• Title/Summary/Keyword: Polyester Resin

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Evaluation of Surface Condition and Food Solution on the Color Stability of Dental Restoration Materials (표면 상태와 용액에 따른 치과용 수복재료의 색안정도 평가)

  • Woo, Hee-Sun;Kim, Hyo-Jin;Jun, Soo-Kyung
    • The Journal of the Korea Contents Association
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    • v.19 no.4
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    • pp.359-367
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    • 2019
  • For this study, specimens were prepared using five types of composite resin and resin-reinforced glass ionomer Fuji II LC, and 29 days precipitation was done in four kinds of solution, which were soy sauce, gochujang, wine, and distilled water. Ten specimens for each coloring sample were divided into two groups, one those surfaces was polyester film and the other with 1200-grit abrasive paper, and 20 specimens per materials. Color change (${\Delta}{\ast}ab$) in the colored specimens is measured in 2days, 7days, 14days and 29days using spectrophotometer (CM-2600d, Konica, Minolta, Ramsey, NJ). All values were considered significant when P<0.05. 1. Each material is discolored over time under the influence of different storage solutions. 2. In soy source, among the specimens polished with polyester film, color change was observed in resin-modified glass ionomer Fuji II LC, prodigy and compomer F-2000 on day 2. Meanwhile, Fuji II LC showed noticeable color change in specimens prepared with 1200-grit sandpaper on day 2, which was followed by flowable resin on day 7. 3. On day 2, there was a color change with the specimens of flowable resin, resin-modified glass ionomer Fuji II LC and Prodigy among the hybrid specimen in the groups of polyester film in gochujang.

Fabrication of palatal lift prosthesis using thermoplastic resin for a patient with velopharyngeal insufficiency (구개인두부전증 환자에서 열가소성레진을 이용해 연구개거상장치를 제작한 증례)

  • Jung, Hyun Jung;Kim, Jee Hwan;Lee, Sang-Hwy;Park, Young-Bum
    • The Journal of Korean Academy of Prosthodontics
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    • v.54 no.3
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    • pp.286-290
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    • 2016
  • Recently, flexible removable prosthesis with thermoplastic resin clasp has increasingly become popular. In comparison with conventionally used acrylic resin, thermoplastic resin has lower flexural strength and elastic modulus. Thus, flexible removable prosthesis has low risk of fracture, so denture base can be made thin and light, increasing patient comfort. Also, it can passively sit at tooth undercut during rest, so abutment teeth need minimum or no preparation. In this case report, a 44 year old female patient with mild velopharyngeal insufficiency was treated with a palatal lift prosthesis made of polyester thermoplastic resin. Since the patient had no missing tooth and desired conservative treatment, the flexible removable prosthesis provided relatively satisfactory results.

Physical Properties of Permeable Polymer Concrete (투수성 폴리머 콘크리트의 물리적 성질)

  • 최재진;황의환
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.41-48
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    • 2002
  • In this paper, permeable polymer concretes with unsaturated polyester or vinylester resin content from 5 to 8 weight %, resin-filler ratio of 1 : 1, sand content from 0 to 15 weight % and crushed stone of size 2.5∼10 mm were prepared, and tested for compressive strength, flexural strength and water permeability. The effects of the resin and sand contents on the properties of permeable polymer concrete were discussed. It is concluded from the test results that increase in the strength and decrease in the coefficient of permeability of the permeable polymer concrete arc clearly observed with increasing the resin and sand contents. The permeable polymer concrete showed compressive strength in the range of 170 to 350 kgf/$\textrm{cm}^2$ and flexural strength in the range of 40 to 90 kgf/$\textrm{cm}^2$ at coefficient of permeability from 0.1 to 1.0 cm/sec in this experiment.

