 반응형태는 Type V 인 연소반응을 나타내었다.

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HTPE 둔감 추진기관의 충격 시험 및 평가 (Impact Test and Evaluation for HTPE IM Rocket Motor)

  • 김창기;이도형;연정모;유지창
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
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    • pp.163-166
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    • 2009
  • 본 연구에서는 추진기관 탄자 및 파편 충격시험을 실시하여 그 특성을 분석 평가 하였다. 연소관은 카본 에폭시 복합재를 사용하였고 추진제는 둔감 특성을 향상 시켜주기 위해 HTPE 추진제를 사용하였다. 반응 형태를 정량적으로 판단하기 위해 음압 및 열유속 센서를 사용하였다. 탄자 및 파편 시험한 HTPE 모타들의 반응형태는 Type V 인 연소반응을 나타내었다.

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Flexible Display Device with Organic Composite Film

  • Choi, Yang-Kyu;Yarimaga, Oktay;Kim, Tae-Won;Jung, Yun-Kyung;Park, Hyun-Gyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1233-1236
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    • 2008
  • This study presents the fabrication process and display characteristics of a flexible organic polymer display device that consists of a thin substrate of Polyether Sulfone, a multilayer serpentine-type microheater array that is fabricated on the substrate, and a UV-sensitive polydiacetylene (PDA)-polyvinyl alcohol (PVA) composite film. A retention time of one second is achieved with cell sizes of $500{\mu}m$ and $700{\mu}m$ with cell-to-cell distances of $100{\mu}m$ and $200{\mu}m$, respectively.

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The Synthetic Potential of SET Photochemistry of Silicon-Substituted Polydonor-Linked Phthalimides

  • Yoon, Ung Chan;Mariano, Patrick S.
    • Bulletin of the Korean Chemical Society
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    • 제27권8호
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    • pp.1099-1114
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    • 2006
  • Our studies in the area of single electron transfer (SET) photochemistry have led to the discovery of efficient processes, in which regioselective formation of carbon-centered radicals takes place by nucleophile assisted desilylation of $\alpha$-trialkylsilyl substituted ether, thioether, amine and amide centered cation radicals. The rates of bimolecular desilylation of the intermediate cation radicals exceed those of other cation radical $\alpha$-fragmentation processes (e.g.,-deprotonation). This sereves as the basis for the design of highly regioselective, SET-induced photomacrocyclization reactions of polyether, polythioether, polyamide, and polypeptide linked phthalimides. Photocyclization reactions of trimethylsilyl-terminated substrates in these families are unique in that they produce polyfunctionalized macrocyclic substances in a highly efficient and regioselective manner. In addition, our studies in this area have led to important information about the factors that govern chemical and quantum efficiencies that should be applicable to a wide variety of redox processes promoted by SET from substrates containing more than one electron donor site.

Synlube 제조에 관한 연구 (A Study on Synthesis of Synthetic Lubricants)

  • 정근우
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1989년도 제8회 학술강연회초록집
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    • pp.1-21
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    • 1989
  • 합성윤활유(synthetic lubricant)라 함음 현재까지도 계속되고 있는 광유(mineral oil)전성시대의 광유에 대응되는 말로써 광유계 윤활유로 부터 얻기 어려운 높은 점도지수, 낮은 저온 유동성 등의 특성을 얻기 위해 유기합성 방법에 의해 인위적으로 제조한 윤활유의 총칭이며 작용기의 종류, 합성방법, 등에 따라 다양하게 분류된다. 합성윤활유의 종류에는 합성방법에 따라 폴리머형(P형), 비포리머형(N형)으로 대별되는데, 폴리머형 합성유에는 Poly-butene, $Poly\alpha$-olefin, Polyalkylenglycol, Silicon oil, Chlorofluorocarbon, Perfluoroalkyl polyether등이 있으며, 비폴리머형 합성유에는 Alkylbenzene, Dibasicacidester, Polyolester, Silicate-ester Polyphenylether, Complex ester등이 포함된다. 전자의 경우에는 중합반응 조건을 조절하므로써 여러점도 등급의 합성유들을 얻을 수 있는 반면 후자의 경우에는 분자량이 크지 않으므로 저점도의 것만 얻어지는 것이 특징이다.

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고분자구조제어에 의한 microcapsule의 감성기능발현(II) -화학구조에 따른 polyurethane microcapsule의 특성- (Revelation of the Susceptibility of Microcapsule by the Control of Polymer Structure (II) -Preparation of polyurethane microcapsules with different chemical structures-)

  • Hong, Ki-Jeong;Park, Soo-Min
    • 한국염색가공학회지
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    • 제9권5호
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    • pp.63-74
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    • 1997
  • Polyurethane microcapsules were synthesized by interfacial polymerization in an aqueous poly(ethylene glycol) dispersion with ethylenediamine as chain extender of toluene diisocyanate in perfume oil using poly(vinyl alcohol) as the stabilizing agent. The effect of chemical structure on the average particle size and distributions, morphologies, and thermal properties to design microcapsules for the sustained release system was investigated. It came to be known that polyurethane microcapsules with ethylene diamine as chain extender had a rounder, more permeable and controlled release membranes. And the release test of polyurethane microcapsules with different soft segment content was done to certify the effect of long methylene chain. According to the higher molecular weight of polyether polyol, the release rate of microencapsulated disperse dye molecular was faster.

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디스크 받침용 고무패드의 거동 및 강성추정 (The Behavior and Estimated Stiffness Rubber Pad for Disk Bearing)

  • 조성철;최은수;박주남;김만철
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2009년도 춘계학술대회 논문집
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    • pp.599-605
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    • 2009
  • The aim of the present study is the characteristics of bridge rubber pads and suggested how to determine the stiffness the pads. A disk bearing is operated as an elastic bearing in the vertical direction and is composed of a Polyether Urethane (polyurethane) disk for elastic support and Polytetrafluoroethylene (PTFE) to accommodate movement. Static tests are conducted in a laboratory to determine the static behavior of a Polyurethane disk. Finite Element (FE) analysis is also performed to verify the static performance. For dynamic behavior, four disk bearings having the identical Polyurethane disk used in the static tests are installed in a full size railway bridge and tested under a running locomotive. From the tests results, the static and dynamic stiffness of disk bearings are estimated and compared with each other. In the procedure to estimate the stiffness of a pad, the dead load(pre-load) of a bridge and live load of a vehicle are considered.

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25,27-Bis(1-propyloxy)-5,11,17,23-tetrakis(1,1-dimethylethy) calix[4]arene-26,28-[(5',6')],(14',15')-dibenzo] crown-7, $C_{70}H_{90}O_9$의 결정구조 (The Crystal Structure of 25,27-Bis(1-propyloxy)-5,11,17,23-tetrakis(1,1-dimethylethy) calix[4]arene-26,28-[(5',6')],(14',15')-dibenzo] crown-7, $C_{70}H_{90}O_9$)

  • 김종성;추건홍;이창희;이진호;김문집;김진구;서일환
    • 한국결정학회지
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    • 제10권2호
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    • pp.114-118
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    • 1999
  • The title compound consisting of a calix[4]arene molecule with four phenyl rings arranged alter-nately in anti-orientation fashion, two propyloxy groups, and four para-tert-butyl group, attached on the upper rim of calix[4]arene, and polyether chain with two phenyl rings attached on the lower rim of calix[4]arene offers a big cavity inside the molecule that might possess a potential for form-ing host-guest complexes.

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The Analysis of the Characteristics according to Polymer Concentration for Polymer Light Emitting Diode Fabricated on Flexible Substrates

  • Cho, Woo-Jin;Kim, Su-Hwan;Kang, Byoung-Ho;Kim, Do-Eok;Kang, Shin-Won
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.752-755
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    • 2007
  • In this paper, to compare thermal and chemical stabilities of poly-ethylene-terephtalate (PET) and polyether- surphone (PES), we fabricated Polymer Light Emitting Diode (PLED) on each substrate and analyzed these characteristics. Moreover, we analyzed the characteristics of the device deposited LiF (1 nm) before cathode deposition.

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