Micro- and Macroscopic Structures of Oriented Poly(trimethylene 2,6-naphthalate)(PTN) films (배향된 Poly(trimethylene 2,6-naphthalate)(PTN) 필름의 미시적/거시적 구조)

  • 양영일;김영호;이한섭
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.341-342
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    • 2003
  • Poly(trimethylene 2,6-naphthalate)(PTN)은 dimethyl-2,6-naphthalene dicarboxylate(NDC)와 1,3-propanediol(PDO)로 합성된 polyester이다. 비록 PTN은 아직 상업화된 resin은 아니지만 Poly(trimethylene terephthalate)(PTT)와 비슷한 화학적 구조를 가지며 PTT 보다 높은 유리전이 온도(72$^{\circ}C$)를 나타내고 있으므로 다양한 분야에 응용될 수 있다. 특히 최근에 1,3-propanediol based polyester는 가스 차탄 특성이 우수하다는 것이 보고되었으며 PTN의 산소, 이산화탄소 등 가스 차단 특성은 poly(ethylene 2,6-naphthalete)(PEN)보다 우수한 것으로 보고되었다. (중략)

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UV-curable polyester-acrylate coating with antimony doped tin oxide nanoparticles

  • Sung, Si-Hyun;Kim, Dae-Su
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.478-481
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    • 2010
  • Antimony doped tin oxide (ATO) nanoparticles were added as nanofillers to UV-curable polyester-acrylate (PEA) resin for coating to improve thermal, mechanical, and electrical properties. In this study, ATO nanoparticles were grafted by 3-glycidyloxypropyltrimethoxysilane and 3-methacryloxypropyltrimethoxysilane respectively to improve dispersion and interfacial adhesion. The physical properties and surface scratch hardness of the UV-curable nanocomposite coating were improved considerably by introducing the modified ATO nanoparticles.

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Reinforcement of mechanical properties in unsaturated polyester resin with nanosheet

  • Vahid Zarei
    • Advances in nano research
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    • v.16 no.1
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    • pp.81-90
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    • 2024
  • In the oil and gas industry, composite materials should exhibit high flexibility and strength for offshore structures. Therefore, weak points in the composites should be improved, such as brittleness, moisture penetration, and diffusion of detrimental ions into nanometric pores. This study aimed to increase the strength, flexibility, and plugging of nanopores using single-layer graphene oxide (SGO) nanosheets. Therefore, SGO is added to unsaturated polyester resin at concentrations of 0.015 and 0.15 % with Normal Methyl Pyrrolidone (NMP) as a solvent for the formation of Nanographene Oxide Reinforced Polymer (NGORP). The mechanical properties of the prepared samples were tested using tensile testing (ASTM-D 638). It has been shown that incorporating SGO, approximately 0.015%, into the base resin resulted in enhanced properties such as rupture resistance forces increased by 745.61 N, applied stress tolerances increased by 4.1 MPa, longitude increased to 1.58 mm, elongation increased by about 2.38%, and rupture energy increased by about 204.51 J. Despite the decrease in tensile force strength properties in the manufactured nanocomposite with 0.15% SGO, it has exclusive flexibility properties such as a high required energy level for rupture of 5,576 times and a formability of 40% more than the base sample. It would be best to use NGORP manufactured from 0.015% nanosheets with exclusive properties rather than base samples for constructing parts and equipment, such as rebars, composite sheets, and transmission pipes, on offshore platforms.

Cure Behavior, Thermal Stability and Flexural Properties of Unsaturated Polyester/Vinyl Ester Blends (불포화 폴리에스터/비닐에스터 블렌드의 경화 거동, 열안정성 및 굴곡 특성)

  • 이종문;조동환
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.120-128
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    • 2003
  • The effects of catalyst, accelerator and blend composition on the cure behavior of unsaturated polyester resin (UPE), vinyl ester resin (VE) and their blends were studied using differential scanning calorimetry(DSC). The DSC thermograms strongly depend on each variable. The result shows that the small exothermic peak at 115$^{\circ}C$ is due mainly to the UPE component in the UPE/VE blends and the large one at 134~138 $^{\circ}C$ is due mainly to the VE component. The results also indicate that the change of the DSC thermogram measured after each blend was exposed to high temperature 18$0^{\circ}C$ and the fast curing conditions of a few tens seconds provide useful information on understanding the thermal processing of a blend at high speed. The measurements of resin flow time represent that there are three distinct stages of cure in the UPE/VE blends: induction, transition and macro-gelation stages, as similarly reported for UPE by others earlier. The thermal stability and flexural properties of the cured UPE are significantly improved by blending it with the VE, depending on the composition.

Properties of Randomly Oriented Chopped E-glass Reinforced Unsaturated Polyester Based Resin Composite -Effect of Length/Content of E-Glass Fiber and Number of Stacking- (랜덤상태의 E-유리 단섬유 강화 불포화 폴리에스터 기반 수지 복합재료의 물성 - E-유리 단섬유의 길이와 함량 및 적층수의 영향 -)

  • Park, Jin-Myung;Park, Young-Gwang;Lee, Young-Hee;Seo, Dae-Kyung;Lee, Jang-Hun;Kim, Han-Do
    • Textile Coloration and Finishing
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    • v.27 no.3
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    • pp.165-174
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    • 2015
  • To develop automobile parts, the unsaturated polyester based matrix resin(PR)/reinforcement(randomly oriented chopped E-glass fiber, GF) composites were prepared using sheet molding compound(SMC) compression molding. The effects of GF length(0.5, 1.0 1.5 and 2.0inch)/content (15, 20, 25, 30wt%) and number of ply(3, 4 and 5) on the specific gravity and mechanical properties of PR/GF composites were investigated in this study. The optimum length of GF was found to be about 1.0inch for achieving improved mechanical properties(tensile strength and initial modulus). The tensile strength and initial modulus of composites increased with increasing GF content up to 30wt%, which is favorable content range for SMC. The specific gravity, tensile strength/initial modulus, compressive strength/modulus, flexural strength/modulus and shear strength increased with increasing the number of ply up to 5, which is the maximum number of ply range for SMC. The effectiveness of ply number increased in the flexural strength > shear strength > compressive strength > tensile strength.

Moisture Absorption Behavior of CNT Reinforced Unsaturated Polyester Composites (CNT 강화 불포화 폴리에스터 복합재료의 수분흡수 거동에 관한 연구)

  • Park, Ji-Hye;Yoon, Sung-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.536-538
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    • 2011
  • In this study, the moisture absorption behaviors of the CNT reinforced unsaturated polyester composites were investigated along with exposure temperature and time. The tensile properties of the specimens were evaluated to identify the effect of absorbed moisture on the mechanical properties. The exposure temperatures of $25^{\circ}C$ and $75^{\circ}C$ were considered and the exposure time up to 600 hours was applied. According to the results, moisture absorption rate was increased as CNT content and exposure temperature were increased. The rate of decrease in tensile strength of the CNT reinforced unsaturated polyester composites was reduced due to the reinforcing effect of CNT compared to the unsaturated polyester resin.

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Jet-Fuel-Resistant PVC Sealant Containing a Polyester Plasticizer (폴리에스터 가소제를 사용한 내제트유성 PVC계 실란트)

  • Nam, Byeong-Uk;Kim, Seog-Jun
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.342-353
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    • 2003
  • This work is about the development of jet-fuel resistant PVC sealant using a polyester plasticizer. PVC copolymer was compounded with adipic acid glycol(Songcizer P-3000) or DOP plasticizers. Fuel-immersed and non-immersed penetration, solubility, flow, and elongation by tensile adhesion of PVC compounds were measured. Penetration increase by fuel immersion and solubility of PVC compounds with adipic acid glycol polyester plasticizer were smaller than those of PVC compounds with DOP plasticizer. Elongation by tensile adhesion test of PVC compound containing 500 phr of Songcizer P-3000 decreased proportionally to the content of DCDP (dicyclopentadiene) base petroleum resin adhesion promoter. Calcium carbonate($CaCO_3$) filler inhibited the diffusion of fuel in all the PVC compounds and decreased the solubility of PVC compounds containing Songcizer P-3000.